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A kind of environment-friendly, temperature-resistant, discoloration-resistant ink composition

An ink composition and color change technology, applied in the field of temperature-resistant, environmentally friendly, and color-change-resistant ink compositions, can solve problems such as unsatisfactory effects and poor effects, eliminate color difference, reduce environmental pressure, and improve temperature resistance. Effect

Active Publication Date: 2019-04-30
上海超彩油墨有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] In the present invention, it is surprisingly found that treating the surface of talcum powder with titanate functional molecules can not only solve the problems of heat resistance and fading, but also reduce the cost and prevent the problem of PVC deformation caused by thermal stress in the printing process, but , the effect of pure ethyl titanate and talcum powder is not ideal, especially the effect with barium sulfate is even worse. Therefore, the present invention is based on the discovery of the effect of ethyl titanate, and the titanate is modified by increasing The function of the organic part solves heat resistance, fading and compatibility with talcum powder, barium sulfate and environmental ink

Method used

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  • A kind of environment-friendly, temperature-resistant, discoloration-resistant ink composition
  • A kind of environment-friendly, temperature-resistant, discoloration-resistant ink composition
  • A kind of environment-friendly, temperature-resistant, discoloration-resistant ink composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] Each material and its mass percent in the present embodiment composition are:

[0049]

[0050]

[0051] Wherein, the resin powder mixture is a mixture of polyester powder and phenolic resin powder in a mass ratio of 10:1; the environmentally friendly solvent mixture is dimethyl succinate, methyl hydroxypropionate, butanol, and ethanol in a mass ratio of A mixture of 10:2.5:0.5:3; the anti-wear additive is a mixture of carnauba wax and decane in a mass ratio of 20:1; the wetting and dispersing agent has the following structure:

[0052]

[0053] Wherein, R1 is a methyl group, R is an alkyl group with 8 carbon atoms, n is 30, Y is 10, and Z is 0; the molecular structure of the leveling agent is

[0054]

[0055] Among them, R is -CH 2 CH 3 , X is an integer of 1, n is an integer of 10, and m is 20; the functional filler is a mixture of talcum powder and barium sulfate according to a mass ratio of 10:1, and the particle size of the functional filler is 0.5 to ...

Embodiment 2

[0061] The ink composition of the present embodiment is prepared from the following components in mass percentage:

[0062]

[0063] Wherein, the resin powder mixture is a mixture of polyester powder and phenolic resin powder according to the mass ratio of 10:1; the environmentally friendly solvent mixture is propanol, butanol, propylene glycol methyl ether, propylene glycol ethyl ether, and propylene glycol butyl ether according to the mass ratio of 8: A mixture of 3:1:2:3; the anti-wear additive is a mixture of carnauba wax and undecane in a mass ratio of 18:1; the wetting and dispersing agent has the following structure:

[0064]

[0065] Wherein, R1 is H, R is an alkyl group with 10 carbon atoms, n is 30, Y is 30, and Z is 10; the preparation method adopts bulk polymer, the initiator is cyclohexanone peroxide, and the reaction time is 16 hours.

[0066] The molecular structure of the leveling agent is

[0067]

[0068] Among them, R is -CH 3 , X is an integer of...

Embodiment 3

[0072] The ink composition of the present embodiment is prepared from the following components in mass percentage:

[0073]

[0074] Among them, the resin powder mixture is a mixture of silicone resin powder, novolac epoxy resin powder, and polyester powder in a mass ratio of 2:3:8; the environmentally friendly solvent mixture is methyl adipate, methyl hydroxypropionate, propylene glycol Diethyl ether and ethanol are a mixture of 8:2:1:2 in mass ratio; the anti-wear additive is a mixture of carnauba wax and dodecane in a mass ratio of 18:1; the wetting and dispersing agent has the following structure:

[0075]

[0076] Wherein, R1 is H, R is an alkyl group with 10 carbon atoms, n is 30, Y is 30, and Z is 10; the molecular structure of the leveling agent is

[0077]

[0078] Among them, R is -CH 3 , X is an integer of 10, n is an integer of 20, and m is 30; the functional filler is a mixture of calcium carbonate and barium sulfate at a mass ratio of 10:1, and the part...

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Abstract

The invention discloses an environmentally-friendly, temperature-resistant and discoloration-resistant ink composition. The ink composition is prepared from the following components in parts by weight: 40-60 parts of resin powder, 10-25 parts of environmentally-friendly solvent mixture, 1-10 part of pigment and / or dye, 2-5 parts of wear-resistant additive, 1-5 parts of wetting dispersing agent, 0.1-2 parts of flatting agent and 5-15 parts of functional filler, wherein the functional filler is filler modified by modified ester titanate. By adopting the environmentally-friendly, temperature-resistant and discoloration-resistant ink composition, the problems of PVC (Polyvinyl Chloride) printing ink smell and color fading in a printing process is solved; meanwhile, the temperature resistance of the pigment is improved, the color difference is eliminated, and the product qualification rate is increased; the prepared ink is environmentally-friendly, has no harm to human bodies, contributes to lowering pressure on the environment, and has no smell.

Description

technical field [0001] The invention belongs to the field of printing, specifically relates to the field of film gravure printing ink, and more specifically relates to an ink composition which is environment-friendly, temperature-resistant and color-change-resistant. Background technique [0002] PVC is an important printing substrate, because it is flame retardant, cheap, and easy to process. It can be used as a thin film to form various materials on various plastic surfaces through lamination technology. The printed PVC film has various patterns printed on the surface, which can be used in wallpapers and floors, and can also be processed into various container shapes as household appliances and devices. Therefore, it is widely used in many fields. [0003] Whether it is a film or a container, in order to achieve a decorative effect, it is necessary to print various beautiful patterns to enhance the competitiveness of the product, beautify the life, and increase the attrac...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D11/03C09D11/033C09D11/104C09D11/103C09D11/102
CPCC09D11/03C09D11/033C09D11/102C09D11/103C09D11/104
Inventor 高延敏陆介平徐静杰
Owner 上海超彩油墨有限公司