Acid pickling assistant for removing residual thick-layer black oil spots on cold-drawn steel pipe and preparing method

A technology of oil spot acid and washing auxiliaries, which is applied in the field of removing thick layer black oil spot acid washing auxiliaries and preparation of cold-drawn steel pipes, can solve the problems of not being able to remove them, affecting the production of high-end furniture, etc., to ensure product quality Effect

Inactive Publication Date: 2016-03-23
DALIAN SANDAAOKE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the equipment and process of drawing pipes, a large number of thick black oil spots will remain on the surface of steel pipes produced by individual enterprises, which cannot be removed by the existing pickling and degreasing steps, which directly affect the steel structure and Production of high-end furniture such as stainless steel structures

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0008] The raw materials and mass percentages used are as follows: mass concentration 98% sulfuric acid 50%, mass concentration 50% hydrofluoric acid 2%, methanesulfonic acid 5%, mass concentration 85% phosphoric acid 2%, oxalic acid%, oleic acid 2%, tartaric acid 3% %, urotropine 0.5%, QYL-211A three-in-one surfactant for degreasing, degreasing, derusting and inhibiting acid mist 3.5%, QYL-290 decarbonization surfactant 1.5%, JFC 3.5%, the balance of tap water .

[0009] The preparation method is carried out according to the following steps: first add the calculated and weighed tap water into the reaction kettle, start the agitator, and control the rotation speed at 60-80 rpm, and then sequentially add the calculated and weighed tartaric acid, oxalic acid, and urotropine Add to the reaction kettle, stir while adding to make it fully dissolved, and then sequentially add the calculated and weighed phosphoric acid, oleic acid, methanesulfonic acid, hydrofluoric acid, QYL-211A ac...

Embodiment 2

[0012] The raw materials and mass percentages used are as follows: mass concentration 98% sulfuric acid 30%, mass concentration 50% hydrofluoric acid 5%, methanesulfonic acid 2%, mass concentration 85% phosphoric acid 5%, oxalic acid 2%, oleic acid 5%, tartaric acid 1%, urotropine 1.5%, QYL-211A three-in-one surfactant for degreasing, degreasing, derusting and inhibiting acid mist 1.5%, QYL-290 decarbonizing surfactant 3.5%, JFC 1.5%, tap water quantity.

[0013] Raw material source and production method are with embodiment 1.

Embodiment 3

[0015] The raw materials and mass percentages used are as follows: mass concentration 98% sulfuric acid 40%, mass concentration 50% hydrofluoric acid 3%, methanesulfonic acid 4%, mass concentration 85% phosphoric acid 3%, oxalic acid 4%, oleic acid 3%, tartaric acid 2%, urotropine 1%, QYL-211A three-in-one surfactant for degreasing, degreasing, derusting and inhibiting acid mist 2%, QYL-290 decarbonization surfactant 2%, JFC 2%, the balance of tap water.

[0016] Raw material source and production method are with embodiment 1.

[0017] When in use, according to the residual degree of black oil spots on the surface of the drawn steel pipe, the stock solution of Example 1, 2 or 3 of the present invention is added to the existing pickling and degreasing two-in-one working solution in a proportion of 5-15% by mass , Under normal temperature conditions, it can completely remove rust, oil and black oil spots in 15-30 minutes.

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PUM

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Abstract

The invention discloses an acid pickling assistant for removing residual thick-layer black oil spots on a cold-drawn steel pipe. The acid pickling assistant comprises, by mass percent, 30%-50% of sulfuric acid with the mass concentration being 98%, 2%-5% of hydrofluoric acid with the mass concentration being 50%, 2%-5% of methanesulfonic acid, 2%-5% of phosphoric acid with the mass concentration being 85%, 2%-5% of oxalic acid, 2%-5% of oleic acid, 1%-3% of tartaric acid, 0.5%-1.5% of urotropin, 1.5%-3.5% of a QYL-211A acid degreasing, oil removing and rust removing restraining acid mist three-in-one surfactant, 1.5%-3.5% of a QYL-290 deposition carbon removing surface active agent, 1.5%-3.5% of JFC and the balance tap water. An existing production line does not need to be changed, the acid pickling assistant only needs to be added into an existing out-line line acid washing and oil removing two-in-one bath solution, the residual thick-layer black oil spots on the cold-drawn steel pipe can be rapidly and thoroughly peeled, and the product quality is guaranteed.

Description

technical field [0001] The invention relates to a pickling aid for metal workpieces, in particular to a pickling aid for removing thick black oil spots remaining on cold-drawn steel pipes and a preparation method thereof, which can quickly and thoroughly strip off the thick-layer black oil spots remaining on cold-drawn steel pipes. Background technique [0002] The raw materials used for high-end furniture with steel and stainless steel structures are cold-drawn pipes of various specifications. Usually, degreasing, silane pottery and other treatments are performed before surface spraying and coating. The specific process flow is outside the line: acid Washing and degreasing two-in-one→water washing→neutralization→rust prevention between processes; inside wires: degreasing→degreasing→water washing→water washing→silane vitrification→water washing→solid film→drying→electrostatic powder spraying, outside wires and inside wires All are operated at room temperature. However, due ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23G1/08
CPCC23G1/088
Inventor 潘德顺朱国玉王剑黄文飞郑力玮李文瀚
Owner DALIAN SANDAAOKE CHEM
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