A
calcium titanate-based
dielectric material with
high energy storage performance was designed. The
chemical formula of this material is Ca. 1‑x Dy x (Ti 1‑y Hf y ) 1‑x / 4 O3-z mol%M, where x=0.005~0.05, y=0.1~0.2, z=0~2, and M is MnO2 or BaCu(B2O5). It is prepared using
solid-state reaction and
tape casting methods. This invention, based on
calcium titanate-based ceramics with high breakdown
field strength, employs a series of strategies to improve
energy storage performance, including element substitution,
doping with
sintering aids, and
process improvement:
partial substitution of Hf elements at the B site increases the
band gap;
doping with
sintering aids improves
grain density, both of which enhance the breakdown
field strength; the addition of
rare earth element Dy enhances the polarization response by introducing defect dipoles; the non-stoichiometric design reduces
oxygen vacancy compensation, thereby increasing resistivity; and the
tape casting method improves
ceramic density and grain uniformity. The final prepared
calcium titanate-based
energy storage medium
ceramic material exhibits good
energy storage performance, with Ca... 0.995 Dy 0.005 (Ti 0.9 Hf 0.1 ) 0.99875 The best energy storage performance was achieved in O3-0.5 mol% BaCu(B2O5) ceramics, with a breakdown
field strength of 101.90 kV / mm and an
effective energy storage density of 10.22 J / cm³. 3 .