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High-hardness polyurethane elastomer pressure-bearing support material for bridge and preparation method and using method thereof

A polyurethane elastomer and high hardness technology, which is applied in the field of polyurethane elastomer pressure-bearing bearing materials for bridges and its preparation, can solve the problems of intensifying cross-linking side reactions, speeding up the reaction speed, and losing the main chain reaction, so as to reduce the use of Quantity, reduce the frequency of replacement, improve the effect of bearing capacity

Active Publication Date: 2016-04-06
LIMING RES INST OF CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But this method will cause two problems: first, increasing the hard segment content will speed up the reaction speed, the curing speed is too fast, and manual operation cannot be performed; Gel, which intensifies the cross-linking side reaction, loses the chance of part of the main chain reaction, causes the strength to decrease, and the material becomes brittle

Method used

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  • High-hardness polyurethane elastomer pressure-bearing support material for bridge and preparation method and using method thereof
  • High-hardness polyurethane elastomer pressure-bearing support material for bridge and preparation method and using method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Component A: Dehydrate 400gPPG (number average molecular weight: 2000) at 100-110°C for 2h under a vacuum of 0.1MPa, cool down to 50°C, add 112gIPDI, react at 80-85°C for 2h under nitrogen protection, and cool down to 60°C Then add 20g of butanediol, 20g of dipropylene glycol and 157g of toluene diisocyanate T-80 and continue the reaction at 80-85°C for 2h to obtain a prepolymer component.

[0029] Component B: Dimethylthiotoluenediamine

[0030] Preparation of the pressure-bearing support: Add 0.62 g of additives compounded by antioxidant 1010 / ultraviolet absorber 328 / light stabilizer 292 / polyphosphite to components A and B at a mass ratio of 100 / 24.2 After mixing, degas and extend the chain, and cast the pressure bearing and the sample. The pressure-bearing support can be used after being placed for 7 days. The performance test results of the sample are shown in Table 2.

Embodiment 2

[0032] Component A: After dehydrating 400gPPG (number average molecular weight 1000) at 100-110°C for 2h under a vacuum of 0.1MPa, cool down to 50°C and add 200g of HMDI, react at 80-85°C for 2h under nitrogen protection, then cool down to 60°C and then Add 50g of diethylene glycol and 200g of toluene diisocyanate T-100 and continue the reaction at 80-85°C for 2h to obtain a prepolymer component.

[0033] Component B: a mixture of di-o-chloroanilinomethane and dimethylthiotoluenediamine in a molar ratio of 2:1.

[0034] Preparation of pressure bearings: Add 0.64g of additives compounded by antioxidant 245 / UV101 / light stabilizer 292 / polyphosphite to component A and component B at a mass ratio of 100 / 28.2 After mixing and degassing, cast pressure bearings and samples. The pressure-bearing support can be used after being placed for 7 days. The performance test results of the sample are shown in Table 2.

Embodiment 3

[0036]Component A: After dehydrating 400gPTMG (number average molecular weight 1000) for 2h under vacuum degree of 0.1MPa, cool down to 50°C and add 150gHDI, react at 80~85°C for 2h under the protection of nitrogen, cool down to 60°C, then add 55g of diethylene glycol Alcohol and 250g toluene diisocyanate T-100 continue to react at 80-85°C for 2h to obtain prepolymer components.

[0037] Component B: a mixture of di-o-chloroanilinomethane and dimethylthiotoluenediamine in a molar ratio of 1:1.

[0038] Preparation of the pressure bearing: the mass ratio of component A and component B is 100 / 27.2, and 0.63g is compounded by antioxidant 1076 / ultraviolet absorber 329 / light stabilizer 292 / polyphosphite The additives are mixed and degassed to extend the chain, and the pressure-bearing support and the sample are cast. The pressure-bearing support can be used after being placed for 7 days. The performance test results of the sample are shown in Table 2.

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Abstract

The invention discloses a high-hardness polyurethane elastomer pressure-bearing support material for bridge and a preparation method and a using method thereof. The high-hardness polyurethane elastomer pressure-bearing support material is prepared from a component A and a component B. The component A is prepared from, by mass, 100 parts of polyhydric alcohols, 10-20 parts of small molecular alcohols and 60-140 parts of mixed isocyanate. The component B is a chain extender. The mass ratio of the component A to the component B is 100 / 24-32. The polyhydric alcohols are PTMG or PPG, and the number-average molecular weight is 500-3000. The mixed isocyanate is the mixture of two of MDI, PPDI, T-100, T-80, HMDI, IPDI and HDI. The small molecular alcohols are the mixture of one or two of EG, BDO, DEG, PG, DPG and the like. The material is long in pot life and good in operative weldability, and the hardness is 80+ / -2D; the solidified polyurethane elastomer material is used as the pressure-bearing support, so that the bearing capacity is improved, the using number of supports can be reduced, the replacement frequency of the bridge support is lowered, and the safety coefficient of a whole retractor device is improved.

Description

technical field [0001] The invention relates to a polyurethane elastomer pressure-bearing support material for bridges and a preparation method thereof. Background technique [0002] Bridge expansion device is a general term for various devices composed of rubber and steel components installed at bridge expansion joints in order to allow vehicles to pass through the bridge deck smoothly and meet the needs of bridge superstructure deformation. According to the different structure of the telescopic body, it can be divided into modular type, comb type, rubber type and special-shaped steel single-slit type. With the development of high-grade highways and urban viaduct construction, breakthroughs have been made in the growth of bridges, and bridge expansion devices with reasonable structure and large displacement are required to meet the needs of this development. Among them, the modular bridge expansion device is a category that has developed rapidly in recent years. The teles...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/76C08G18/75C08G18/73C08G18/66C08G18/48C08G18/32C08G18/12
CPCC08G18/12C08G18/4854C08G18/6674C08G18/724C08G18/73C08G18/755C08G18/758C08G18/7614C08G18/3857C08G18/3814
Inventor 郭映瀚石雅琳苏丽丽王亚萌韩冰王振周文英
Owner LIMING RES INST OF CHEM IND