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A kind of preparation method of n-type single crystal double-sided battery

A double-sided cell and single crystal technology, applied in circuits, photovoltaic power generation, electrical components, etc., can solve the problems of increased fragmentation rate of silicon wafers and achieve high photoelectric conversion efficiency

Active Publication Date: 2017-12-01
宁波乐丰新能源有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing technology is to mechanically engrave small pyramids on the front of the silicon wafer, and put the engraved silicon wafer into the corrosive solution to make texture. The hidden damage formed by mechanical engraving is under the uncontrollable erosion of the corrosive solution. It is easy to cause the fragmentation rate of silicon wafers to increase, which needs to be improved urgently

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A method for preparing an N-type single crystal bifacial battery, specifically comprising the following steps:

[0022] S1 Texturize the front side of the silicon wafer, and then carry out B diffusion; Among them, the specific method of texturizing the front side of the silicon wafer is: first use a laser to form a pyramid structure on the front side of the silicon wafer, clean it with nitrogen, and then heat the silicon wafer to 80°, use Ultrasonic atomization technology deposits a layer of uniform and discontinuous NaOH small droplets on the front of the silicon wafer, and after 2 minutes of corrosion, a pyramid texture structure is formed on the front surface of the silicon wafer; the mass percentage of NaOH solution before the NaOH small droplets are atomized The concentration is 20%;

[0023] S2 performs wet etching to remove the self-diffusion layer formed on the back and edge of the silicon wafer;

[0024] S3 Then use PEVCD equipment to deposit SiN on the B diff...

Embodiment 2

[0030] A method for preparing an N-type single crystal bifacial battery, specifically comprising the following steps:

[0031] S1 Texturize the front side of the silicon wafer, and then carry out B diffusion; Among them, the specific method of texturizing the front side of the silicon wafer is: first use a laser to form a pyramid structure on the front side of the silicon wafer, clean it with nitrogen, and then heat the silicon wafer to 70°, use Ultrasonic atomization technology deposits a layer of uniform and discontinuous NaOH small droplets on the front of the silicon wafer, and after 4 minutes of corrosion, a pyramid texture structure is formed on the front surface of the silicon wafer; the mass percentage of NaOH solution before the NaOH small droplets are atomized The concentration is 10%;

[0032] S2 performs wet etching to remove the self-diffusion layer formed on the back and edge of the silicon wafer;

[0033] S3 Then use PEVCD equipment to deposit SiN on the B diff...

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PUM

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Abstract

The invention discloses a preparation method for an N-type single-crystal double-faced battery which is high in wafer forming ratio and good in photoelectric conversion efficiency. The method comprises the steps of performing texturing on a front surface of a silicon wafer and carrying out B diffusion, wherein the steps of the front surface texturing comprises the steps of forming a pyramid structure on the front surface of the silicon wafer by employing laser, after nitrogen is cleaned, heating the silicon wafer to 70-80 degrees centigrade, depositing NaOH droplets on the front surface of the silicon wafer through ultrasonic atomization, and forming a pyramid texture structure after corrosion is carried out for 2-4 minutes; carrying out wet etching to remove self-diffusion layers formed on the back and edge of the silicon wafer, and depositing a SiN<X> mask; carrying out P diffusion on the back of the silicon wafer, performing plasma etching on the self-diffusion layer on the edge, and carrying out washing by employing corrosive liquid to remove the SiN<X> mask and a phosphorosilicate glass layer on the surface; using an ALD method to form a Al<2>O<3> passive film on the front surface of the silicon wafer, depositing a SiN<X> protection film on the front surface of the silicon wafer and depositing SiN<X> antireflective film on the back of the silicon wafer; and carrying out silk-screen printing to form an electrode for sintering.

Description

technical field [0001] The invention relates to the field of photovoltaic equipment manufacturing, in particular to a method for preparing an N-type single-crystal double-sided battery. Background technique [0002] In the current photovoltaic market, P-type polycrystalline cells are commonly used, but the photovoltaic conversion efficiency of this P-type polycrystalline cell is not high. With the advancement of technology, the production cost of N-type silicon wafers is also further reduced. In addition, because the efficiency of monocrystalline materials is higher than that of polycrystalline materials, N-type solar cells have also been used more and more. Moreover, now There is a double-sided diffusion method for N-type single-crystal double-sided cells in the technology. First, boron is diffused after texturizing the front side of the silicon wafer, and then silicon nitride and silicon oxide are deposited by CVD as a mask for the back side. Phosphorus is an effective ba...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L31/18H01L31/0236
CPCH01L31/02363H01L31/1804H01L31/1868Y02E10/547Y02P70/50
Inventor 励小伟梁海赖儒丹周涛铭胡巧张小明
Owner 宁波乐丰新能源有限公司
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