Preparation method of an odorless, highly dispersible sludge calcium polypeptide mixture and its application in shale sintered bricks

A high-dispersity, sintered brick technology, applied in applications, water pollutants, sludge treatment, etc., can solve problems such as difficulty in dispersion, affect the living environment of surrounding residents, and affect the quality of sintered bricks, and achieve the effect of high dispersion.

Active Publication Date: 2017-09-01
HUBEI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] At present, although the process of preparing sintered bricks from sludge shale seems to be feasible, the reason why it has not been popularized and applied is that there are several serious problems in this process: 1. The production process, the factory area and its surrounding environment have stench, and the production workers and surrounding areas residents can not afford
2. There are technical bottlenecks in the process
Sludge is mainly composed of microorganisms, silt, unknown organic and inorganic substances, and its particles are relatively coarse and poorly dispersed. Because sludge is a colloidal substance, it has the ability to coagulate and aggregate, and is usually in the form of agglomerates or blocks. It is difficult to disperse after stirring. When sludge is added to crushed shale, it is difficult to mix the two evenly, resulting in large holes and rough surfaces in the fired bricks, which will affect the quality of fired bricks.
3. Cost issues
There are many defects in this patent: on the one hand, the preparation of municipal sludge powder is a very energy-consuming process. Although the sludge is dried, the protein contained in it is not removed or transformed and decomposed, and the odorous substances are not destroyed. The process of natural drying and heating drying has stench, which is unbearable for operators; on the other hand, sludge bricks containing a large amount of protein and having stench will produce odorous substances that seriously pollute the air during the sintering process, including ammonia smell, hydrogen sulfide, etc. , skatole, methyl sulfide and other odors seriously affect the living environment of the surrounding residents, making residents uninhabitable
Therefore, based on the limitations of the above factors, the process of directly using sludge and shale to prepare sintered bricks is still not suitable for large-scale industrial application.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A kind of preparation method of odorless, highly dispersible sludge calcium polypeptide mixture, described method comprises the steps:

[0032] Put 3000kg of wet sludge with water content of 80% in the sewage treatment plant into 5m 3 In the high temperature reaction kettle, add 180kg of calcium oxide powder, and then inject 1000kg (1m 3 ) water to disperse the calcium oxide powder, then stir and mix evenly, then directly pass in 0.7Mpa water vapor, heat to 165°C, keep warm for 1.5h, take a sample from the beaker and observe, if there is no odor and the solid and liquid parts have been separated , which means that the reaction is complete, and cooled to normal temperature to obtain the odorless, highly dispersible sludge calcium polypeptide mixture.

[0033] After the reaction is over, the prepared mixture can be passed through 80m by using the residual gas pressure of the reaction process. 2 The plate and frame filter is used for filtering, the filter residue and the...

Embodiment 2

[0035] A kind of preparation method of odorless, highly dispersible sludge calcium polypeptide mixture, described method comprises the steps:

[0036] Add 150kg of quicklime powder to the wall oil heating reactor, and then inject 600kg (0.6m 3 ) water, used to disperse quicklime powder, using the air generated by the air compressor to stir the lime into a lime emulsion, and then put 3000kg of sludge from a sewage treatment plant with a water content of 80% into the reactor, so that the inner wall of the reactor is in the The lime emulsion medium is in contact with the state, and then indirectly heat the sludge mixture in the reactor through the heating oil in the partition wall. The heating rate is 1-3°C / min. Before the temperature rises to 100°C, pause for 5-8 hours after every 10-30 minutes of heating. Minutes, in order to avoid the organic matter of the sludge in the carbonization reaction kettle to produce odor and smoke. When heated to 100°C, the sludge has been completel...

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Abstract

The invention discloses a preparation method of an odorless and high-dispersity sludge and calcium polypeptide mixture as well as an application of the mixture in a shale sintering brick, and belongs to the technical field of treatment and reclamation utilization of sludge. The odorless and high-dispersity sludge and calcium polypeptide mixture is prepared by adding a certain amount of calcium oxide or quicklime and an appropriate amount of water into the sludge of an urban domestic sewage treatment factory, heating to 155-185 DEG C, holding for 0.5-6.5 h and then cooling to the room temperature. According to the method, the sludge is subjected to alkaline conversion at high temperature, no odor is diffused into ambient air in a whole preparation process, and air pollution influencing a living environment of residents around a production factory cannot be caused. The sludge and calcium polypeptide mixture prepared by the method is admixed into a shale grinding raw material in proportion to prepare the sintering brick; in a process of preparing the shale sintering brick, a green brick is odorless in a natural drying process, a heat drying process and a sintering process; the prepared sintering brick is light in weight, smooth and clean; and the performance of the sintering brick such as compression resistance and fracture resistance meets national standards.

Description

technical field [0001] The invention belongs to the technical field of sludge treatment and resource utilization, and in particular relates to the sludge treatment and utilization of urban domestic sewage treatment plants. More specifically, the invention relates to an odorless, highly dispersible sludge calcium polypeptide mixture The preparation method and its application in shale sintered bricks. Background technique [0002] With the development of modern urbanization, the discharge of urban sewage in my country has increased sharply, and the sewage treatment volume and sludge production of sewage treatment plants have also increased day by day. Sludge is a porous medium material with high water content and complex composition. In addition to containing a large amount of water, there are also bacterial micelles formed by various microorganisms and aggregates composed of organic and inorganic substances adsorbed, organic matter, pathogenic microorganisms, Heavy metals, s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F11/14C02F11/00C02F101/32C04B33/132C04B28/12C04B18/30C04B24/14
CPCY02P40/60Y02W30/91
Inventor 李亚东蹇守卫王行国杨兰芳倪红李龙盘周姍娜李顺意李海波
Owner HUBEI UNIV
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