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A kind of preparation method of antimony sulfide film

A technology of antimony sulfide film and antimony sulfide, applied in the direction of electrolytic inorganic material coating, etc., can solve the problems of poor process controllability, sample waste, and inapplicability of a small amount of precious samples, so as to avoid barrier effect, short reaction time and high yield high effect

Active Publication Date: 2018-04-03
YANSHAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the sample waste in the preparation process of the spin coating method is serious, it is not suitable for a small amount of precious samples, and the process controllability is poor

Method used

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  • A kind of preparation method of antimony sulfide film
  • A kind of preparation method of antimony sulfide film
  • A kind of preparation method of antimony sulfide film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Conductive glass (ITO) was ultrasonically cleaned in acetone and ethanol solutions for 15 minutes, and then rinsed with deionized water; 0.02gSb 2 S 3 Add to 10ml 1,2-ethylenediamine and 1ml 1,2-ethanedithiol mixed solvent, stir and dissolve at room temperature to prepare electrodeposition solution; figure 1 As shown, two pieces of conductive glass 2 are used as the working electrode and the counter electrode, and are vertically arranged in the electrolytic cell 1 equipped with the above-mentioned electrodeposition solution 3. The electrode surfaces are parallel to each other, and the cathode constant potential electrodeposition is carried out at a voltage of 4V. The time is 30 minutes. After the electrodeposition is completed, a uniform and dense film is deposited on the conductive glass. The electrodeposited film is heat-treated at 400° C. for 3 minutes under nitrogen gas, and cooled to room temperature to obtain an antimony sulfide film.

[0025] like figure 2 As ...

Embodiment 2

[0028] Conductive glass (FTO) was ultrasonically cleaned in acetone and ethanol solutions for 15 minutes, and then rinsed with deionized water; 0.03gSb 2 S 3 Add it to a mixed solvent of 10ml 1,2-ethylenediamine and 1ml 1,2-ethanedithiol, stir and dissolve at room temperature to obtain an electrodeposition solution; use two pieces of conductive glass as the working electrode and the counter electrode, and put them in a vertical arrangement In the electrolytic tank with the above-mentioned electrodeposition solution, the electrode surfaces are parallel to each other, and the cathode constant potential electrodeposition is carried out, the voltage is 8V, and the electroplating time is 5min. After the electrodeposition is completed, a layer of uniform and dense film is deposited on the conductive glass. The electrodeposited film was heat-treated at 300° C. for 1 minute under nitrogen gas, and cooled to room temperature to obtain an antimony sulfide film.

Embodiment 3

[0030] Conductive glass (AZO) was ultrasonically cleaned in acetone and ethanol solutions for 15 minutes, and then rinsed with deionized water; 0.01gSb 2 S 3 Add it to a mixed solvent of 10ml 1,2-ethylenediamine and 1ml 1,2-ethanedithiol, stir and dissolve at room temperature to obtain an electrodeposition solution; use two pieces of conductive glass as the working electrode and the counter electrode, and put them in a vertical arrangement In the electrolytic tank with the above-mentioned electrodeposition solution, the electrode surfaces are parallel to each other, and the cathode constant potential electrodeposition is carried out, the voltage is 1.5V, and the electroplating time is 10min. After the electrodeposition is completed, a layer of uniform and dense film is deposited on the conductive glass. The electrodeposited film was heat-treated at 350° C. for 10 minutes under nitrogen gas, and then cooled to room temperature to obtain an antimony sulfide film.

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Abstract

The invention discloses a preparation method for antimony sulfide films. The method is mainly characterized in that antimony sulfide is added into a mixed solution of 1,2-ethylenediamine and 1,2-ethanedithiol according to the proportion of 0.01-0.03 g of the antimony sulfide to per 11 milliliter of the mixed solution of the 1,2-ethylenediamine and the 1,2-ethanedithiol and is dissolved in the mixed solution, and electro-deposition liquid is obtained; two transparent electrodes are vertically arranged and placed into an electrolytic cell containing the electro-deposition liquid for cathode constant potential electro-deposition, the voltage is 1.5-8 V, the electroplating time is 5-30 min, uniform and compact films are deposited on cathodes after completion of electro-deposition; the electro-deposited films are subjected to heat treatment at 300-400 DEG C under nitrogen atmosphere and are naturally cooled to the room temperature, and the antimony sulfide films are obtained. The preparation method is simple, short in reaction time, high in productivity, suitable for batch production in factories and high in practicability, and the prepared antimony sulfide films can be applied to catalysis and solar cells and has broad application prospects in the field of photoconductive materials.

Description

technical field [0001] The invention relates to a method for preparing an inorganic functional film, in particular to a method for an antimony sulfide film. Background technique [0002] Antimony sulfide is a layered V-VI group direct bandgap semiconductor material with an energy bandgap of 1.5-2.2eV. It belongs to the orthorhombic crystal system and has high photosensitivity and high thermoelectric energy. It is widely used It is also an ideal material for utilizing solar energy in thermoelectric cooling technology, electronic and optoelectronic devices, and optoelectronics research in the infrared region. Currently, for Sb 2 S 3 There have been many researches on the preparation of thin films, and the preparation methods can be classified into the following categories: spray pyrolysis, chemical bath deposition, dipping and thermal evaporation. These preparation methods usually require strict control of experimental conditions, such as high temperature, concentration of m...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25D9/08
CPCC25D9/08
Inventor 张海全侯文龙梁波郭慧云王海龙赵乐乐彭飞程才红杨越冬
Owner YANSHAN UNIV
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