A method for separating lanthanides
A technology for lanthanide elements and elements, applied in the field of element separation, can solve the problems of long separation times, low separation ratio, and long time for purifying lanthanide elements, and achieves the effects of avoiding multiple separations, high-efficiency crystallization separation, and low cost.
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Embodiment 1
[0040] Embodiment one: the separation of neodymium samarium (NdSm)
[0041] 0.3mmol NdCl 3 ·6H 2 O, 0.3 mmol SmCl 3 ·6H 2 O and 4.5 mmol H 3 BO 3 Put it in a 10ml polytetrafluoroethylene reaction kettle, add 0.1ml deionized water, seal it, heat up to 190°C, heat for 3 days, then cool to room temperature at a rate of 3-4oC / h, wash the product with a large amount of boiling water, and wash the lotion Collect them into a 100ml volumetric flask and make up to volume, and the resulting crystalline product is washed with ethanol and dried at room temperature.
[0042] The resulting crystals were characterized by a powder diffractometer, such as Figure 4Shown, prove that this doping reaction only generates the crystal of a kind of structure type, and this crystal has identical structure with NdBOCl crystal; Crystal is first dissolved with concentrated nitric acid, then diluted to low acidity, with inductively coupled plasma mass spectrometer ( ICP-Ms) measure the concentratio...
Embodiment 2
[0043] Embodiment two: the separation of neodymium dysprosium (NdDy)
[0044] 0.3mmolNdCl 3 ·6H 2 O, 0.3mmol DyCl 3 ·6H 2 O and 4.5 mmol H 3 BO 3 Put it in a 10ml polytetrafluoroethylene reaction kettle at a ratio of 1:1:15, add 0.1ml of deionized water, seal it, heat it up to 200°C, heat it for 3 days, and then cool it to room temperature at a rate of 3-4oC / h. After washing with a large amount of boiling water, the obtained crystal product was washed with ethanol and dried at room temperature, and the washing liquid was collected into a 100ml volumetric flask to constant volume.
[0045] The resulting crystals were characterized by a powder diffractometer, such as Figure 6 As shown, it proves that the doping reaction only generates crystals of one structure type, and the crystals have the same structure as NdBOCl crystals; the crystals are first dissolved with concentrated nitric acid, then diluted to low acidity, and analyzed by an inductively coupled plasma mass spec...
Embodiment 3
[0046] Embodiment three: the separation of neodymium dysprosium (NdDy)
[0047] 0.3mmolNdCl 3 ·6H 2 O, 0.3mmol DyCl 3 ·6H 2 O and 6.0 mmol H 3 BO 3 Put it in a 10ml polytetrafluoroethylene reaction kettle at a ratio of 1:1:20, add 0.1ml of deionized water, seal it, heat it up to 210°C, heat it for 7 days, and then cool it to room temperature at a rate of 3-4oC / h. Wash with a large amount of boiling water, wash the product crystals with ethanol and dry at room temperature, and collect the washing liquid into a 100mL volumetric flask to constant volume.
[0048] The resulting product was characterized by a powder diffractometer, such as Figure 8 As shown, it was proved that the product contained three crystal types (NdBOCl, DyBO-1 and DyBO-2) with different structures.
[0049] Put the product in bromoform, stir well, let it stand for a period of time, and selectively suspend or precipitate in the bromoform solution due to the different densities of crystals of different...
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