Preparation method and application of modified zeolite

A modified zeolite, modified technology, applied in chemical instruments and methods, crystalline aluminosilicate zeolite, water/sludge/sewage treatment, etc., can solve the problem of rapid water quality changes, toxicity and carcinogenicity, sources and pollutant components Complicated problems, to achieve the improvement of water environment and the effect of high concentration removal

Active Publication Date: 2016-05-25
LIAONING UNIVERSITY OF PETROLEUM AND CHEMICAL TECHNOLOGY
View PDF5 Cites 11 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Printing and dyeing wastewater has complex sources and pollutant components, and has the characteristics of large water volume, high content of organic pollutants, deep chroma, high alkalinity, and rapid water quality changes. The direction of chemical and anti-biochemical development has increased the difficulty of treatment of printing and dyeing wastewater
After the dye wastewater enters the envi

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method and application of modified zeolite
  • Preparation method and application of modified zeolite
  • Preparation method and application of modified zeolite

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Embodiment 1 A kind of modified zeolite and its preparation method and application

[0040] (1) Preparation method

[0041] 1) Artificial zeolite sample pretreatment: put the artificial zeolite sample in 400ml of distilled water, add 1-2 drops of dilute hydrochloric acid and shake it to neutralize the residual alkaline substances in the pores of the zeolite, wash it repeatedly until it is neutral, and then filter it. Tumble dry low.

[0042] 2) Mix HDTMA and deionized water at a ratio of 1:6 (m:m), and prepare an organic modification solution after ultrasonic stirring.

[0043] 3) Add artificial zeolite samples to the organic modification solution, the mass ratio of HDTMA to zeolite is 1:10, 1:20, 1:40, 1:60 respectively, after mixing, shake at room temperature for 30 hours, and wash repeatedly with distilled water to neutral, filter and separate to obtain a filter cake, and dry it at 60°C to obtain an organically modified zeolite.

[0044] (2) Application 1

[0045...

Embodiment 2

[0050] Embodiment 2 A kind of modified zeolite and its preparation method and application

[0051] (1) Preparation method

[0052] 1) Artificial zeolite sample pretreatment: put the artificial zeolite sample in 400ml of distilled water, add 1-2 drops of dilute hydrochloric acid and shake it to neutralize the residual alkaline substances in the pores of the zeolite, wash it repeatedly until it is neutral, and then filter it. Tumble dry low.

[0053] 2) Mix DTBA and deionized water at a ratio of 1:3 (m:m), and prepare an organic modification solution after ultrasonic stirring.

[0054] 3) Add artificial zeolite samples to the organic modification solution. The mass ratios of DTBA to zeolite are 1:10, 1:40, and 1:60 respectively. After mixing, shake at room temperature for 30 hours, and wash repeatedly with distilled water until neutral. Filter and separate to obtain a filter cake, and dry it at 70° C. to obtain an organically modified zeolite.

[0055] (2) Application

[005...

Embodiment 3

[0058] Embodiment 3 A kind of modified zeolite and its preparation method and application

[0059] (1) Preparation method

[0060] 1) Artificial zeolite sample pretreatment: put the artificial zeolite sample in 400ml of distilled water, add 1-2 drops of dilute hydrochloric acid and shake it to neutralize the residual alkaline substances in the pores of the zeolite, wash it repeatedly until it is neutral, and then filter it. Tumble dry low.

[0061] 2) Mix HDTMA and deionized water at a ratio of 1:5 (m:m), and prepare an organic modification solution after ultrasonic stirring.

[0062] 3) Add artificial zeolite samples to the organic modification solution. The mass ratios of HDTMA to zeolite are 1:10, 1:40, and 1:60 respectively. After mixing, shake at room temperature for 30 hours, and wash repeatedly with distilled water until neutral. Filter and separate to obtain a filter cake, and dry it at 50° C. to obtain an organically modified zeolite.

[0063] (2) Application

[0...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to a preparation method and application of modified zeolite. The preparation method includes: adding a surfactant into deionized water to obtain an organic modified solution, with the surfactant and deionized water being in a mass ratio of 1:3-1:6; adding zeolite into the organic modified solution, with the surfactant and zeolite being in a mass ratio of 1:10-1:60, mixing the substances uniformly, then carrying out concussion reaction for 20-32h, performing filtering and low temperature drying, thus obtaining an organic modified zeolite product. Also, inorganic metal salt titanium sulfate can be added to conduct further compound modification. The composite modified zeolite prepared by the method provided by the invention shows good adsorption capacity to both copper ions and dye solutions.

Description

technical field [0001] The invention belongs to the technical field of sewage treatment, in particular to a method for removing heavy metal copper ions and organic dye pollutants in sewage by using modified zeolite. Background technique [0002] The pollution of heavy metal ions caused by industrial sewage discharge is a worldwide environmental protection problem. Heavy metal ions such as Sb, Cr, Cu, Pb, Cd, Hg will cause harm to human health and the environment. Copper ions mainly come from industrial wastewater in electroplating, metal processing and other industries, and the enrichment of copper ions is often found near mines, landfills and waste disposal sites. [0003] Copper ions can cause skin itching and keratin of hands and feet in light cases, and cause gastrointestinal discomfort and liver and kidney discomfort in severe cases. People who are often exposed to high concentrations of copper ions are also at risk of liver cancer. The World Health Organization (WHO)...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): B01J20/18B01J20/30C01B39/02C02F1/28C02F1/62
Inventor 邓慧陈澳
Owner LIAONING UNIVERSITY OF PETROLEUM AND CHEMICAL TECHNOLOGY
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap