High strength flame-retardant composite wood containing CaCO3/Mg(OH)2 and preparation method thereof
A fire-retardant composite, high-strength technology, applied in wood treatment, impregnated wood, wood impregnation, etc., can solve the problems of poor mechanical properties, soft material, easy to burn, etc., to improve mechanical properties and flame retardant properties, and the preparation process is simple. , the effect of expanding the scope of application
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Embodiment 1
[0033] Example 1CaCO 3 / Mg(OH) 2 / Preparation of wood composites:
[0034] (1) Wood is extracted with benzene alcohol, and it is stand-by after vacuum drying;
[0035] (2) Preparation containing 0.3mol·L -1 Ca(Ac) 2 , 0.6mol·L -1 CO(NH 2 ) 2 and 0.3mol·L -1 Mg(NO 3 ) 2 solution as a precursor;
[0036] (3) immerse the wood in step (1) into the precursor solution prepared in step (2) for 6-8h in a vacuum decompression system, so that the precursor solution is injected into the wood matrix;
[0037] (4) Pour the impregnated wood block and the remaining precursor solution in the step (3) into a stainless steel (inner cup is polytetrafluoroethylene) autoclave, the volume is not more than 75% of the volume of the autoclave, and put it into an oven for heating , from the ambient temperature to 90-120 ° C, keep for 6-12 hours, after the heating is completed, cut off the power to let the oven cool down naturally, and take out the wood after cooling to room temperature;
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Embodiment 2
[0039] The performance test of embodiment 2 composite wood
[0040] For the prepared CaCO 3 / Mg(OH) 2 / Testing and testing of wood composite materials, including optical microscope to observe the internal structure of wood, use X-ray diffractometer (XRD) to measure the composition of wood, and adopt mechanical testing machine to measure material (untreated wood), the composite of the present invention The compressive strength and elastic modulus of wood, the test method: use sandpaper to grind the surface of the wooden block test block to remove the surface deposits, put it into the center of the spherical movable support of the WDW microcomputer-controlled universal mechanical testing machine (Changchun Testing Machine Factory), Uniform pressure is applied to destroy the sample within 2 minutes, and the axial compressive strength, elastic modulus and proportional limit of the wood block are tested.
[0041] The results showed that under the optical microscope, the internal ...
Embodiment 3
[0044] Combustion performance analysis of embodiment 3 composite wood
[0045] Heat release rate (HRR) refers to the rate at which a material releases heat per unit area. HRR can be used as the risk index of materials encountering fire, and its peak value (pk-HRR) is an important parameter for judging the scale, development and fire extinguishing conditions of fire; The sum of the heat released; the total smoke release (TSP) indicates the total amount of smoke produced by the sample during combustion or cracking.
[0046] In this example, the heat release rate (HRR), total heat release (THR) and (total smoke release) of the composite wood of the present invention and the material (untreated wood) were respectively measured.
[0047] Experimental results: if Figure 4 As shown, the heat release rate (HRR) of the composite material decreases, and the peak heat release rate (135kW / m 2 ) than material (190kW / m 2 ) was reduced by about 41%, indicating that the flame retardancy ...
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Abstract
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