Efficient compound-type hydrate dynamics inhibitor

A kinetic inhibitor, composite technology, applied in drilling compositions, chemical instruments and methods, piping systems, etc., can solve the problem of increasing the risk of hydrate blockage, the influence of supercooling, and the influence of supercooling. and other problems, to achieve the effect of prolonging the formation time of blockage, enduring a large degree of subcooling, and inhibiting the formation rate

Inactive Publication Date: 2016-07-27
CHINA PETROLEUM & CHEM CORP +1
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Problems solved by technology

[0004] In terms of the development of hydrate kinetic inhibitors, the Chinese patent CN103305200A "A Composite Hydrate Inhibitor" relates to a composite hydrate inhibitor consisting of polyvinyl caprolactam, alcohol or salt, and water, but the Inhibitors are greatly affected by the subcooling of the system, and the salts in the inhibitors have a risk of corrosion to the pipeline, and the existence of the water phase increases the risk of hydrate blockage
Chinese patent CN101602940A "Efficient Kinetic Hydrate Inhibitor" synthesizes a compound with a unique unit structure as a hydrate kinetic inhibitor. Through adsorption, it inhibits the hydrate particles from remaining dispersed without aggregation, thereby inhibiting the formation of hydrates. However, this The invention is greatly affected by the supercooling degree of the system, high cost, complex synthesis process, many intermediate by-products, poor biodegradability, and certain pollution to the environment

Method used

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Examples

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preparation example Construction

[0035] The present invention also provides a preparation method for the above-mentioned copolymer formed by the reaction of vinylpyrrolidone, vinylcaprolactam and vinylimidazole, which comprises:

[0036] In the first step, vinylpyrrolidone and vinylcaprolactam are added into a reactor with a solvent in a certain proportion, stirred at a constant speed until they are evenly mixed, and heated to a certain temperature;

[0037] In the second step, under the protection of nitrogen, add an initiator, put vinylimidazole into the reaction container, and obtain a solid product after reacting for a certain period of time. After the product is slowly cooled to room temperature, filter the solid product in the reaction solution, and wash and purify it with ether. times, and then vacuum-dried to obtain a copolymer product.

[0038] The mass ratio of the added amounts of vinylpyrrolidone, vinylcaprolactam and vinylimidazole is (0.1-5):(0.1-5):(0.1-10).

[0039] Preferably, the vinylpyrroli...

Embodiment 1

[0070] This embodiment provides a compound hydrate kinetic inhibitor, which is obtained by mixing polyvinyl caprolactam, diethyl monobutyl ether and ethanol at a mass ratio of 2:1:1.

[0071] In this example, the above-mentioned high-pressure transparent sapphire reactor is used for evaluation, and 15ml of deionized water is prepared, and the above-mentioned composite hydrate kinetic inhibitor with a system water quality of 0.5% is added. The experimental pressure is 4.5 MPa, and the experimental temperature is 277.2 K, no hydrate particles appeared in the reactor within 24 hours.

Embodiment 2

[0073] This example provides a composite hydrate kinetic inhibitor, which is obtained by mixing Inhibex501, ethanolamine and ethanol at a mass ratio of 2:1:2.

[0074] In this example, the above-mentioned high-pressure fully transparent sapphire reactor is used for evaluation, and 15ml of deionized water is prepared, and the above-mentioned composite hydrate kinetic inhibitor with a system water quality of 1.0% is added. The experimental pressure is 4.5MPa, and the experimental temperature is 277.2 K, no hydrate particles appeared in the reactor within 24 hours.

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Abstract

The invention provides an efficient compound-type hydrate dynamics inhibitor. The efficient compound-type hydrate dynamics inhibitor comprises a dynamics inhibitory component, a dynamics inhibitor assistant and a dynamics inhibitor solvent. By means of the dynamics inhibitor, the defects that a traditional thermodynamical inhibitor is large in use quantity, high in economic cost, large in environment pollution and the like are overcome. Compared with a common hydrate dynamics inhibitor and a common hydrate polymerization inhibitor, by means of the dynamics hydrate inhibitor, the formation rate of a hydrate can be effectively inhibited, the blocking forming time of the hydrate is delayed, and the efficient compound-type hydrate dynamics inhibitor has the advantages of being small in use quantity, capable of bearing the large super-cooling degree, stable in performance, economical, efficient and the like, is suitable for an oil-air-water three-phase or air-water two-phase mixing transmission system, and has the good application prospects.

Description

technical field [0001] The invention relates to the technical field of oil and gas pipeline transportation, in particular to a high-efficiency composite hydrate kinetic inhibitor. Background technique [0002] In the process of oil and gas extraction and gathering, due to its special high pressure and low temperature environment, hydrocarbon gases with low boiling points (such as natural gas components, CO 2 、H 2 S, etc.) can easily form a kind of ice-like solid compound with a cage structure with water molecules, which is often called combustible ice. Hydrates will grow and accumulate rapidly after formation, causing pipeline flow obstacles, such as hydrate solids clogging wellbore or gathering and transportation pipelines, valves, safety tanks and other devices with throttling effects, resulting in production stoppage, production reduction or even pipeline rupture, resulting in oil and gas leakage polluted environment. Therefore, how to effectively prevent and control t...

Claims

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Application Information

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IPC IPC(8): C09K8/524F17D1/17F17D1/02C08F226/06C08F226/10
CPCC09K8/524C08F226/06C08F226/10C09K2208/22F17D1/02F17D1/17
Inventor 闫柯乐尚祖政姜鸣张红星邹兵姜素霞吴京峰
Owner CHINA PETROLEUM & CHEM CORP
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