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High-chlorine raw material catalytic conversion method

A catalytic conversion method and raw material technology, applied in the field of catalytic cracking for processing high-chlorinated hydrocarbon oil raw materials, can solve the problems of inability to achieve dechlorination effect, equipment corrosion environment, low adsorption capacity, etc., to improve product selectivity and reduce dry gas The effect of improving yield and conversion rate

Active Publication Date: 2016-03-02
CHINA PETROLEUM & CHEM CORP +1
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Problems solved by technology

[0010] When the content of organic chloride in the raw material is high, the above-mentioned electric desalination method still cannot achieve the ideal dechlorination effect. Although the process of removing chloride by adsorption is simple, the selectivity of the adsorbent is poor, the adsorption capacity is low, and the regeneration cycle of the adsorbent The problem of utilization is difficult to solve. Hydrogenation is an ideal technical route for removing organic chlorides. The problem with this method is that the equipment investment and operating costs are high, and it may cause equipment corrosion and environmental pollution.

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Embodiment approach

[0060] According to one embodiment of the present invention, when the method of the present invention is carried out in riser reactor, generally carry out as follows:

[0061] The high-temperature regenerated catalyst enters the pre-lift section of the riser reactor, and flows upward under the action of the pre-lift medium into the oil agent initial contact reaction zone at the lower part of the riser reactor. The preheated high-chlorine raw material enters the oil from the lower part of the riser reactor In the initial contact reaction zone of the agent, it contacts, reacts and goes up with the high-temperature regenerated catalyst; the formed oil mixture enters the main reaction zone of the riser, where the hydrocarbon conversion reaction continues, and the reaction product flows through the riser reactor The outlet enters the cyclone separator, and the separated reaction oil and gas extraction device is further separated to obtain fractions such as dry gas, liquefied gas, ga...

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Abstract

The invention relates to a high-chlorine raw material catalytic conversion method, wherein a high temperature regeneration catalyst enters the pre-rising section on the lower portion of a riser reactor, flows upward under the effect of a pre-rising medium, and then enters the oil agent initial contact reaction region on the lower portion of the riser reactor, a pre-heated high-chlorine raw material is introduced into the lower portion of the oil agent initial contact reaction region, the pre-heated high-chlorine raw material and the high temperature regeneration catalyst contact, react and rise, the formed oil agent mixture enters a riser main reaction region, a hydrocarbon conversion reaction is continuously performed in the main reaction region, the formed oil agent mixture is subjected to gas-solid separation through the reactor outlet, the separated catalyst with charcoal is subjected to steam stripping and charring so as to be recycled, and the separated reaction oil gas is conveyed to the subsequent product separation system. According to the present invention, with the method, the high-chlorine raw material can be directly processes, the high-chlorine raw material conversion rate is improved, and the product selectivity is improved; and the method is simple and is easy to perform, and the method can be achieved only by carrying out simple transforming on the conventional catalytic cracking equipment.

Description

technical field [0001] The invention belongs to a catalytic cracking method of hydrocarbon oil without hydrogen, more specifically, belongs to a catalytic cracking method of processing high-chlorinated hydrocarbon oil raw material without hydrogen. Background technique [0002] my country's oil resources are relatively short. In 2012, the Swiss Bank issued a report on the status quo of the global oil field. It pointed out that China's oil reserves are about 15 billion barrels, accounting for 1.1% of the world's oil reserves, which is only enough for 10 years. The trend of poor quality of crude oil is becoming more and more serious all over the world. Especially in the past ten years, water injection production has been the main method. The application of various oil recovery and transportation technologies has made the components of crude oil and reinjected water complex, which not only causes difficulties in the treatment of crude oil and sewage, but also Moreover, it has a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G29/00C10G29/02C10G29/04C10G29/06
Inventor 龙军魏晓丽
Owner CHINA PETROLEUM & CHEM CORP
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