Modification and use methods for straw biomass
A technology of biomass and biomass materials, applied in the field of new materials and straw plastic products, can solve the problems of reducing the strength of composite materials, affecting the plasticity of straw biomass, and the complexity of straw ultrastructure, and achieve the effect of reducing the use
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Embodiment 1
[0026] Select rice straw, use mechanical equipment to crush to 80 mesh, and dry until the water content is 4%; in the high mixer, first add 48 parts of the above-mentioned treated rice straw powder, heat and dry, heat up to 90°C, and rotate at 360~410r / min, keep 10min; then add 48 parts of commercial quartz powder, 300 mesh, water content is 6%; turn on the negative pressure function, the relative vacuum degree reaches -0.096MPa, the temperature is 115℃, the speed is 420~560r / min, start mixing . During the mixing process, 3 parts of caprolactam and 1 part of silane coupling agent were sequentially added, and mixed for 20 minutes to obtain modified rice straw powder. The experiment shows that the moisture absorption rate of the modified straw powder is 16.53%, and the moisture absorption rate of the unmodified rice straw powder is 22.45%, and the hygroscopicity decreases.
Embodiment 2
[0028] Wheat straw was crushed to 250 mesh and dried to a moisture content of 10%; commercial calcium carbonate powder of 1600 mesh was selected with a moisture content of 12%; based on 100 parts of wheat straw powder, the amount of calcium carbonate powder was 300 parts. Heat and dry the wheat straw powder in the high-mixer first, raise the temperature to 110°C, and keep it for 10 minutes, then add the above-mentioned commercial calcium carbonate powder, and perform high-speed mixing under negative pressure. During the mixing process, add maleic anhydride and 2.5 parts each of isocyanate coupling agent, heated to 130°C; mixed for 15 minutes to obtain modified wheat straw powder. The experiment shows that the moisture absorption rate of the modified straw powder is 16.89%, and the moisture absorption rate of the unmodified wheat straw powder is 23.02%, and the hygroscopicity decreases.
Embodiment 3
[0030] Add 40 parts of modified straw powder and 57 parts of polyethylene in Implementation 1 into the plastic internal mixer at a speed of 2490 rpm. During the mixing process, add 1.5 parts of paraformaldehyde and 1.5 parts of dioctyl phthalate in sequence, and keep mixing 15min; blend and melt the above-mentioned processed mixture through a twin-screw extruder, the working temperature is 140°C~210°C during the extrusion process, chop the extruded mixture into 4-6mm straw plastic masterbatch, and dry When the water content reaches 4-7%, the straw-plastic composite masterbatch is obtained. The obtained modified straw powder is compounded with polyethylene to make a modified plastic masterbatch, and the straw-plastic dinner plate is successfully prepared, which can be reused more than 6 times.
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