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Carbonized silicone rubber cable material and preparation method thereof

A rubber cable and silicon carbide technology, applied in the direction of plastic/resin/wax insulators, organic insulators, etc., can solve the problems of carbon nanotubes dispersed carbon nanotubes, agglomeration, and few groups, and achieve firm interface, high hardness, The effect of high tensile strength

Inactive Publication Date: 2016-01-06
滁州君越高分子新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to achieve the purpose of enhancement, there are two problems to be solved: one is the dispersion of carbon nanotubes, and the other is the interface between carbon nanotubes and the matrix. Since the surface of carbon nanotubes is relatively inert and the specific surface area is relatively large, it is easy to cause agglomeration. Therefore, the effect of carbon nanotube-reinforced polymers is not very obvious." For this reason, many people began to physically or chemically treat carbon nanotubes. Among these methods, acid treatment to generate oxygen-containing groups is a common and efficient method. Yes, because it can provide effective / reactive sites to chemically bond with the matrix resin "However, in most cases, this method tends to produce too few groups to provide sufficient linkage to the matrix" so , in order to increase the number of reaction points, it is necessary to introduce more functional groups to interact with the matrix resin

Method used

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Embodiment Construction

[0021] A silicon carbide rubber cable material, which is made up of the following raw materials in parts by weight:

[0022] Silicone rubber 370, carbon nanotubes 50, acrylic acid 80, N,N' dicyclohexyl carboximide 80, 4 dimethylaminopyridine 7, tetrahydrofuran 300, silane coupling agent KH5501.3, 65wt% sulfuric acid 120, 95wt % nitric acid 100, ethyl cellulose 2, chlorinated paraffin 0.8, toluene 8, tetraethyl orthosilicate 30, ammonia water 2, vulcanizing agent double 254.

[0023] A kind of preparation method of described silicon carbide rubber cable material, comprises the following steps:

[0024] (1) Mix the above 65wt% sulfuric acid and 95wt% nitric acid, stir evenly, add carbon nanotubes, stir ultrasonically for 20 hours, condense and reflux at 120°C for 50 minutes, suction filter, wash with water, and dry to obtain acidified carbon nanotubes Tube;

[0025] (2) Mix the above-mentioned acidified carbon nanotubes, acrylic acid, N,N'dicyclohexylcarboimide, tetrahydrofura...

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PUM

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Abstract

The invention discloses a carbonized silicone rubber cable material. The cable material comprises the following raw materials in parts by weight: 370-400 parts of a silicone rubber, 50-60 parts of a carbon nanotube, 80-90 parts of acrylic acid, 80-100 parts of N,N'-dicyclohexylcarbodiimide, 7-10 parts of 4-dimethylaminopyridine, 300-460 parts of tetrahydrofuran, 1.3-2 parts of a silane coupling agent KH550, 120-150 parts of 65-68wt% sulfuric acid, 100-130 parts of 95-98wt% nitric acid, 2-4 parts of ethyl cellulose ethoce, 0.8-1 parts of chlorcosane, 8-10 parts of methylbenzene, 30-40 parts of ethyl orthosilicate, 2-3 parts of ammoniacal liquor, and 4-5 parts of 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane. The carbonized raw materials are compounded with silicone rubber to obtain the carbon-silicon composite material, and the composite material has good hardness and surface strength, and better resistance.

Description

technical field [0001] The invention relates to the technical field of cables, in particular to a silicon carbide rubber cable material and a preparation method thereof. Background technique [0002] Since carbon nanotubes can improve the mechanical properties, electrical properties and other properties of composite materials, carbon nanotube / rubber composites have attracted more and more attention. In order to achieve the purpose of enhancement, there are two problems to be solved: one is the dispersion of carbon nanotubes, and the other is the interface between carbon nanotubes and the matrix. Since the surface of carbon nanotubes is relatively inert and the specific surface area is relatively large, it is easy to cause agglomeration. Therefore, the effect of carbon nanotube-reinforced polymers is not very obvious." For this reason, many people began to physically or chemically treat carbon nanotubes. Among these methods, acid treatment to generate oxygen-containing groups...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/04C08K9/02C08K9/04C08K9/06C08K9/00C08K7/24C08K5/14H01B3/46
Inventor 任兆军
Owner 滁州君越高分子新材料有限公司