Soil heavy metal passivator and preparation method thereof

A heavy metal passivator and passivator technology, applied in chemical instruments and methods, soil conditioning materials, organic fertilizers, etc., can solve the problems of soil heavy metal pollution, nutrient loss, affecting the activity of antioxidant enzymes, etc., and achieve the maintenance of heavy metal pollution. , the effect of passivating heavy metals

Active Publication Date: 2015-12-16
BEIJING LEILI MARINE BIOINDUSTRY INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In recent years, due to the backward level of ore dressing and smelting technology in mineral development, some mining areas have no environmental protection treatment equipment, and a large amount of waste is directly released into the environment without treatment, resulting in soil heavy metal pollution
Excessive use of chemical fertilizers and pesticides is also another cause of soil heavy metal pollution (although nitrogen and potassium fertilizers contain less heavy metals, but phosphorus fertilizers contain more heavy metals); in addition, the use of pesticides containing lead and organic mercury causes changes in the colloidal structure of the soil , nutrient loss, has a great adverse effect on the yield and quality of crops
[0005] Soil heavy metal pollution will first affect the growth and development of plants, and then affect the yield and quality of crops
For example, the combination of cadmium with sulfhydryl-containing amino acids and proteins will cause the inactivation of amino acids and proteins, and even lead to the death of plants. For example, Cd, through the formation of excessive oxygen free radicals, affects the activity of antioxidant enzymes in plants and destroys cell membrane systems, proteins, and nucleic acids. and other biological macromolecules, inhibiting the synthesis of rice chlorophyll and plant growth, and ultimately brought serious economic losses to the country

Method used

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  • Soil heavy metal passivator and preparation method thereof
  • Soil heavy metal passivator and preparation method thereof
  • Soil heavy metal passivator and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Embodiment 1: the preparation of soil heavy metal deactivator of the present invention

[0037] The composition of soil heavy metal deactivator: by weight percentage, chitosan 94%, glacial acetic acid 4%, water 2%.

[0038] Wherein, described chitosan is prepared through the following steps:

[0039] (1) Shrimp shells and / or crab shells are crushed to a particle size of 40 mesh;

[0040] (2) preparation concentration is the sodium hydroxide solution of 0.15mol / L;

[0041] (3) Mix 200 kilograms of shrimp shells and / or crab shell particles obtained in step (1) with 800 kilograms of sodium hydroxide solution obtained in step (2), and add 100,000 U / g of enzyme activity at 45° C. 3.3 kilograms of neutral protease and 1.7 kilograms of alkaline protease with enzyme activity of 100,000 U / g were cooled to normal temperature after 6 hours of reaction;

[0042] (4) At 40°C, 6 kg of calcium oxalate was added to 1005 kg of the mixed solution obtained in step (3), stirred, reacte...

Embodiment 2

[0046] Embodiment 2: the preparation of soil heavy metal deactivator of the present invention

[0047] The composition of the soil heavy metal deactivator: by weight percentage, chitosan 90%, glacial acetic acid 6%, water 4%.

[0048] Wherein, described chitosan is prepared through the following steps:

[0049] (1) Shrimp shells and / or crab shells are crushed to a particle size of 40 mesh;

[0050] (2) preparation concentration is the sodium hydroxide solution of 0.2mol / L;

[0051] (3) Mix 100 kilograms of shrimp shells and / or crab shell particles obtained in step (1) with 900 kilograms of sodium hydroxide solution obtained in step (2), and add 100,000 U / g of enzyme activity at 50° C. 2.7 kilograms of neutral protease and 1.3 kilograms of alkaline protease with enzyme activity of 100,000 U / g were cooled to normal temperature after 6 hours of reaction;

[0052] (4) At 45°C, 7 kg of calcium oxalate was added to 1004 kg of the mixed solution obtained in step (3), stirred, re...

Embodiment 3

[0056] Embodiment 3: the preparation of soil heavy metal deactivator of the present invention

[0057] The composition of the soil heavy metal deactivator: by weight percentage, chitosan 88%, glacial acetic acid 6%, water 6%.

[0058] Wherein, described chitosan is prepared through the following steps:

[0059] (1) Shrimp shells and / or crab shells are crushed to a particle size of 40 mesh;

[0060] (2) preparation concentration is the sodium hydroxide solution of 0.2mol / L;

[0061] (3) Mix 100 kilograms of shrimp shells and / or crab shell particles obtained in step (1) with 900 kilograms of sodium hydroxide solution obtained in step (2), and add 100,000 U / g of enzyme activity at 40° C. 2 kilograms of neutral protease and 1 kilogram of alkaline protease with enzyme activity of 100,000 U / g were cooled to normal temperature after 5 hours of reaction;

[0062] (4) At 50°C, 8 kg of calcium oxalate was added to 1003 kg of the mixed solution obtained in step (3), stirred, reacted...

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Abstract

The invention provides a soil heavy metal passivator. The soil heavy metal passivator comprises, in percentage by weight, 88%-94% of chitosan, 4%-6% of glacial acetic acid and 2%-6% of water. The chitosan can be combined with heavy metal in soil, the passivation function on the heavy metal in the soil is realized, the condition that crops absorb the heavy metal in the soil in the production period is prevented, and the crops are protected from pollution of the heavy metal.

Description

technical field [0001] The invention belongs to the technical field of soil improvement, in particular, the invention relates to a soil heavy metal passivator and a preparation method thereof. Background technique [0002] Soil is one of the main resources that human beings rely on for survival, and it is also an important part of the human ecological environment. However, with the intensification of air pollution and the increase in the types and quantities of agricultural chemicals, soil heavy metal pollution is becoming more and more serious. [0003] Heavy metals refer to metals with a specific gravity equal to or greater than 5.0 and an atomic weight greater than 40, such as Fe, Mn, Zn, Cd, Hg, Ni, Co, Pb, Cr, As, etc. Heavy metals in the soil refer to the entry of heavy metals into the soil due to human activities, which makes the soil heavy metals significantly higher than their original content, resulting in the deterioration of the ecological environment. [0004]...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K17/32A62D3/33C09K101/00A62D101/43
Inventor 汤洁严国富
Owner BEIJING LEILI MARINE BIOINDUSTRY INC
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