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Preparation method for environment-friendly automotive adhesive

Inactive Publication Date: 2016-09-07
郭迎庆
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The technical problem mainly solved by the present invention: Although the current traditional vehicle adhesive has the characteristics of strong adhesion, good low temperature resistance, and good weather resistance and air tightness, it still has strong acid and strong alkali resistance in use. Relatively poor, the glue layer is prone to foaming, and the current situation of water resistance and humidity resistance is poor. A kind of peanut shell is used as raw material, and after being ground into powder, absolute ethanol and toluene are added for pretreatment to remove surface wax. After massaging, it is hydrolyzed by cellulase, and the peanut shell extract is obtained by precipitation with sulfuric acid solution, and then the peanut shell extract is modified by epichlorohydrin, and the modified peanut shell extract is mixed with diphenylmethane diisocyanate The preparation method of the prepolymer obtained by polymerization with polyethylene glycol is mixed, and cooled to room temperature after reaction to obtain an adhesive for environmentally friendly vehicles

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0020]First, weigh 300g of peanut shells, after manual selection and removal of impurities, wash 3 times with deionized water, transfer them to a tissue grinder, crush them into 0.1cm pieces, then place them in an oven at 105°C, and dry them until constant Then use a mortar to grind the dried peanut shell fragments into powder; then place the above-mentioned powder in a Soxhlet extractor filled with 300mL of absolute ethanol and 400mL of toluene, and reflux for 2h at 60°C , filtered, and the resulting filter residue was washed 3 times with absolute ethanol, then poured into an oven at 80°C, and dried for 20 minutes to obtain pretreated peanut shell powder; then 1g of Cellulase and 60g of the above-mentioned pretreated peanut shell powder, start the stirrer, set the speed at 300r / min, add dropwise citric acid solution under stirring, adjust the pH of the mixed solution in the beaker to 4.5, and heat up to 45°C. Stir and react for 3 hours, after the materials in the reaction ket...

example 2

[0023] First, weigh 400g of peanut shells, after manual selection and removal of impurities, wash them with deionized water for 4 times, transfer them to a tissue grinder, and crush them into 0.2cm pieces, then place them in an oven at 108°C, and dry them until constant Then use a mortar to grind the dried peanut shell fragments into powder; then put the above-mentioned powder into a Soxhlet extractor filled with 300mL of absolute ethanol and 400mL of toluene, and reflux for 3h at 65°C , filtered, and the resulting filter residue was washed 4 times with absolute ethanol, then poured into an oven at 85°C, and dried for 25 minutes to obtain pretreated peanut shell powder; then, 1.5 g cellulase and 70 g of the above-mentioned pretreated peanut shell powder, start the stirrer, set the speed at 400 r / min, and add the citric acid solution dropwise under stirring, adjust the pH of the mixed solution in the beaker to 4.8 and warm to 48 ° C, Stirring and reacting for 4 hours, after the...

example 3

[0026] First, weigh 500g of peanut shells, after manual sorting and removal of impurities, wash them with deionized water for 5 times, transfer them to a tissue grinder, crush them into 0.3cm pieces, then place them in an oven at 110°C, and dry them until constant Then use a mortar to grind the dried peanut shell fragments into powder; then place the above-mentioned powder in a Soxhlet extractor filled with 300mL of absolute ethanol and 400mL of toluene, and reflux for 4h at 70°C , filtered, and the resulting filter residue was washed 5 times with absolute ethanol, then poured into a 90°C oven, and dried for 30 minutes to obtain pretreated peanut shell powder; then 2g of Cellulase and 80g of the above-mentioned pretreated peanut shell powder, start the stirrer, set the rotation speed to 500r / min, add dropwise citric acid solution under the stirring state, adjust the pH of the mixed solution in the beaker to 5.0, and heat up to 50°C. Stirring and reacting for 5 hours, after the...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention discloses a preparation method for an environment-friendly automotive adhesive, and belongs to the technical field of adhesive preparation. The preparation method comprises the following steps: taking peanut shells as raw materials, grinding the peanut shells into powder, adding absolute ethyl alcohol and toluene for pre-treatment, hydrolyzing by cellulase after removing surface wax, and precipitating by use of a sulfuric acid solution to obtain peanut shell extract; and modifying the peanut shell extract by use of epoxy chloropropane, and mixing the modified peanut shell extract with diphenylmethane diisocyanate and polyethylene glycol to obtain prepolymer for mixing, cooling to the room temperature after reacting, thereby obtaining the environment-friendly automotive adhesive. According to the embodiment, the preparation method is simple and convenient to operate; the peanut shells are used as raw materials, so that the raw materials are simple and easily available, and the production cost is reduced; the preparation method is green and environmentally friendly, does not need a special instrument, and the process is simplified, so that the prepared environment-friendly automotive adhesive has remarkably improved water resistance and dampness-heat resistance while having extremely high strong acid resistance and strong alkaline resistance.

Description

technical field [0001] The invention discloses a method for preparing an adhesive for environment-friendly vehicles, which belongs to the technical field of adhesive preparation. Background technique [0002] At present, with the vigorous development of my country's automobile industry, the number of automobiles has increased significantly. With the improvement of the overall quality requirements of the car, the requirements for the special adhesives for the car are also constantly increasing with the needs of the market. [0003] Commonly used automotive adhesives can be classified into five categories: automotive body adhesives, automotive interior adhesives, automotive engine chassis adhesives, auto parts adhesives, and automotive manufacturing process adhesives. In recent years, the annual demand for polyurethane adhesives in my country has grown at an average rate of 30%. Due to my country's strict environmental protection regulations on adhesives used in the automotiv...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/76C08G18/64C08G18/48C08G18/10C08H8/00C09J175/08
CPCC08G18/10C08G18/4833C08G18/6492C08G18/7671C08H8/00C09J175/08
Inventor 郭迎庆许博伟张明
Owner 郭迎庆