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Flue gas treatment system and flue gas treatment method

一种处理系统、处理方法的技术,应用在气体处理、化学仪器和方法、分离方法等方向,能够解决影响工厂稳定运行、长期运行、浓度增加等问题

Active Publication Date: 2018-07-03
MITSUBISHI POWER LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, even in the exemplary cases described in Patent Documents 1 and 2, the oxidation reaction represented by the following formula (2) significantly proceeds during the treatment of combustion flue gas, and thus SO 3 The concentration may increase
In addition, failure may thus occur within the system, and the operation of the plant must be stopped each time such a failure occurs, and therefore, stable operation, long-term operation, etc. of the plant may be affected

Method used

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  • Flue gas treatment system and flue gas treatment method
  • Flue gas treatment system and flue gas treatment method
  • Flue gas treatment system and flue gas treatment method

Examples

Experimental program
Comparison scheme
Effect test

no. 1 approach

[0046] will be referenced below figure 1 A first embodiment of a flue gas treatment system according to the present invention is described. refer to figure 1 ,Will figure 1 The flue gas treatment system shown in is arranged in a coal-fired power plant, and the system includes at least a boiler 2; a first adding device 3a; a second adding device 3b; a denitration device 4; an air preheater 5; 6; heat recovery and reheating equipment 7a and 7b; desulfurization equipment 8; and chimney 9. Note that here and in the claims, the configuration consisting of at least the first adding device 3a, the second adding device 3b, and the denitrification device 4 is referred to as denitrification and SO 3 Restore the device.

[0047] The boiler 2 burns externally supplied boiler fuel in a combustion chamber and supplies combustion flue gas generated by the combustion to the denitration device 4 . Flue gases produced by combustion include at least SO 2 The oxidation produces SO 3 .

[...

no. 2 approach

[0101] will be referenced below figure 2 A second embodiment of a flue gas treatment system is described. provided and shown in figure 1 The same elements as those of the first embodiment have the same reference numerals and symbols in , and detailed descriptions thereof will not be repeated below. refer to figure 2 The flue gas treatment system 10 differs from that of the first embodiment at least in that it is arranged in a power plant burning low-grade fuels and that it comprises a third addition device 3c. Low-grade fuels include heavy oil, petroleum tars (petrokokes), vacuum residue (VR) and low-grade coal.

[0102] For the third adding device 3c, an injection pipe installed in an existing factory, which is arranged on the downstream side of the air preheater 5 and on the upstream side of the dust collector 6, can be used. The third adding device 3c further injects the third additive ammonia (NH 3 ) to the combustion flue gas to which the first additive and the sec...

Embodiment 1

[0117] Evaluation for the reduction of SO in flue gas produced under the same conditions as in coal-fired power plants 3 SO 3 Effect of reducing agent (second additive).

[0118] (Preparation of Catalyst A)

[0119] Catalyst A was produced by applying the basic and per se known methods for the production of denitration catalysts.

[0120] (SO 3 Reduction performance and denitrification performance test I)

[0121] Through a laboratory-scale test in which a real machine was assumed to be used, two catalysts in which three catalysts A were continuously combined were produced, and the catalyst blocks were used as Test Example 1 and Test Example 2. Allow flue gas with predetermined properties to flow through the test case, and test SO at the outlet of the first layer, the outlet of the second layer and the outlet of the third layer of the catalyst layer 3 Concentration and NO x concentration. In Test Example 1, no SO was added at the inlet of the catalyst layer 3 reducing ...

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Abstract

The invention provides a flue gas treatment system and a flue gas treatment method. Compared with common ones, the plant can run stably for a long time by reducing NOx in the combustion flue gas and reducing the concentration of SO3 more. The flue gas treatment method according to the present invention is a flue gas treatment method for removing NOx and SO3 in flue gas including NOx and SO3, and the method includes denitrification and SO3 reduction steps of denitrating the gas and reducing SO3 to SO2, Wherein the first additive NH3 and the second additive are added to the combustion flue gas before the combustion flue gas is contacted with the catalyst, the second additive includes an olefin selected from the general formula: CnH2n (n is an integer from 2 to 4) And general formula: one or more of the group consisting of alkanes represented by CmH2m+2 (m is an integer from 2 to 4).

Description

technical field [0001] The present invention relates to flue gas treatment systems and flue gas treatment methods, and more particularly to treatment systems for the treatment of combustion flue gas comprising sulfur trioxide produced in coal fired power plants or power plants fired with lower grade fuels and Flue gas treatment methods. Background technique [0002] In general, in order to prevent air pollution, flue gas treatment systems and flue gas treatment for treating combustion flue gas burned in various boilers for power plants such as coal-fired power plants and low-grade fuel-fired power plants have been strongly desired method. Such flue gases include nitrogen oxides (NO x ) and a large amount of sulfur oxides (SO x ), and in order to deal with them, denitration equipment, dust collectors, desulfurization equipment, etc. are installed in the factory. However, SO x Sulfur trioxide (SO 3 ) are corrosive and are factors that prevent the stable and long-term ope...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/86B01D53/50B01J23/30
CPCB01D53/75B01D2257/302B01D2257/404B01D2251/2062B01D2251/208B01D53/8637B03C3/017B01D2255/20707B01D2255/65B01D2255/40B01D53/343B01D53/8609B01D53/869
Inventor 增田具承三好崇仁东野耕次
Owner MITSUBISHI POWER LTD