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A normal temperature and pressure dyeing method for polyester textiles mediated by a polyelectrolyte polymer nanofilm

A polyelectrolyte and atmospheric pressure dyeing technology, which is applied in the field of textile printing and dyeing, can solve the problems of polyester fabrics such as the decrease of color fastness and the failure to form a firm bond, and achieve easy operation, improved hydrophilicity, and avoid toxic carriers and complicated dyeing The effect of using the equipment

Active Publication Date: 2017-01-18
南通崧澜纺织科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But because nano TiO 2 There is physical adsorption between the particles and the polyester fabric, and no firm combination is formed, and the color fastness of the polyester fabric decreases significantly after washing

Method used

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  • A normal temperature and pressure dyeing method for polyester textiles mediated by a polyelectrolyte polymer nanofilm

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] According to the above process steps: choose 180g / m 2The pure polyester fabric was used as the sample to be dyed, and the 0.5M sodium hydroxide aqueous solution was prepared, and the polyester fabric was soaked in the lye solution, and the liquor ratio was kept at 1:10. Magnetic stirring was carried out at 40 °C for 1 h. The alkali-treated polyester fabric was washed three times with deionized water and then dried at a drying temperature of 60°C for 30 min. The dried polyester fabric is immersed in an aqueous solution of polyelectrolyte polymer solution polyethyleneimine and polyacrylic acid in turn, wherein the concentrations of the aqueous solutions of polyethyleneimine and polyacrylic acid are 0.5 mg / mL respectively, and both contain 0.5 M NaCl. Scanning electron microscope test showed that the surface of polyester fiber treated with alkali solution at 40 ℃ did not change significantly, and the surface morphology (attached). figure 1 b) The basic and as-received s...

Embodiment 2

[0041] According to the above process steps: choose 180g / m 2 The pure polyester fabric was taken as the sample to be dyed, and the 0.5M sodium hydroxide aqueous solution was prepared, and the polyester fabric was soaked in the lye solution, and the liquor ratio was kept at 1:20. Magnetic stirring was carried out at 70 °C for 1 h. The alkali-treated polyester fabric was washed three times with deionized water and then dried at a drying temperature of 60°C for 30 min. The dried polyester fabric was immersed in an aqueous solution of polyelectrolyte polymer solution polyethyleneimine and sodium alginate in turn, wherein the concentrations of the aqueous solutions of polyethyleneimine and sodium alginate were 0.5 mg / mL, and both contained 0.5M NaCl. Scanning electron microscope test showed that the surface of polyester fiber after being treated with alkali solution at 70 ℃ began to become rough (attached). figure 1 Figure c in ). Moreover, in the polyester fabric after assembl...

Embodiment 3

[0044] According to the above process steps: select 180g / m2 pure polyester fabric as the sample to be dyed, configure 0.5M sodium hydroxide aqueous solution, soak the polyester fabric in lye, and keep the liquor ratio at 1:10. Magnetic stirring was carried out at 70 °C for 1 h. The alkali-treated polyester fabric was washed three times with deionized water and then dried at a drying temperature of 60°C for 30 min. The dried polyester fabric is soaked in an aqueous solution of polyelectrolyte polymer solution polyethyleneimine and sodium polystyrene sulfonate in turn, wherein the concentrations of the aqueous solutions of polyethylene imine and sodium polystyrene sulfonate are 0.5 mg respectively / mL, and both contained 0.5M NaCl. The polyester fabric assembled with two double-layer polyethyleneimine / sodium polystyrene sulfonate nanomembranes was immersed in a water-soluble dye methylene blue dye solution at room temperature and pressure for dyeing with a liquor ratio of 1:50....

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Abstract

The invention discloses a polyelectrolyte nano-membrane-mediated terylene textile normal temperature normal pressure dyeing method. The invention relates to a method for dyeing a terylene textile under conditions of a normal temperature and normal pressure and belongs to the technical field of textile dyeing. The terylene textile normal temperature normal pressure dyeing method is characterized in that a polyelectrolyte polymer nano-membrane with hydrophilic function groups is self-assembled to the surface of a terylene textile to be dyed and then the terylene textile is dyed under conditions of a normal temperature and normal pressure. The hydrophilic function groups of the nano-membrane can improve surface performances of a terylene textile so that dyeing performances and dyeing conditions of the terylene textile are improved. In the whole dyeing process, operation is simple, carriers are avoided, toxic chemical substances are avoided and the use of a toxic carrier and a complex dyeing device, which are used in high-temperature high-pressure carrier dyeing, is avoided. Therefore, the method has a wide application prospect in synthetic fiber dyeing.

Description

technical field [0001] The invention relates to a method for dyeing polyester textiles at room temperature and pressure mediated by a polyelectrolyte polymer nanofilm, belonging to the technical field of textile printing and dyeing. [0002] technical background [0003] Polyester, chemical name polyethylene terephthalate, is one of the most attractive and competitive synthetic fibers. It has high strength, high modulus and high elastic recovery ability. The textile fabric formed by it is strong and durable, wrinkle-resistant and iron-free , and has good light resistance and heat resistance. However, the molecular structure of polyester lacks reactive groups that can be combined with dye molecules like cellulose or protein fibers. The fiber structure is dense, and its crystallinity and orientation are high, which makes it difficult for the dye to wet it, which hinders the dye in the fiber. On the adsorption and diffusion, difficult to dye. For this reason, disperse dyes are...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M15/03D06M15/356D06M15/61D06M15/13D06M15/263D06M11/38D06P3/52D06M101/32
Inventor 肖仕丽王浩陈小捷徐卫林
Owner 南通崧澜纺织科技有限公司