Technology for recovering platinum, palladium and rhodium from spent auto-catalyst

An auto catalyst and platinum-palladium technology, which is applied in the field of recovering platinum, palladium and rhodium, can solve the problems of polluting the environment with nitrogen oxides, high content of leaching residues and high direct yield, and achieve good environmental protection, high direct yield and simple process. Effect

Inactive Publication Date: 2015-08-12
KUNMING ZHENGJIANG IND & TRADE CO LTD
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  • Abstract
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  • Application Information

AI Technical Summary

Problems solved by technology

[0009] For overcoming above defect, the beneficial effect of a kind of technology that reclaims platinum palladium rhodium from exhausted automobile catalyst of the present invention is: effectively solve the problem that the leaching rate of invalidated automobile catalyst wet process is low, the leaching slag content is high, needs further extraction, greatly Reduce production costs and improve recovery efficiency; avoid the problem of a large amount of nitrogen oxides that are seriously polluted by the traditio

Method used

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  • Technology for recovering platinum, palladium and rhodium from spent auto-catalyst
  • Technology for recovering platinum, palladium and rhodium from spent auto-catalyst
  • Technology for recovering platinum, palladium and rhodium from spent auto-catalyst

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Embodiment 1

[0034] (1) Pretreatment

[0035] The exhausted automobile catalyst is crushed and sieved, the sieve mesh is 205 mesh, the sieve is returned to continue to be crushed and then sieved, and the undersieve is treated with sulfuric acid acid etching, the temperature of sulfuric acid acid etching is 250 ℃, and the concentration of sulfuric acid is 65%. Acid etching material, used for enrichment process;

[0036] During the crushing and sieving process, fans are used to draw air and dust is collected by cloth bags. During the acid etching process, the equipment is sealed, and the gas generated enters the third stage of absorption through the exhaust. The acidic water absorption solution is returned to acid etching;

[0037] (2) Enrichment

[0038] The acid etching material is subjected to secondary chlorination leaching, and the leaching solution is replaced to obtain platinum, palladium and rhodium replacement slag, and the leaching slag is piled up for storage;

[0039] Seconda...

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Abstract

A technology for recovering platinum, palladium and rhodium from a spent auto-catalyst comprises the following steps: pre-processing, enriching, removing impurities, separating, and purifying to obtain relevant platinum, palladium and rhodium products. The technology has the following advantages: environment protection in the whole flow from preprocessing to enriched platinum, palladium and rhodium separation and purification and product discharge is good; the technology has good process continuity, simple flow, and high platinum, palladium and rhodium separation and purification efficiency; and in the recovery process, the direct recovery rate of platinum is not lower than 91%, and the direct recovery rate of palladium is not lower than 95%.

Description

technical field [0001] The invention belongs to the technical field of metal material extraction, in particular to a process for recovering platinum, palladium and rhodium from exhausted automobile catalysts. Background technique [0002] The three elements of platinum, palladium and rhodium (hereinafter referred to as platinum group metals) have unique physical and chemical properties, and are widely used in aviation, aerospace, navigation, missiles, rockets, atomic energy, microelectronics technology, chemical industry, petrochemical industry, glass fiber, Exhaust gas purification and metallurgical industry are widely used in various fields, and have become important materials in modern industry, military industry and high-tech industries, known as "modern industrial vitamins". [0003] In recent years, the consumption of platinum group metals in my country has continued to grow rapidly, from a few tons in the past to dozens of tons at present. However, my country's plati...

Claims

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Application Information

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IPC IPC(8): C22B7/00C22B11/00
CPCY02P10/20
Inventor 唐平江
Owner KUNMING ZHENGJIANG IND & TRADE CO LTD
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