Soil heavy metal passivator and preparation method thereof
A heavy metal passivator and passivator technology, applied in chemical instruments and methods, soil conditioning materials, organic fertilizers, etc., can solve the problems of soil heavy metal pollution, nutrient loss, affecting the activity of antioxidant enzymes, etc., and achieve the maintenance of heavy metal pollution. , the effect of passivating heavy metals
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Embodiment 1
[0036] Embodiment 1: the preparation of soil heavy metal deactivator of the present invention
[0037] The composition of soil heavy metal deactivator: by weight percentage, chitosan 94%, glacial acetic acid 4%, water 2%.
[0038] Wherein, described chitosan is prepared through the following steps:
[0039] (1) Shrimp shells and / or crab shells are crushed to a particle size of 40 mesh;
[0040] (2) preparation concentration is the sodium hydroxide solution of 0.15mol / L;
[0041] (3) Mix 200 kilograms of shrimp shells and / or crab shell particles obtained in step (1) with 800 kilograms of sodium hydroxide solution obtained in step (2), and add 100,000 U / g of enzyme activity at 45° C. 3.3 kilograms of neutral protease and 1.7 kilograms of alkaline protease with enzyme activity of 100,000 U / g were cooled to normal temperature after 6 hours of reaction;
[0042] (4) At 40°C, 6 kg of calcium oxalate was added to 1005 kg of the mixed solution obtained in step (3), stirred, reacte...
Embodiment 2
[0046] Embodiment 2: the preparation of soil heavy metal deactivator of the present invention
[0047] The composition of the soil heavy metal deactivator: by weight percentage, chitosan 90%, glacial acetic acid 6%, water 4%.
[0048] Wherein, described chitosan is prepared through the following steps:
[0049] (1) Shrimp shells and / or crab shells are crushed to a particle size of 40 mesh;
[0050] (2) preparation concentration is the sodium hydroxide solution of 0.2mol / L;
[0051] (3) Mix 100 kilograms of shrimp shells and / or crab shell particles obtained in step (1) with 900 kilograms of sodium hydroxide solution obtained in step (2), and add 100,000 U / g of enzyme activity at 50° C. 2.7 kilograms of neutral protease and 1.3 kilograms of alkaline protease with enzyme activity of 100,000 U / g were cooled to normal temperature after 6 hours of reaction;
[0052] (4) At 45°C, 7 kg of calcium oxalate was added to 1004 kg of the mixed solution obtained in step (3), stirred, re...
Embodiment 3
[0056] Embodiment 3: the preparation of soil heavy metal deactivator of the present invention
[0057] The composition of the soil heavy metal deactivator: by weight percentage, chitosan 88%, glacial acetic acid 6%, water 6%.
[0058] Wherein, described chitosan is prepared through the following steps:
[0059] (1) Shrimp shells and / or crab shells are crushed to a particle size of 40 mesh;
[0060] (2) preparation concentration is the sodium hydroxide solution of 0.2mol / L;
[0061] (3) Mix 100 kilograms of shrimp shells and / or crab shell particles obtained in step (1) with 900 kilograms of sodium hydroxide solution obtained in step (2), and add 100,000 U / g of enzyme activity at 40° C. 2 kilograms of neutral protease and 1 kilogram of alkaline protease with enzyme activity of 100,000 U / g were cooled to normal temperature after 5 hours of reaction;
[0062] (4) At 50°C, 8 kg of calcium oxalate was added to 1003 kg of the mixed solution obtained in step (3), stirred, reacted...
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