The invention belongs to the technical field of nano materials and particularly relates to a method for preparing a
carbon nanofiber and
carbon nanotube modified carbon fiber /
epoxy resin multi-dimensional
hybrid composite. The method comprises the following steps of: performing surface
carboxylation and
acylation treatment on carbon nanotubes, carbon nanofibers and carbob fibers; introducing
diamine or
polyamine to the obtained product; modifying amino carbon nanofibers and carbon nanotubes with an aromatic polyanhydride compound to prepare the
carbon fibers, the carbon nanofibers and the carbon nanotubes carrying anhydride radicals; and ultrasonically oscillating the carbon nanofibers, the carbon nanotubes and the
epoxy resin with the anhydride and stirring the
mixed materials at a high speed to make the carbon nanofibers and the carbon nanotubes uniformly dispersed in the
epoxy resin matrix and make the carbon nanofibers and the carbon nanotubes grafted with the anhydride and the epoxy resin fully undergo a chemical crosslinking reaction so as to obtain an epoxy resin linear block
polymer, and combining the epoxy resin linear block
polymer serving as a matrix and the
carbon fibers to form multi-dimensional
hybrid composite structures connected by covalent bonds. In the invention, by using the carbon nanotubes, the carbon nanofibers and the strength and
toughness toughened epoxy resin, the
bonding strength of carbon
fiber interfaces is improved, so that the integral performance of the carbon
fiber / epoxy resin multi-dimensional
hybrid composite is improved, and the application range of the
carbon fibers and the epoxy resin is widened.