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Aluminum tellurium master alloy and its preparation method and application

A technology of aluminum-tellurium master alloy and master alloy, which is applied in the field of aluminum-tellurium master alloy and its preparation, can solve the problems of tellurium segregation and precipitation, difficulty in control, deposition at the bottom of the crucible, etc., achieve stable and accurate yield, and not easy to burn and oxidize , Reduce the effect of burning loss and oxidation

Active Publication Date: 2017-06-16
成都锦钛精工科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the low melting and boiling point of tellurium (melting point is 452°C, boiling point is 1390°C), burning loss and oxidation are prone to occur at the conventional melting temperature of aluminum alloy (740°C), resulting in low yield of tellurium in aluminum alloy, and Yield is unstable and difficult to control
At the same time, due to the high density of tellurium (6.25g / cm 3 ), tellurium tends to segregate and precipitate during the smelting process, and tellurium is partially distributed unevenly and deposited at the bottom of the crucible, resulting in uneven distribution of tellurium in the prepared aluminum alloy, low yield, and affecting the mechanical properties of the aluminum alloy and electrical conductivity

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] The preparation method of the aluminum-tellurium master alloy described in this embodiment is as follows:

[0035] (1) Ingredients

[0036] Using tellurium and aluminum as raw materials, the mass fraction of tellurium in the aluminum-tellurium master alloy is 0.1%, and the mass fraction of aluminum is 99.9% to weigh the raw materials;

[0037] (2) Melting

[0038] After preheating aluminum in a heating furnace to remove adsorbed moisture and gas, add a covering agent of 0.5% of the total mass of aluminum and tellurium, the covering agent is obtained by mixing sodium chloride and potassium chloride at a mass ratio of 1:1 The mixture is heated to melt all the aluminum to obtain aluminum liquid, and then the tellurium is pressed into the aluminum liquid in batches with a bell jar at 680 ° C. The amount added each time is 3% of the total amount of tellurium. After all the tellurium is added and melted, Keep stirring at 680°C for 5 minutes, then remove slag, keep the tempe...

Embodiment 2

[0042] The preparation method of the aluminum-tellurium master alloy described in this embodiment is as follows:

[0043] (1) Ingredients

[0044] Using tellurium and aluminum as raw materials, the mass fraction of tellurium in the aluminum-tellurium master alloy is 1.0%, and the mass fraction of aluminum is 99.0% to weigh the raw materials;

[0045] (2) Melting

[0046]After the aluminum is preheated in a heating furnace to remove the adsorbed moisture and gas, 1.0% of the total mass of aluminum and tellurium is added as a covering agent potassium chloride, heated to melt all aluminum to obtain aluminum liquid, and then batched at 720 ° C. Press the tellurium into the molten aluminum with a bell jar, and the amount of each addition is 5% of the total amount of tellurium. After all the tellurium is added and melted, keep stirring at 700 ° C for 10 minutes, and then remove the slag. Adding 0.7% of the total mass of aluminum and tellurium to the aluminum and tellurium melts af...

Embodiment 3

[0050] The preparation method of the aluminum-tellurium master alloy described in the present embodiment is as follows:

[0051] (1) Ingredients

[0052] Using tellurium and aluminum as raw materials, the raw materials are weighed according to the mass fraction of tellurium in the aluminum-tellurium master alloy is 10.0% and the mass fraction of aluminum is 90.0%;

[0053] (2) Smelting

[0054] After the aluminum is preheated in a heating furnace to remove the adsorbed moisture and gas, 1.0% of the total mass of aluminum and tellurium is added as a covering agent potassium chloride, heated to melt all aluminum to obtain aluminum liquid, and then batched at 720 ° C. Press the tellurium into the molten aluminum with a bell jar, and the amount of each addition is 5% of the total amount of tellurium. After all the tellurium is added and melted, keep stirring at 700 ° C for 10 minutes, and then remove the slag. Adding 0.7% of the total mass of aluminum and tellurium to the alumin...

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Abstract

The aluminum-tellurium master alloy of the present invention is composed of tellurium with a mass fraction of 0.1% to 48% and aluminum with a mass fraction of 52% to 99.9%. The preparation method is as follows: (1) batching; (2) smelting, placing aluminum in Preheat in a heating furnace, heat under the protection of an inert gas or add a covering agent to melt all the aluminum to obtain aluminum liquid, the amount of the covering agent added is 0.5% to 2% of the total mass of aluminum and tellurium, and then Press tellurium into the molten aluminum in batches at 800°C. When all the tellurium is added to the molten aluminum and melted, adjust the temperature to 680-740°C and keep stirring for 5-30 minutes to remove slag. After removing slag, keep the temperature and add refining agent Refining, followed by static heat preservation for 5 to 10 minutes; (3) pouring. The invention also provides the application of the aluminum-tellurium master alloy in the preparation of tellurium-containing aluminum alloys. The invention can improve the tellurium yield in the tellurium-containing aluminum alloy, make the tellurium yield stable and easy to control, and make the tellurium distribution in the aluminum alloy even.

Description

technical field [0001] The invention belongs to the field of aluminum and aluminum alloy materials, and in particular relates to an aluminum-tellurium master alloy and its preparation method and application. Background technique [0002] Due to the advantages of abundant resources, light weight, high specific strength, good electrical and thermal conductivity, and strong corrosion resistance, aluminum alloys are widely used in various fields such as machinery manufacturing, transportation machinery, power machinery, chemical industry, aviation industry, and military. With the development of the automobile, electronics, machinery and other industries towards lightweight, precision and intelligence, especially the rapid development of the automobile industry, higher requirements are put forward for the comprehensive performance of aluminum alloys. Therefore, how to improve the comprehensive properties of aluminum alloys has become an important and difficult point in the resear...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C21/00C22C1/03
Inventor 陈婷赵明建
Owner 成都锦钛精工科技有限公司
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