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Sulfur solidifying catalyst

A catalyst, titanium dioxide technology, applied in physical/chemical process catalysts, organic compound/hydride/coordination complex catalysts, solid fuels, etc., can solve the problems of ecological environment damage, atmospheric environmental pollution, etc., to reduce the amount of coal burning , reducing the effect of desulfurization and full combustion

Active Publication Date: 2016-01-20
张家界鸿燕新材料科技发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Harmful gases such as SO2 and NOx and soot emitted by coal combustion have caused great pollution to the atmospheric environment in my country and seriously damaged the ecological environment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A kind of sulfur-fixing catalyst, is made from following raw material and method:

[0020] (1) Weigh the following raw materials by weight: 280 parts of water, 250 parts of glycerol, 60 parts of sodium carbonate, 110 parts of sodium methacrylate, 130 parts of sodium gluconate, 120 parts of titanium dioxide, and 50 parts of triethanolamine. Titanium dioxide is a nano-titanium dioxide material obtained after modification.

[0021] (2) Add sodium carbonate, sodium methacrylate, and sodium gluconate to 3 / 4 of the water, and stir fully with a stirring tank for 1 hour to prepare a mixed solution A;

[0022] (3) Add titanium dioxide to the remaining 1 / 4 of the water and stir with a stirring tank for 30 minutes, then add glycerol and triethanolamine and stir for 1 hour to obtain dispersion B;

[0023] (4) Mix the mixed liquid A and the dispersion liquid B and stir them thoroughly for 30 minutes to prepare the sulfur-fixing catalyst.

Embodiment 2

[0025] A kind of sulfur-fixing catalyst, is made from following raw material and method:

[0026] (1) Weigh the following raw materials by weight: 300 parts of water, 280 parts of glycerol, 125 parts of sodium carbonate, 140 parts of sodium methacrylate, 200 parts of sodium gluconate, 135 parts of titanium dioxide, and 75 parts of triethanolamine.

[0027] （2） Add sodium carbonate, sodium methacrylate, and sodium gluconate to 3 / 4 of the water, and stir fully with a stirring tank for 50 hours to obtain a mixed solution A；

[0028] （3） Add titanium dioxide to the remaining 1 / 4 of the water and stir for 35 minutes with a stirring tank, then add glycerol and triethanolamine and stir for 70 hours to obtain a dispersion B；

[0029] （4） the mixture A with dispersion B Mix well and stir for 25 minutes to prepare a sulfur-fixing catalyst.

Embodiment 3

[0031] A kind of sulfur-fixing catalyst, is made from following raw material and method:

[0032] (1) Weigh the following raw materials by weight: 350 parts of water, 300 parts of glycerol, 115 parts of sodium carbonate, 150 parts of sodium methacrylate, 160 parts of sodium gluconate, 180 parts of titanium dioxide, and 80 parts of triethanolamine.

[0033] （2） Add sodium carbonate, sodium methacrylate, and sodium gluconate to 3 / 4 of the water, and stir fully with a stirring tank for 70 hours to obtain a mixed solution A；

[0034] （3） Add titanium dioxide to the remaining 1 / 4 of the water and stir for 25 minutes with a stirring tank, then add glycerin and triethanolamine and stir for 50 hours to obtain a dispersion B；

[0035] （4） the mixture A with dispersion B Mix and stir thoroughly for 35 minutes to obtain a sulfur-fixing catalyst.

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PUM

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Abstract

The invention provides a sulfur solidifying catalyst. The sulfur solidifying catalyst is prepared by mixing the following raw materials by weight percent: 20%-30% of glycerol, 5%-10% of sodium carbonate, 5%-15% of sodium methylallyl sulfonate, 8%-13% of sodium gluconate, 6%-15% of titanium dioxide, 2%-6% of triethanolamine and 25%-35% of water, wherein the sum of the weight percent of the raw materials is 100%. Titanium dioxide is modified to obtain nano titanium dioxide material. According to the sulfur solidifying catalyst, fire coals can be burned sufficiently, 10% or above dosages of fire coals can be reduced, the emission amount of sulfur dioxide can be reduced, 30% or above desulfurization amount can be achieved, and meanwhile, the emission amount of dust and harmful gas can be reduced.

Description

technical field [0001] The invention relates to a catalyst, in particular to a new high-efficiency sulfur-fixing catalyst which is composed of a composite functional surfactant with glycerol as a carrier and has the function of coal sulfur-fixing and denitrification. Background technique [0002] Coal is the most important energy source in my country, accounting for 70% of the total energy consumption. Although my country's coal resources are quite rich, in terms of coal quality, there are many difficult-to-separate coals in my country, and the proportion of high-ash and high-sulfur coal is large. Medium-high-sulfur coal and high-sulfur coal with a sulfur content of more than 2% in coal account for about 1 / 3 of the total reserves. Harmful gases such as SO2 and NOx and soot emitted by coal burning have caused great pollution to the atmospheric environment of our country and seriously damaged the ecological environment. [0003] The coal catalyst is a lipophilic substance, an...

Claims

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Application Information

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IPC IPC(8): B01J31/38B01J35/12C10L9/10C10L10/00C10L10/02
Inventor 张桂燕
Owner 张家界鸿燕新材料科技发展有限公司
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