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A kind of pbt plastic and its preparation process

A preparation process and technology for plastics, applied in the field of PBT plastic and its preparation, can solve the problems of decreased mechanical properties of PBT plastics, poor safety performance, poor flame retardancy, etc., and achieve good fatigue resistance and dimensional stability, good flame retardant effect, The effect of high mechanical strength

Active Publication Date: 2018-02-16
东莞市立晶塑胶有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The technical problem to be solved by the present invention is to provide a PBT plastic and its preparation process, which solves the problem that the traditional PET plastic has poor flame retardancy, is easy to ignite when it is applied to fields such as electronic appliances, and has poor safety performance. At the same time, Traditional PBT plastics use titanium dioxide as the white pigment. After adding titanium dioxide, the mechanical properties of PBT plastics will drop significantly.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Mix 100kg polybutylene terephthalate (PBT), 60kg polyethylene terephthalate (PET), 25kg terephthalic acid, 13kg magnesium hydroxide, 13kg aluminum hydroxide to form a mixture M ; The mixture M and 17kg of glass fiber are mixed and sent into a twin-screw extruder for extrusion and granulation. The temperature of the extruder is controlled at 200° C., and the rotating speed of the screw is 200 rpm to obtain pellets; the pellets are baked at 230° C. Bake for 20 minutes to form a molten PBT slurry, add 2kg of dibutyltin and send it to the esterification reactor, and carry out the esterification reaction at a temperature of 260°C and a pressure of 10KPa for 20 minutes to obtain the PET esterification product N; the PET esterification product N and 5 kg of zinc sulfide were mixed and sent to an injection molding machine for injection molding. The injection molding temperature was 200° C. and the injection molding pressure was 70 MPa. After cooling, the PET plastic was obtained...

Embodiment 2

[0019] Example 2 Mix 100kg polybutylene terephthalate (PBT), 70kg polyethylene terephthalate (PET), 30kg terephthalic acid, 17kg magnesium hydroxide, and 17kg aluminum hydroxide, The mixture M is formed; the mixture M is mixed with glass fibers and sent to a twin-screw extruder for extrusion and granulation. The temperature of the extruder is controlled at 230°C, and the rotation speed of the screw is 280rpm to obtain pellets; the pellets are heated at 250°C Bake under low temperature for 40min to form a molten PBT slurry, add 3kg of stannous octoate and send it into the esterification reactor, and carry out the esterification reaction at a temperature of 300°C and a pressure of 30KPa for 35min to obtain the PET esterification product N; PET Esterification product N was mixed with 7 kg of zinc sulfide, and sent to an injection molding machine for injection molding at an injection temperature of 245° C. and an injection pressure of 85 MPa. After cooling, the PBT plastic was obta...

Embodiment 3

[0021] Mix 100kg polybutylene terephthalate (PBT), 65kg polyethylene terephthalate (PET), 27kg terephthalic acid, 15kg magnesium hydroxide, 15kg aluminum hydroxide to form a mixture M ; The mixture M and 19kg of glass fibers are mixed and sent into a twin-screw extruder for extrusion and granulation. The temperature of the extruder is controlled at 210° C., and the rotating speed of the screw is 250 rpm to obtain pellets; the pellets are baked at 240° C. Bake for 30 minutes to form a molten PBT slurry, add 2.5kg of triphenyltin and send it into the esterification reactor, and carry out the esterification reaction at a temperature of 275°C and a pressure of 15KPa for 28 minutes to obtain PET esterification product N; The PET esterification product N was mixed with 6 kg of zinc sulfide, and fed into an injection molding machine for injection molding. The injection molding temperature was 230° C., and the injection molding pressure was 77 MPa. After cooling, the PBT plastic was ob...

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PUM

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Abstract

The invention discloses a PBT plastic and a preparation process thereof, wherein the preparation process comprises: uniformly mixing PBT, PET, terephthalic acid, magnesium hydroxide, and aluminum hydroxide to form a mixture M; mixing the mixture M with glass After the fibers are mixed, they are sent to a twin-screw extruder for extrusion and granulation to obtain pellets; the pellets are baked at 230-250°C for 20-40 minutes to form a molten PBT slurry, which is sent to the esterification reactor after adding a catalyst , carry out the esterification reaction at a temperature of 260-300°C and a pressure of 10-30KPa to obtain a PET esterification product N; mix the PET esterification product N with zinc sulfide, and send it to an injection molding machine for injection molding, and after cooling, the obtained The PET plastic. It solves the problem that traditional PET plastics have poor flame retardancy, are easy to ignite when used in electronic appliances and other fields, and have poor safety performance. At the same time, traditional PBT plastics use titanium dioxide as a white pigment. After adding titanium dioxide, PBT plastics There will be a problem of a relatively large decline in mechanical properties.

Description

technical field [0001] The invention relates to the field of plastic preparation, in particular to a PBT plastic and a preparation process thereof. Background technique [0002] PBT is a thermoplastic, semi-crystalline saturated polyester, which has many advantages such as high strength, excellent aging resistance and heat resistance, good dimensional stability, extremely low water absorption, good electrical insulation, etc. It has become the fifth largest general-purpose engineering plastic in the world after polyamide, polycarbonate, polyoxymethylene and polyphenylene ether, and has been widely used in many industries such as automobile industry, mechanical equipment, and electronic appliances. However, traditional PET plastics have poor flame retardancy, and when used in electronic appliances and other fields, they are easy to ignite and have poor safety performance. White is the most commonly used color matching for PBT products. Titanium dioxide is usually used as the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/02C08K13/04C08K7/14C08K3/22C08K3/30C08K5/092
Inventor 李莉玲
Owner 东莞市立晶塑胶有限公司
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