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Preparation method for W-Cu composite materials of fiber and particle hybrid structure

A composite material and particle technology, applied in the field of preparation of fiber and particle hybrid structure copper-tungsten composite material, can solve the problems of aggravating ablation and wear, difficult to achieve continuous skeleton structure, insufficient strength of tungsten skeleton, etc., and achieve high temperature strength. improved effect

Active Publication Date: 2015-11-11
XIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There is limited space for synergistically improving the high-temperature strength and arc ablation resistance of contact materials in traditional processes, such as strengthening the sintering of the tungsten skeleton, adding a third component, etc. Although it can improve the arc ablation resistance of contact materials, However, after multi-frequency breaking, since the powder is randomly sintered, it is difficult to achieve a complete continuous skeleton structure, resulting in insufficient strength of the tungsten skeleton after ablation, which aggravates ablation and wear

Method used

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  • Preparation method for W-Cu composite materials of fiber and particle hybrid structure
  • Preparation method for W-Cu composite materials of fiber and particle hybrid structure
  • Preparation method for W-Cu composite materials of fiber and particle hybrid structure

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Step 1, prepare composite material green body:

[0037] Weigh 70% of W powder and 30% of Cu powder according to mass percentage, the sum of the mass percentages of the above components is 100%, put W powder and Cu powder in a drum mixer with a ball-to-material ratio of 0.5:1 at 400r / min Mix at a rotating speed for 6h;

[0038] After the mixed composite powder is sieved to remove impurities, it is laid out layer by layer with the pickled tungsten fiber net in the cold pressing mold, and the interval between the pressed tungsten fiber net is 2mm, and it is pre-pressed at 200MPa, and the pressure is maintained for 90s. A composite green body is formed.

[0039] The tungsten fiber mesh is woven from tungsten fibers with a wire diameter of 60 μm, and its specification is 100 mesh. Before laying layers, the tungsten fiber mesh is pickled with HF to remove the oxide film on its surface.

[0040] Step 2, heat pressing:

[0041] Put the green body obtained in step 1 into a pr...

Embodiment 2

[0045] Step 1, prepare composite material green body:

[0046] Weigh 90% of W powder and 10% of Cu powder according to mass percentage, the sum of the mass percentages of the above components is 100%, put W powder and Cu powder in a drum mixer with a ball-to-material ratio of 0.7:1 at 400r / min Mix at a rotating speed for 7 hours;

[0047] After the mixed composite powder is sieved to remove impurities, it is layered with the pickled tungsten fiber net in the cold pressing mold, and the distance between the pressed tungsten fiber net is 3mm, and it is pre-pressed at 400MPa, and the pressure is maintained. After 30s, a composite material green body is formed.

[0048] The tungsten fiber mesh is woven from tungsten fibers with a wire diameter of 40 μm, and its specification is 30 mesh; the tungsten fiber mesh is pickled with HF before laying layers to remove the oxide film on its surface.

[0049] Step 2, heat pressing:

[0050] Put the green body obtained in step 1 into a pre...

Embodiment 3

[0054] Step 1, prepare composite material green body:

[0055] Weigh 85% of W powder and 15% of Cu powder according to mass percentage, the sum of the mass percentages of the above components is 100%, put W powder and Cu powder in a drum mixer with a ball-to-material ratio of 1:1 at 400r / min Mix at a rotating speed for 8 hours;

[0056]After the mixed composite powder is sieved to remove impurities, it is layered with the pickled tungsten fiber net in the cold pressing mold, and the distance between the pressed tungsten fiber net is 1mm, and it is pre-pressed, the pre-pressure is 340MPa, and the After pressing for 60s, a composite material green body is formed.

[0057] The tungsten fiber mesh is woven from tungsten fibers with a wire diameter of 40 μm, and its specification is 30 mesh; the tungsten fiber mesh is pickled with HF before laying layers to remove the oxide film on its surface.

[0058] Step 2, heat pressing:

[0059] Put the green body obtained in step 1 into a...

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Abstract

The invention provides a preparation method for W-Cu composite materials of a fiber and particle hyrid structure. Particularly, W powder and Cu powder hyrid evenly and a W fiber net obtained after acid pickling are laid in a cold pressing mold in a layered mode and then subjected to pre-pressing and pressure maintenance to obtain a composite material green body; then the green body is put in to a mold capable of being pressurized and subjected to hot pressing in an atmosphere protection hot pressing furnace; and finally, the composite material green body obtained after hot pressing is subjected to copper cementation in a high-temperature atmosphere sintering furnace, so that the W-Cu composite materials of the fiber and particle hyrid structure are obtained. The two-dimensional W fiber net is added in the preparation process of a W-Cu pseudo alloy W framework. The two-dimensional W fiber net and the W-Cu pseudo alloy W framework form metallurgical bonding through processing of an interface of fibers and the W framework and reasonable technological parameters, the W fiber net has a function like reinforcing ribs for the W framework, and therefore the high-temperature strength of the composite materials is obviously improved.

Description

technical field [0001] The invention belongs to the technical field of composite material preparation, and relates to a preparation method of copper-tungsten composite material with fiber and particle hybrid structure. Background technique [0002] In order to meet the requirements of the continuous development of the power market, my country's high-voltage switchgear is developing in the direction of high voltage, large capacity and miniaturization. The capacity of new circuit breakers will continue to increase, while the space of the arc extinguishing chamber will continue to shrink, so that the load borne by the unit area of ​​the arcing contacts will continue to increase; at the same time, in order to reduce maintenance costs, the life of the contacts is required However, it is getting longer and longer, so it is hoped that the contact material not only has excellent arc ablation resistance, but also has excellent high temperature strength. There is very limited space f...

Claims

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Application Information

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IPC IPC(8): C22C47/14C22C47/20C22C49/10C22C111/02
Inventor 梁淑华李阳张乔李向阳李玉春邹军涛卓龙超
Owner XIAN UNIV OF TECH
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