High-performance tire containing oxidized graphene

A high-performance, graphene technology, used in special tires, tire parts, transportation and packaging, etc., can solve the problems of dispersing rubber matrix, difficult graphene oxide peeling, breaking graphene oxide sheets, etc. Tensile strength, improved physical and mechanical properties, the effect of excellent performance

Inactive Publication Date: 2016-04-13
QINGDAO DOUBLESTAR TIRE IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the current industrial production, limited to the technical conditions of tires, the compounding of graphene oxide and rubber generally adopts the mechanical blending method. Although direct mechanical blend

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0021] The method for preparing the above-mentioned tread rubber and tire, that is, the method for preparing a high-performance tire containing graphene oxide, includes the following steps:

[0022] (1) In the step of preparing graphene oxide suspension, the graphene oxide powder is ultrasonically dispersed in deionized water, the mass concentration of graphene oxide powder is 0.5-1mg / ml, the ultrasonic power is 300-1000W, and the ultrasonic time is 30- 60 minutes, the ultrasonic frequency is 1-20KHz;

[0023] (2) The graphene oxide masterbatch preparation step is to add the natural rubber latex corresponding to the amount of graphene oxide to the graphene oxide suspension, continue to sonicate for 10-30 minutes, and then flocculate, wash, and dry in turn to prepare the oxide Graphene and natural rubber masterbatch, the flocculation adopts the compound latex added to 0.5-2wt% CaCl 2 In aqueous solution

[0024] (3) Steps for preparing semi-finished treads and tires, combining graphe...

Example Embodiment

[0026] Example 1

[0027] A high-performance tire containing graphene oxide and a preparation method thereof. The mass parts of each component of the tread rubber composite material are:

[0028] 25 parts of natural rubber matrix;

[0029] 25 parts of butadiene rubber matrix;

[0030] 50 parts of styrene butadiene rubber matrix;

[0031] 51 parts of highly dispersed white carbon black;

[0032] 4.1 parts of silane coupling agent;

[0033] Graphene oxide (added in the form of graphene oxide and natural rubber masterbatch) 4 parts;

[0034] Carbon black N330: 5 parts;

[0035] 3 parts of aromatic oil;

[0036] 1.5 parts of zinc oxide;

[0037] 1.5 parts of stearic acid;

[0038] Anti-aging agent 6PPD: 1.5 parts;

[0039] Vulcanization accelerator: 2 parts;

[0040] 1.5 parts of ordinary sulfur;

[0041] 0.1 part of antiscorching agent;

[0042] The mass fraction of graphene oxide in graphene oxide and natural rubber masterbatch is 10%.

[0043] Tread rubber and high-performance tire preparation metho...

Example Embodiment

[0044] Example 2

[0045] A high-performance tire containing graphene oxide and a preparation method thereof. The mass parts of each component of the tread rubber composite material are:

[0046] 40 parts of natural rubber matrix;

[0047] 20 parts of butadiene rubber matrix;

[0048] 40 parts of styrene butadiene rubber matrix;

[0049] 54 parts of highly dispersed white carbon black;

[0050] 4.3 parts of silane coupling agent;

[0051] Graphene oxide (added in the form of graphene oxide and natural rubber masterbatch) 1 part;

[0052] Carbon black N234: 10 parts;

[0053] 5 parts of paraffin oil;

[0054] 2.5 parts of zinc oxide;

[0055] 2.5 parts of stearic acid;

[0056] Anti-aging agent RD: 2 parts;

[0057] Vulcanization accelerator: 1.5 parts;

[0058] 1 part of ordinary sulfur;

[0059] 0.1 part of antiscorching agent;

[0060] The mass fraction of graphene oxide in graphene oxide and natural rubber masterbatch is 5%.

[0061] Tread rubber and high-performance tire preparation method: ult...

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Abstract

The invention relates to a high-performance tire containing oxidized graphene and a preparing method thereof. Tread rubber is basically prepared from, by mass, 80-100 parts of matrix rubber, 50-70 parts of high dispersion white carbon black, 4-6 parts of silane coupling agent, 5-10 parts of carbon black, 0-10 parts of oxidized graphene rubber master batch, 2-8 parts of plasticizer, 1-3 parts of active agent, 1-3 parts of antiager, 1-3 parts of vulcanization accelerator, 1-2 parts of common sulphur and 0-0.3 part of scorch retarder. The oxidized graphene rubber master batch is the compound of oxidized graphene and natural rubber, and the mass of oxidized graphene is 5-15% of the total mass of the rubber master batch. By the adoption of oxidized graphene, the properties, including tensile strength, stress at definite elongation, hardness and wear resistance, of the composite tread rubber material are improved.

Description

technical field [0001] The invention relates to a high-performance tire containing graphene oxide, a preparation method and a preparation process thereof. Background technique [0002] Tires are one of the most important components of a car. The tire tread must provide the grip or traction necessary for driving, braking and steering. The tread compound is specially configured to balance wear, traction, handling and rolling resistance. Tread compounds must be effective in a variety of driving conditions, including wet, dry or snow-covered roads, and meet customer expectations for tires with high wear resistance, high durability, low rolling resistance, and environmental protection. [0003] Graphene oxide flakes are the product of graphite powder after chemical oxidation and exfoliation. Graphene oxide is a single atomic layer that can expand to tens of microns in lateral dimension at any time. Therefore, its structure spans the typical of general chemistry and materials scie...

Claims

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Application Information

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IPC IPC(8): C08L9/06C08L7/00C08L7/02C08L9/00C08K13/06C08K9/00C08K3/36C08K3/04C08K3/22C08K5/09B60C1/00
CPCC08L9/06B60C1/0016C08K2201/014C08L7/00C08L2205/02C08L2205/035C08L7/02C08L9/00C08K13/06C08K9/00C08K3/36C08K3/04C08K2003/2296C08K5/09
Inventor 李勇戚顺青刘甲雪张静单鹏
Owner QINGDAO DOUBLESTAR TIRE IND CO LTD
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