Refractory castable for blast furnace tapping trough and preparation method thereof

A technology of refractory castables and blast furnace iron tapping, which is applied in the field of refractory castables, can solve the problems of shortened service life, accelerated melting loss rate, intensified soaking erosion, etc., and achieves long service life, room temperature flexural strength and room temperature compressive strength Increase and improve the effect of volume stability

Active Publication Date: 2018-09-07
WUHAN UNIV OF SCI & TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Because the refractory materials used in the tap trough are directly scoured by the high temperature of molten iron and slag, mechanical wear and chemical erosion, and also affected by the comprehensive effects of sharp changes in temperature gradient or long-term high temperature (Hu Wenqiang, Wei Hangyu. No. 5 blast furnace iron in Handan Iron and Steel Gully erosion and production maintenance[J]. Nanfang Metallurgy. 2015(1):43-48), intensified the penetration and erosion of molten iron and slag into refractory materials, resulting in structural damage, accelerated melting loss rate, shortened service life, and reduced traffic flow. iron content
"Blast Furnace Tap Tunnel Castable" (CN102775165A) patented technology, the castable is composed of alumina, sintered tabular alumina, andalusite, alumina hollow balls, fused zirconia, alumina micropowder and ferrosilicon nitride, etc. Composition of raw materials, although this castable with bauxite as the main component has a lower melting loss rate and a longer service life than ordinary castables.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038]A refractory castable for a blast furnace tapping trough and a preparation method thereof. With 25~30wt% high alumina bauxite, 5~10wt% ferro-titanium alloy slag, 24~28wt% fused white corundum, 14~16wt% silicon carbide, 11~13wt% alumina micropowder, 4~5wt% % silica powder, 4~5wt% silica powder, 4~5wt% calcium aluminate cement and 2~3wt% spherical asphalt as raw materials, plus 0.01~0.03wt% FDN naphthalene-based water reducer , 0.03~0.06wt% sodium tripolyphosphate and 0.05~0.1wt% aluminum powder, dry mix for 1~2min, then add 4~4.5wt% water of the raw materials, and mix for 3~5min to get blast furnace Refractory castables for iron trenches.

[0039] The refractory castables for blast furnace tapping trough prepared in this example are tested after heat treatment at 110°C×24h and 1450°C×3h: the bulk density is 2.90~2.98g / cm 3 and 2.85~2.89g / cm 3 , the room temperature flexural strength is 8~12MPa and 9~14MPa, the room temperature compressive strength is 40~55MPa and 57~76...

Embodiment 2

[0041] A refractory castable for a blast furnace tapping trough and a preparation method thereof. With 20~25wt% high alumina bauxite, 10~15wt% ferro-titanium alloy slag, 32~36wt% fused white corundum, 10~12wt% silicon carbide, 7~9wt% alumina powder, 3~4wt% % silica powder, 2~3wt% silica powder, 3~4wt% calcium aluminate cement and 4~5wt% spherical asphalt as raw materials, plus 0.03~0.05wt% of the raw materials FDN naphthalene-based water reducer , 0.06~0.09wt% sodium tripolyphosphate and 0.1~0.15wt% aluminum powder, dry mix for 2~3min, then add 4.5~5wt% water of the raw materials, mix for 4~6min, that is blast furnace tapping Ditch with refractory castables.

[0042] The refractory castables for blast furnace tapping trough prepared in this example were tested after heat treatment at 110°C×24h and 1450°C×3h: the bulk density was 2.92~3.0g / cm 3 and 2.85~2.9g / cm 3 , the room temperature flexural strength is 8~13MPa and 10~16MPa, the room temperature compressive strength is 43...

Embodiment 3

[0044] A refractory castable for a blast furnace tapping trough and a preparation method thereof. With 15~20wt% high alumina bauxite, 15~20wt% ferro-titanium alloy slag, 28~32wt% fused white corundum, 12~14wt% silicon carbide, 9~11wt% alumina powder, 2~3wt% % silica powder, 3~4wt% silica powder, 2~3wt% calcium aluminate cement and 3~4wt% spherical asphalt as raw materials, plus 0.05~0.07wt% FDN naphthalene-based water reducer , 0.09~0.12wt% sodium tripolyphosphate and 0.15~0.2wt% aluminum powder, dry mix for 2~3min, then add 5~5.5wt% water of the raw materials, mix for 5~7min, and get blast furnace Refractory castables for iron trenches.

[0045] The refractory castables for blast furnace tapping trough prepared in this example are tested after heat treatment at 110°C×24h and 1450°C×3h: the bulk density is 2.91~3.0g / cm 3 and 2.86~2.9g / cm 3 , the room temperature flexural strength is 9~13MPa and 11~16MPa, the room temperature compressive strength is 45~57MPa and 55~75MPa; th...

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Abstract

The invention relates to a fireproof castable for producing blast furnace iron runners and a preparation method thereof. The castable is composed of the following raw materials in percentage by weight: 15 to 30 wt% of high-alumina bauxite, 5 to 20 wt% of titanium-iron alloy slag, 24 to 36 wt% of fused white corundum, 10 to 16 wt% of silicon carbide, 7 to 13 wt% of alumina micropowder, 2 to 5 wt% of silicon micropowder, 2 to 5 wt% of silicon powder, 2 to 5 wt% of calcium aluminate cement, and 2 to 5 wt% of spherical asphalt. The preparation method comprises the following steps: preparing the raw materials mentioned above, adding an FDN naphthalene water reducer accounting for 0.01 to 0.07 wt% of the total weight of raw materials, sodium tripolyphosphate accounting for 0.03 to 0.12 wt% of the total weight of raw materials, and aluminum powder accounting for 0.05 to 0.2 wt% of the total weight of raw materials, carrying out dry-mixing for 1 to 3 minutes, then adding water accounting for 4 to 5.5 wt% of the total weight of raw materials, and mixing for 3 to 7 minutes so as to obtain the fireproof castable. The provided fireproof castable has the characteristics of simple technology, low production cost, recyclable raw materials, and no special requirement on equipment, and has the advantages of stable volume, high strength, excellent corrosion resistant performance, and long service life.

Description

technical field [0001] The invention relates to a refractory pouring material. In particular, it relates to a refractory castable for a blast furnace tapping trough and a preparation method thereof. Background technique [0002] With the development of large-scale and long-life blast furnaces and the increase in ironmaking output of blast furnaces, the service life requirements for refractory materials used in blast furnaces are getting higher and higher. The blast furnace tapping trough is the channel that guides the high-temperature molten iron and slag to flow from the furnace to the molten iron tank through the tap hole. The performance of the castable for the tapping trough directly determines the service life of the tapping trough, thereby determining the production capacity and efficiency of the blast furnace. high and low. [0003] Because the refractory materials used in the tap trough are directly scoured by the high temperature of molten iron and slag, mechanica...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/66
Inventor 梁永和李晨晨赵惠忠冯立聂建华张寒乔婉尹玉成
Owner WUHAN UNIV OF SCI & TECH
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