Method for synthesizing vinyl acetate

A vinyl acetate, diethylene acetate technology, applied in chemical instruments and methods, preparation of organic compounds, preparation of carboxylate and other directions, can solve the problems of low vinyl acetate yield, low selectivity, etc., to improve activity and Effects of stability, improved yield and selectivity

Active Publication Date: 2016-05-18
CHINA PETROLEUM & CHEM CORP +1
View PDF4 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is the problem of low vinyl acetate yield and low selectivity, and a n

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for synthesizing vinyl acetate
  • Method for synthesizing vinyl acetate
  • Method for synthesizing vinyl acetate

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0026] [Example 1]

[0027] Preparation of carbonylation catalyst: Co containing 9.35gCo, 3.20gBe and 1.85gAu 2 (CO) 8 , BeCl 2 and NH 4 AuCl 4 ·2H 2 O is thoroughly mixed and dissolved in acetic acid with a concentration of 10wt% to obtain 400ml of immersion solution, and 1.0L of the specific surface is 170m 2 / g, spherical SiO with a pore volume of 0.97 and a diameter of 5.6 mm 2The carrier was immersed in the above-mentioned dipping solution, and dried at 100° C. for 2 hours to obtain the catalyst. The carbonylation catalyst was analyzed by ICP, and the Co content was 9.35 g / L, the Be content was 3.20 g / L, and the Au content was 1.85 g / L.

[0028] Synthesis of vinyl acetate:

[0029] Step (1): add 1.5mol acetic acid, 0.05mol carbonylation catalyst, 0.10mol methyl iodide and 0.45mol methyl acetate into the 500ml titanium material reaction kettle, discharge the air in the kettle with argon first and then pressurize to 2.0MPa, then Introduce carbon monoxide and hydrog...

Example Embodiment

[0033] [Example 2]

[0034] Preparation of carbonylation catalyst: Co containing 9.35g Co, 3.20g Be and 1.85g Sb 2 (CO) 8 , BeCl 2 and Cl 3 Sb was thoroughly mixed and dissolved in acetic acid with a concentration of 10wt% to obtain 400ml of immersion solution, and 1.0L of the specific surface was 170m 2 / g, spherical SiO with a pore volume of 0.97 and a diameter of 5.6 mm 2 The carrier was immersed in the above-mentioned dipping solution, and dried at 100° C. for 2 hours to obtain the catalyst. The carbonylation catalyst was analyzed by ICP, and the Co content was 9.35 g / L, the Be content was 3.20 g / L, and the Sb content was 1.85 g / L.

[0035] Synthesis of vinyl acetate:

[0036] Step (1): add 1.5mol acetic acid, 0.05mol carbonylation catalyst, 0.10mol methyl iodide and 0.45mol methyl acetate into the 500ml titanium material reaction kettle, discharge the air in the kettle with argon first and then pressurize to 2.0MPa, then Introduce carbon monoxide and hydrogen until...

Example Embodiment

[0049] [Example 3]

[0050] Preparation of carbonylation catalyst: Co(OAc) containing 7.00 g Co, 1.00 g Mg and 1.00 g Au 2 ·4H 2 O, MgSO 4 ·7H 2 O and HAuCl 4 Fully mixed and dissolved in pure water to obtain 400ml of immersion liquid, and the specific surface of 1.0L was 150m 2 / g, spherical Al with a pore volume of 0.90 and a diameter of 5.6 mm 2 O 3 The carrier was immersed in the above-mentioned dipping solution, and dried at 80° C. for 2 hours to obtain the catalyst. The carbonylation catalyst was analyzed by ICP, and the Co content was 7.00 g / L, the Mg content was 1.00 g / L, and the Au content was 1.00 g / L.

[0051] Synthesis of vinyl acetate:

[0052] Step (1): add 1.5mol acetic acid, 0.05mol carbonylation catalyst, 0.10mol methyl iodide and 0.45mol methyl acetate into the 500ml titanium material reaction kettle, first discharge the air in the kettle with argon and pressurize to 2.0MPa, then Feed carbon monoxide and hydrogen until the pressure is 8.2MPa, increas...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Diameteraaaaaaaaaa
Specific surfaceaaaaaaaaaa
Specific surfaceaaaaaaaaaa
Login to view more

Abstract

The invention relates to a method for synthesizing vinyl acetate. When vinyl acetate is prepared from methyl acetate through the route of carbonylation and cracking, vinyl acetate yield and selectivity are low. The invention mainly aims at solving the problems. The vinyl acetate synthesis method comprises the following steps: methyl acetate carbonylation is carried out, such that ethylene diacetate is obtained; and ethylene diacetate is cracked, such that vinyl acetate is obtained. A carbonylation catalyst adopts SiO2, Al2O3 or a mixture thereof as a carrier, and has active components comprising at least one selected from iron-series elements, alkaline earth metal and at least one metal element selected from IB and VA. With the technical scheme, the technical problem is well solved. The method can be used in industrial production of vinyl acetate.

Description

technical field [0001] The present invention relates to a process for the synthesis of vinyl acetate. Background technique [0002] Vinyl acetate (vinylacetate, VAC or VAM for short), is a colorless, transparent, flammable liquid at room temperature with a sweet ether fragrance. It is one of the most productive organic chemical raw materials in the world, widely used in the production of polyvinyl acetate (PVAc), polyvinyl alcohol, coatings, pastes, adhesives, vinylon, films, vinyl copolymer resins, acetal resins A series of chemical and chemical fiber products are widely used in various industries. [0003] The production of vinyl acetate adopts ethylene gas-phase method and acetylene gas-phase method both at home and abroad, which belong to the petrochemical process route. Since the rise of C1 chemistry, in the 1980s, the American Halcon (Halcon) company and the British Petroleum (BP) company successively A new process for the production of vinyl acetate from methanol an...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C07C69/15C07C67/297C07C67/36C07C69/16B01J31/28B01J23/89B01J23/843B01J23/78
Inventor 查晓钟杨运信
Owner CHINA PETROLEUM & CHEM CORP
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap