Modification and use methods for straw biomass

A technology of biomass and biomass materials, applied in the field of new materials and straw plastic products, can solve the problems of reducing the strength of composite materials, affecting the plasticity of straw biomass, and the complexity of straw ultrastructure, and achieve the effect of reducing the use

Inactive Publication Date: 2016-02-10
NANJING UNIV OF TECH
View PDF6 Cites 25 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, the patent application with application number 200410021704.3 uses 100 parts of high-pressure polyethylene with a ratio of 10-60 parts of heavy calcium powder to prepare modified plastics, which have the characteristics of wear resistance, impact resistance and anti-aging, but this patent does not add straw powder
The patent application with the application number 200610030671.8 uses ultra-fine wood powder, ultra-fine ore powder and waste plastics to melt and stir to form products directly, but this patent does not form modified straw powder materials, but directly produces finished products
The patent application with application number 201310029919.9 injects montmorillonite suspension into wood powder to strengthen wood powder, improve the interfacial compatibility of wood-plastic composite materials, and improve the use efficiency of wood powder. However, wood-plastic products need to be dried during the production process. Obviously, it does not match the plasticity characteristics pursued by straw plastic materials
[0004] The main problems facing the development of straw-plastic materials to replace wood-plastic materials at full price are: first, straw has a porous structure, and the total bulk density is about 0.4, while the total bulk density of plastic is about 1.0; second, the ultra-microstructure of straw Complexity emerges, especially the presence of hydrophilic groups affects the plasticity of straw biomass
Due to the above reasons, when straw powder is mixed with the plastic base material, it is easy to separate and agglomerate with the plastic base material, resulting in the destruction of the internal order structure of the plastic, which may reduce the strength of the composite material.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Select rice straw, use mechanical equipment to crush to 80 mesh, and dry until the water content is 4%; in the high mixer, first add 48 parts of the above-mentioned treated rice straw powder, heat and dry, heat up to 90°C, and rotate at 360~410r / min, keep 10min; then add 48 parts of commercial quartz powder, 300 mesh, water content is 6%; turn on the negative pressure function, the relative vacuum degree reaches -0.096MPa, the temperature is 115℃, the speed is 420~560r / min, start mixing . During the mixing process, 3 parts of caprolactam and 1 part of silane coupling agent were sequentially added, and mixed for 20 minutes to obtain modified rice straw powder. The experiment shows that the moisture absorption rate of the modified straw powder is 16.53%, and the moisture absorption rate of the unmodified rice straw powder is 22.45%, and the hygroscopicity decreases.

Embodiment 2

[0028] Wheat straw was crushed to 250 mesh and dried to a moisture content of 10%; commercial calcium carbonate powder of 1600 mesh was selected with a moisture content of 12%; based on 100 parts of wheat straw powder, the amount of calcium carbonate powder was 300 parts. Heat and dry the wheat straw powder in the high-mixer first, raise the temperature to 110°C, and keep it for 10 minutes, then add the above-mentioned commercial calcium carbonate powder, and perform high-speed mixing under negative pressure. During the mixing process, add maleic anhydride and 2.5 parts each of isocyanate coupling agent, heated to 130°C; mixed for 15 minutes to obtain modified wheat straw powder. The experiment shows that the moisture absorption rate of the modified straw powder is 16.89%, and the moisture absorption rate of the unmodified wheat straw powder is 23.02%, and the hygroscopicity decreases.

Embodiment 3

[0030] Add 40 parts of modified straw powder and 57 parts of polyethylene in Implementation 1 into the plastic internal mixer at a speed of 2490 rpm. During the mixing process, add 1.5 parts of paraformaldehyde and 1.5 parts of dioctyl phthalate in sequence, and keep mixing 15min; blend and melt the above-mentioned processed mixture through a twin-screw extruder, the working temperature is 140°C~210°C during the extrusion process, chop the extruded mixture into 4-6mm straw plastic masterbatch, and dry When the water content reaches 4-7%, the straw-plastic composite masterbatch is obtained. The obtained modified straw powder is compounded with polyethylene to make a modified plastic masterbatch, and the straw-plastic dinner plate is successfully prepared, which can be reused more than 6 times.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
particle sizeaaaaaaaaaa
water contentaaaaaaaaaa
Login to view more

Abstract

The invention discloses a straw-derived composite material, i.e., proper-plasticity modified straw biomass obtained through carrying out modification on straw powder by using ore powder and adjuvants, new materials formed through further compounding the modified straw biomass and plastics and a method for producing straw-plastics products by using the new materials. According to the method, firstly, the straw biomass is crushed to certain fineness, then, the straw biomass powder is mixed with the ore powder in the presence of an esterifying agent and a coupling agent so as to form modified straw powder, and the modified straw powder is further compounded with the plastics in the presence of the adjuvants such as a grafting agent so as to form the new materials, which replace wood-plastics and plastics, and new products.

Description

technical field [0001] The invention belongs to the fields of agriculture and plastic industry, and specifically relates to a straw-sourced composite material, that is, to modify the straw powder with ore powder and additives to obtain a plastic-adaptive modified straw powder, and to further combine the modified straw powder with plastics. New materials and straw plastic products formed by compounding. Background technique [0002] Straw biomass has a huge stock, which is both a waste and a resource, so it has a wide range of application potential. However, no matter using straw to make biogas or process pulp, it will bring waste residue and liquid, leading to "waste from waste". It is of great significance to utilize straw biomass at full price or to utilize waste residue (ash) in the process of straw processing. Straw biomass instead of lignocellulose to prepare straw plastic products is one of the ways to solve the above problems. [0003] In view of the fact that the ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L97/02C08L23/06C08L69/00C08L59/04C08K13/02C08K3/36C08K3/26C08K5/3412C08K5/1539C08K5/12
CPCC08K3/26C08K3/36C08K5/12C08K5/1539C08K5/3412C08K13/02C08L23/06C08L59/04C08L69/00C08L97/02
Inventor 陈集双张文涛蒋海侠陈锦周邓归阁王耀东金磊磊
Owner NANJING UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products