This invention discloses a two-component self-healing
polyurethane crack
sealant based on dynamic disulfide bonds and its preparation method. The
sealant comprises, by weight, component A containing 40-50 parts of
polyol and 10-20 parts of diisocyanate, and component B containing 3-9 parts of a chain
extender containing dynamic disulfide bonds, 0.5-3.5 parts of an auxiliary chain
extender, 20-25 parts of filler, and 0.05-0.2 parts of catalyst; wherein the molecular weight of the
polyol is 650-2000; the
mass ratio of component A to component B is (1.5-2.5):1; and the catalyst is an organotin
carboxylate catalyst. The
sealant provided by this invention provides damage / repair functionality through the dynamic
disulfide bond chain
extender, while the auxiliary chain extender constructs stable hard segment crystals or
hydrogen bond networks, providing
initial strength and dimensional stability. These two components synergistically improve the self-healing properties and
toughness of the prepared
polyurethane crack sealant.