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311results about How to "Improve strength and toughness" patented technology

High-strength, high-toughness and high-plasticity martensitic stainless steel and preparation method thereof

ActiveCN103614649AImprove the level of toughness and plasticityImprove stabilityMartensitic stainless steelRoom temperature
The invention discloses high-strength, high-toughness and high-plasticity martensitic stainless steel, and belongs to the technical field of metallurgy. The martensitic stainless steel comprises the following components in percentage by weight: 0.15 to 0.4 percent of C, 0 to 0.12 percent of N, 0.2 to 2.5 percent of Si, 0.4 to 3.0 percent of Mn, less than or equal to 0.02 percent of S, less than or equal to 0.02 percent of P, 13.0 to 17.0 percent of Cr, 0 to 5.0 percent of Ni, 0 to 2.0 percent of Mo, 0 to 0.3 percent of V, 0 to 0.2 percent of Nb, 0 to 0.05 percent of Ti, 0 to 0.8 percent of Al and the balance of Fe and inevitable impurities. A preparation method comprises the following steps of (1) smelting molten steel according to the set components, and solidifying the molten steel to form an ingot blank by using a continuous casting machine or a casting mold; (2) hot-rolling the ingot blank to form a hot-rolled plate blank; (3) heating the hot-rolled plate blank to 950 to 1100 DEG C, preserving heat for 0.5 to 2 hours, cooling the plate blank to 25 to 200 DEG C, heating the plate blank to 350 to 500 DEG C, preserving heat for 10 to 60 minutes, and air-cooling the plate blank to room temperature. According to the martensitic stainless steel prepared by the method, dispersed remaining martensite is introduced into a microscopic structure, so that the strength, toughness and plasticity of the martensitic stainless steel are greatly improved.
Owner:NORTHEASTERN UNIV

Preparation method of multidimensional hybrid composite of glass fibre/ grapheme- carbon nano tube/ epoxy resin

The invention relates to a preparation method of multidimensional hybrid composite of glass fibre/ grapheme-carbon nano tube/ epoxy resin. In the method, after grapheme-carbon nano tube network structure is subjected to surface carboxylation, diamine or polyamine is introduced on the grapheme-carbon nano tube network structure; the grapheme-carbon nano tube connected with the amino is modified by micromolecule aromatic polybasic anhydride compound to prepare the carbon nano tube carried with an anhydride group; the grapheme-carbon nano tube is dispersed in the epoxy resin matrix by ultrasonic oscillation and high-speed stirring; organic acid anhydride curing agent is adopted for curing; and the obtained epoxy resin polymer containing the grapheme-carbon nano tube serves as the matrix to be compounded with glass fiber processed by silane coupling agent to form a multifunctional hybrid composite structure connected by covalent bonds. The multidimensional hybrid composite is convenient to prepare, the application range of the glass fiber, the grapheme, the carbon nano tube and the epoxy resin is widened, so that the hybrid composite can be widely applied on the aspects of aerospace, traffic transportation, electronic industry, civil facilities, building, chemical engineering and the like, can be industrially produced on a large scale, has low cost and is friendly to environment.
Owner:TONGJI UNIV

Silicon carbide based reinforced composite ceramic and preparation

The invention discloses a reinforced silicon carbide-based composite ceramic and a preparation method thereof. The composite ceramic is characterized by comprising the following components based on weight percentages: 30%-40% of silicon carbide powder, 5%-17% of boron carbide powder, 9%-12% of nano carbon black and 40%-50% of silicon metal. The method comprises the following steps: firstly, ball milling and wet mixing are performed on the silicon carbide powder, the carbon black and the boron carbide powder to obtain mixed powder, and a bonding agent PVB is added for granulation, die pressing is performed for forming; then the formed green compact is dried and put in an air furnace for binder removal; and finally, the obtained green compact is put into a graphite crucible with silicon powder, and siliconizing and sintering are completed after 1-3h heat preservation at 1450-1550 DEG C under a vacuum environment, thus obtaining a sintering body. The boron carbide particle reinforced reaction sintered silicon carbide composite ceramic prepared by the method can be widely used as a structural material under high-temperature atmosphere and corrosive atmosphere, a frictional wear material and the like; and as the composite ceramic has better obdurability and hardness, the ceramic can be used as a substitute material of the traditional reaction sintered silicon carbide.
Owner:珠海亿特立新材料有限公司

Method for preparing hybrid composite material of carbon fibers/carbon nanotubes/bismaleimide resin

The invention belongs to the technical field of nano materials, and in particular relates to a method for preparing a hybrid composite material of carbon fibers/carbon nanotubes/bismaleimide resin. The method comprises the following steps: after carboxylating, acylating and chlorinating the surfaces of purified carbon nanotubes and dried carbon fibers, introducing diamine or polyamine with a feature structure thereon, wherein a large amount of the diamine or the polyamine are jointed on the surfaces of the carbon nanotubes and the carbon fibers; performing an addition reaction on the carbon nanotubes jointed with the amidogen and the bismaleimide resin to obtain a carbon nanotubes-containing bismaleimide resin linear block polymer serving as a substrate; and compositing the substrate and the carbon fibers in a certain mode to form a multi-dimensional hybrid composite material structure linked by covalent bonds finally. The method has the advantages of strengthening and toughening bismaleimide by using the strength and the toughness of the carbon nanotubes, improving the bonding strength between the bismaleimide and the carbon fiber substrate surface, improving overall performance of the multi-dimensional hybrid composite material of the carbon fibers/the carbon nanotubes/ the bismaleimide resin, and widening the application of the carbon fibers, the carbon nanotubes and the bismaleimide resin.
Owner:TONGJI UNIV

Nonionic self-emulsifying water-based epoxy curing agent with Gemini surfactant structure and preparation method thereof

The invention discloses a nonionic self-emulsifying water-based epoxy curing agent with Gemini surfactant structure, of which the molecular general formula is disclosed in the specification. The preparation method comprises the following steps: 1) adding alkyl phenol, polyamine and formalin in a solvent to carry out Mannich reaction, and removing the solvent and byproduct after the reaction finishes, thereby obtaining Mannich amine containing primary amine group; and 2) sufficiently reacting the Mannich amine containing primary amine group with diglycidyl ether, cooling after the reaction finishes, adding water, and sufficiently dispersing to obtain an emulsion, thereby obtaining the product. The synthesis technique is simple and pollution-free; the synthesized curing agent does not need to perform salification reaction to implement self-emulsifying action by using organic acid; the epoxy curing agent has the advantages in the Gemini surfactant and has the characteristics of excellent wettability, excellent emulsibility, excellent stability and the like; and the epoxy curing agent can directly emulsify and cure the liquid epoxy resin, and can also cure an epoxy resin dispersion solution.
Owner:GUANGZHOU SUPER CHEM COATING CO LTDGUANGZHOU SUPER CHEM COATING CO LTD

Method for manufacturing X100 pipeline steel submerged arc straight weld pipe

The invention discloses a method for manufacturing an X100 pipeline steel longitudinal submerged arc welded pipe which is a longitudinal submerged arc welded pipe for transporting oil and gas. The method comprises using an X100 controlled rolled steel plate, the chemical compositions by percentage are: 0.02 to 0.08 percent of C, 0.10 to 0.30 percent of Si, 1.60 to 2.10 percent of Mn, less than or equal to 0.02 percent of, less than or equal to 0.005 percent of S, 0.06 to 0.1 percent of V+Nb+Ti, 0.6 to 1.0 percent of Ni+Cr+Cu, 2 to 2.6 percent of Cr+Mo+Mn. The manufacturing process of the pipe includes: baiting, edge milling of the steel plate, prebending, molding, prewelding, internal welding, external welding, expanding, and chamfering, wherein the molding process is punching the steel plate by a JCO molding machine and bend the steel plate into a J-shape, a C-shape and an open O-shape in turn; the internal welding and the external welding are welding the internal side and the external side of the pipe by four-wire submerged arc welding. The method of the invention can mold the steel plate into a pipe much more approximate to a round shape, realizes high-speed welding and improves working efficiency, with the welding process ensuring the internal quality and external quality of the steel plate.
Owner:BC P INC CHINA NAT PETROLEUM CORP +2

Super-high-strength martensite aging stainless steel resistant to seawater corrosion

The invention belongs to the field of high-strength stainless steel and provides martensite aging stainless steel which is high in toughness and good in corrosion resistance. The strength of the martensite aging stainless steel reaches 2000 MPa or above. The specific chemical constituents of the martensite aging stainless steel comprise, by weight percentage, less than or equal to 0.03% of C, 13.0-14.0% of Cr, 5.5-7.0% of Ni, 5.5-7.5% of Co, 3.0-5.0% of Mo, 1.9-2.5% of Ti, less than or equal to 0.1% of Si, less than or equal to 0.1% of Mn, less than or equal to 0.01% of P, less than or equal to 0.01% of S and the balance Fe. The stainless steel has the excellent seawater corrosion resistance; the pitting potential Epit is greater than or equal to 0.15 V, and high tough fit is achieved; sigma b is greater than or equal to 2000 MPa, sigma 0.2 is greater than or equal to 1700 MPa, delta is greater than or equal to 8%, and psi is greater than or equal to 40%; the martensite aging stainlesssteel is applicable to manufacturing of high-strength and high-toughness structural components used in a chloridion-containing rigorous corrosion environment such as seawater; the content of preciousmetal Co in the steel is low; material production cost is effectively lowered; and wide application prospect is achieved.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI +1

Preparation method of glass fiber/carbon nanotube/epoxy resin multi-dimensional hybrid composite material

The invention relates to a preparation method of a glass fiber/carbon nanotube/epoxy resin multi-dimensional hybrid composite material. The preparation method provided by the invention comprises the following steps of: treating glass fiber with a silane coupling agent; carrying out surface carboxylation and chlorination on carbon nanotubes, then introducing diamine or polyamine to the carbon nanotubes, and modifying the carbon nanotubes connected with an amino group by a polybasic anhydride compound to prepare the carbon nanotubes carrying an anhydride group; dispersing the treated carbon nanotubes in an epoxy resin matrix by ultrasonic oscillation and high-speed stirring, and curing with an organic anhydride curing agent; and compounding the obtained carbon-nanotube-containing epoxy resin polymer used as a matrix with the coupling-agent-treated glass fiber to form a multi-dimensional hybrid composite material structure linked through covalent bonds. The preparation method provided by the invention has the advantages that: the composite material is convenient to prepare, the dispersion of the carbon nanotubes in epoxy resin is improved, and the strength and toughness of the carbon nanotubes are utilized to toughen epoxy resin and to improve the bonding strength with the base surface of the glass fiber, thereby enhancing the overall performance of the glass fiber/carbon nanotube/epoxy resin multi-dimensional hybrid composite material and broadening the applications of the glass fiber, carbon nanotubes and epoxy resin.
Owner:TONGJI UNIV

Environment-friendly water-based static electricity conductive corrosion-resistant coating and preparation method thereof

The invention discloses an environment-friendly water-based static electricity conductive corrosion-resistant coating. The environment-friendly water-based static electricity conductive corrosion-resistant coating is prepared from the raw materials in percentage by weight: component A and nonionic water-based epoxy curing agent in the ratio of 100:(10-20), wherein the component A is prepared from raw materials in percentage by weight: 20-40 percent of nonionic water-based epoxy resin, 20-30 percent of static electricity conductive material, 5-10 percent of rutile type titanium dioxide, 5-10 percent of talcum powder, 3-5 percent of additive, 1-5 percent of nanocomposite preservative and 20-30 percent of water. The invention also discloses a preparation method for the environment-friendly water-based static electricity conductive corrosion-resistant coating. The environment-friendly water-based static electricity conductive corrosion-resistant coating has the characteristics of environment friendliness, light weight, color light, stable static electricity conductive performance, excellent preservative performance, mechanical property, chemical stability and the like. The environment-friendly water-based static electricity conductive corrosion-resistant coating can be widely applied to the fields of electronics, petroleum, ordnance industries and the like, is especially suitable for building inner walls having requirement on electrostatic protection, such as hospitals and electronicelectrical workshops and can provide an economic and environment-friendly scheme for solving the electrostatic protection in the indoor buildings.
Owner:KING STRONG MATERIAL ENG LTD +1

Method for preparing carbon nanofiber and carbon nanotube modified carbon fiber/epoxy resin multi-dimensional hybrid composite

InactiveCN101979436AImprove the shortcomings of insufficient interlaminar shear strength, etc.CurableFiberCarbon fibers
The invention belongs to the technical field of nano materials and particularly relates to a method for preparing a carbon nanofiber and carbon nanotube modified carbon fiber / epoxy resin multi-dimensional hybrid composite. The method comprises the following steps of: performing surface carboxylation and acylation treatment on carbon nanotubes, carbon nanofibers and carbob fibers; introducing diamine or polyamine to the obtained product; modifying amino carbon nanofibers and carbon nanotubes with an aromatic polyanhydride compound to prepare the carbon fibers, the carbon nanofibers and the carbon nanotubes carrying anhydride radicals; and ultrasonically oscillating the carbon nanofibers, the carbon nanotubes and the epoxy resin with the anhydride and stirring the mixed materials at a high speed to make the carbon nanofibers and the carbon nanotubes uniformly dispersed in the epoxy resin matrix and make the carbon nanofibers and the carbon nanotubes grafted with the anhydride and the epoxy resin fully undergo a chemical crosslinking reaction so as to obtain an epoxy resin linear block polymer, and combining the epoxy resin linear block polymer serving as a matrix and the carbon fibers to form multi-dimensional hybrid composite structures connected by covalent bonds. In the invention, by using the carbon nanotubes, the carbon nanofibers and the strength and toughness toughened epoxy resin, the bonding strength of carbon fiber interfaces is improved, so that the integral performance of the carbon fiber / epoxy resin multi-dimensional hybrid composite is improved, and the application range of the carbon fibers and the epoxy resin is widened.
Owner:TONGJI UNIV

Preparation method of carbon fiber/carbon nano tube/epoxy resin multi-dimensional hybrid composite

The invention belongs to the technical field of nano materials, and in particular relates to a preparation method of a carbon fiber/carbon nano tube/epoxy resin multi-dimensional hybrid composite. The invention comprises the following steps: carrying out surface carboxylation and chloride acetylation on carbon nano tubes and carbon fibers, introducing diamine or polyamine, and modifying the amino-grafted carbon nano tubes with small-molecule aromatic polyanhydride compounds to prepare carbon nano tubes carrying with anhydride groups; carrying out ultrasonic oscillation, stirring at a high speed to dispersing the carbon nano tubes in an epoxy resin matrix, and curing with organic anhydride curing agent to obtain an epoxy resin polymer containing carbon nano tubes; and using the epoxy resinpolymer containing the carbon nano tubes as the matrix for being compounded with the carbon fibers to form the covalently-bonded multi-dimensional hybrid composite structure. The invention has the advantage of convenient preparation; the carbon nano tubes are endued with activity for participating in the reaction, and the anhydride groups on the carbon nano tubes and the epoxy groups in the epoxyresin generate chemical crosslink, thereby promoting the dispersion of the carbon nano tubes in the epoxy resin; and the epoxy resin is toughened by using the strength and the toughness of the carbonnano tubes to enhance the bonding strength with the carbon fiber substrate, thus improving the overall performance of the carbon fiber/carbon nano tube/epoxy resin multi-dimensional hybrid composite,and widening the application of the carbon fibers, the carbon nano tubes and the epoxy resin.
Owner:TONGJI UNIV

Current collection component of anode supporting tube type solid oxide fuel cell and application thereof

The invention discloses a current collection component of an anode supporting tube type solid oxide fuel cell and an application thereof. The current collection component comprises a plate-like alloy base material and a protective coating coated to the surface of the base material surface and capable of inhibiting high temperature oxidation of alloy. Materials used to form the protective coating on the surface of the alloy base material comprise at least two oxide components: 40%-90% of composite oxide and 10%-60% of single oxide in molar percentage, wherein the composite oxide comprises one or more than two of oxides with perovskite structure, spinel structure, fluorite structure or wurtzite structure, and at least one composite oxide has the conductivity greater than 1 S/cm at 500-900 DEG C. A hole or groove throughout the plate body is arranged on the plate-like alloy base material, and one or more than two bulges or grooves are arranged in the axial direction on the surface of the alloy base material parallel to a tube type cell unit, and the shape of the bulges or grooves is matched with an external electrode or a ceramic connector on the tube type cell unit. The current collection component provided by the invention can simultaneously play the actions of supporting and connecting the fuel cell unit and collecting and conducting current, and has the advantages of high temperature oxidation resistance, good conductivity, high strength and toughness, easiness in cell stack assembly, etc. The invention also discloses a method for making the current collection component.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

High-strength steel plate for Q500GJE quenched and tempered building structure and manufacturing method of high-strength steel plate

ActiveCN110184525AGood brittle transition temperatureLower brittle transition temperatureImpact energyBainite
The invention relates to a high-strength steel plate for a Q500GJE quenched and tempered building structure. The high-strength steel plate comprises the following chemical components: less than or equal to 0.14% of C, 0.20%-0.50% of Si, 1.10%-1.60% of Mn, less than or equal to 0.015% of P, less than or equal to 0.005% of S, less than or equal to 0.20% of Cr, less than or equal to 0.30% of Mo, lessthan or equal to 0.90% of Ni+Mo, less than or equal to 0.30% of Cu, 0.02%-0.04% of Al, less than or equal to 0.20% of V+Nb+Ti, less than or equal to 0.006% of N, and the balance of Fe and inevitableimpurity elements, wherein the carbon equivalent is less than or equal to 0.52%. The yield strength is 545-585 MPa, the tensile strength is 670-715 MPa, and the elongation is larger than or equal to 18.5%. A high-strength steel product for a building, with the yielding-to-tensile ratio less than or equal to 0.84, and the V-type impact energy higher than or equal to 110 J at -40 DEG C, is of a ferrite+pearlite+bainite structure, and the grain size is 8.5 levels or above. The comprehensive performance can completely meet GB/T 19879-2015 and the clients' requirements of steel plates for high-risebuildings.
Owner:JIANGYIN XINGCHENG SPECIAL STEEL WORKS CO LTD

Steel for marine riser flange of marine deepwater drilling and manufacturing method of marine riser flange

InactiveCN102191442AImprove strength and toughnessMeet the technical requirements of low-carbon high-strength toughnessDrilling rodsDrilling casingsElectric arc furnaceDeepwater drilling
The invention discloses steel for a marine riser flange of marine deepwater drilling. The steel comprises the following components in percentage by weight: 0.13 to 0.21 percent of C, 1.65 to 1.95 percent of Mn, 0.25 to 0.35 percent of Mo, 0.03 to 0.09 percent of Nb, 0.02 to 0.08 percent of V, less than or equal to 0.015 percent of Ti, 0.5 to 0.9 percent of Ni, 0.07 to 0.2 percent of Cu, less than or equal to 0.15 percent of Cr, less than or equal to 0.22 percent of Si, less than or equal to 0.01 percent of S, less than or equal to 0.02 percent of P and the balance of Fe. The invention also discloses a manufacturing method of the marine riser flange of marine deepwater drilling. The method comprises the following steps of: preparing the materials according to the content of the components, and smelting the materials in an arc furnace to obtain molten steel, and heating the molten steel with arc in vacuum and stirring the molten steel by blowing argon to degas the molten steel; casting a steel ingot, blowing an inert gas through a blowing sliding water gap, balancing the components and the temperature and purifying the molten steel; forging the obtained steel ingot and annealing the steel ingot after forging; machining and polishing the steel ingot; and performing die forging on the steel ingot to obtain the finished product of the marine riser flange. By the manufacturing method, each mechanical property of the steel and the marine riser flange meets the requirements on API related steel for marine riser flange by setting the best component proportion and a heat treatment process.
Owner:BAOJI PETROLEUM MASCH CO LTD
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