Method for preparing hydroxylation graphene oxide-magnesium titanate/silver molybdate composite materials

A composite material, graphene technology, applied in chemical instruments and methods, metal/metal oxide/metal hydroxide catalysts, chemical/physical processes, etc., can solve the problem of low processing efficiency, limited adsorption capacity, and difficulty in composite pollution remediation Large and other problems, to achieve the effect of strong adsorption, simple operation and efficient treatment

Active Publication Date: 2017-01-25
江苏长三角环境科学技术研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the complex adsorption, chemical and microbial interactions between heavy metals and organic pollutants, compound pollution is much more difficult than single-factor pollution remediation.
[0003] The sheet structure of graphene oxide contains highly active oxygen-containing functional groups such as hydroxyl groups and a high specific surface area, which can effectively remove organic matter-heavy metal complex pollutants in the medium, but its adsorption capacity is li

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] The preparation method of hydroxylated graphene oxide-magnesium titanate / silver molybdate composite material comprises the following steps:

[0022] Step 1: Preparation of Hydroxylated Graphene Oxide

[0023] (1) First, 2.0g graphene oxide, 1.0gP 2 o 5 , 1.0g Na 2 S 2 o 8 and 10 mL concentrated H 2 SO 4 After mixing evenly, heat to 85°C in a water bath, react for 8 hours, and place it for 12 hours after cooling. Repeatedly wash with ultrapure water to remove residual acid, ultrasonicate at 60°C for 5h, then vacuum dry at 65°C, add the dried crystals to 120mL of concentrated H 2 SO 4 , then add 2.0gKNO 3 , and vibrate in the oscillator for 5h, then add 0.5L water, control the temperature at 85°C to react, continue to shake for 3h, wash repeatedly with hydrochloric acid (mass percentage concentration 5-20%) and ultrapure water, and then ultrasonicate at 50°C 5h, obtain the graphene oxide that concentration is 5g / L after constant volume;

[0024] (2) Take 2g of ...

Embodiment 2

[0034] Step 1: Preparation of Hydroxylated Graphene Oxide

[0035] (1) First, 3.0g graphene oxide, 1.5gP 2 o 5 , 1.5gNa 2 S 2 o 8 and 10 mL concentrated H 2 SO 4 After mixing evenly, heat to 95°C in a water bath, react for 10 hours, and place it for 12 hours after cooling. Repeatedly wash with ultrapure water to remove residual acid, sonicate at 80°C for 8h, then vacuum-dry at 85°C, add the dried crystals to 200mL of concentrated H 2 SO 4 , then add 3.5gKNO 3 , and shake in the oscillator for 10h, then add 1.0L water, control the temperature at 95°C to react, continue to shake for 8h, wash repeatedly with hydrochloric acid (mass percentage concentration 5-20%) and ultrapure water, and then ultrasonic at 80°C 8h, obtain the graphene oxide that concentration is 10g / L after constant volume;

[0036] (2) The bromoethane that takes 5g is dissolved in the volume concentration of 50mL and is 1:1 ammoniacal liquor, after dissolving, add in the graphene oxide gained in step (...

Embodiment 3

[0046] Step 1: Preparation of Hydroxylated Graphene Oxide

[0047] (1) First, 4.0g graphene oxide, 2.0gP 2 o 5 , 2.0g Na 2 S 2 o 8 and 15 mL concentrated H 2 SO 4 After mixing evenly, heat to 95°C in a water bath, react for 12 hours, and place it for 12 hours after cooling. Repeatedly wash with ultrapure water to remove residual acid, ultrasonicate at 80°C for 8h, and then vacuum-dry at 85°C, add the dried crystals to 200mL of concentrated H 2 SO 4 , then add 3.5gKNO 3 , and shake in the oscillator for 10h, then add 1.0L water, control the temperature at 95°C to react, continue to shake for 10h, wash repeatedly with hydrochloric acid (mass percentage concentration 5-20%) and ultrapure water, and then ultrasonic at 80°C 5 to 8 hours, after constant volume, graphene oxide with a concentration of 10g / L was obtained;

[0048] (2) The bromoethane that takes 5g is dissolved in the volume concentration of 50mL and is 1:1 ammoniacal liquor, after dissolving, add in the graph...

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Abstract

The invention relates to a method for preparing hydroxylation graphene oxide-magnesium titanate/silver molybdate composite materials. The hydroxylation graphene oxide-magnesium titanate/silver molybdate composite materials are mainly used for treating sewage organic matter/heavy metal combined pollution. The method has the advantages that the shortcoming of limited sewage organic matter/heavy metal combined pollution treatment effects in the prior art can be overcome; graphene oxide grafted groups are subjected to hydroxylation modification treatment, so that the absorption capacity of the hydroxylation graphene oxide-magnesium titanate/silver molybdate composite materials can be improved, and the organic pollutant degradation capacity of the hydroxylation graphene oxide-magnesium titanate/silver molybdate composite materials can be greatly improved by magnesium titanate/silver molybdate photocatalysts; the hydroxylation graphene oxide-magnesium titanate/silver molybdate composite materials have excellent organic matter and heavy metal adsorption functions, organic pollutants can be effectively degraded by the hydroxylation graphene oxide-magnesium titanate/silver molybdate composite materials, and the hydroxylation graphene oxide-magnesium titanate/silver molybdate composite materials are easy to operate and efficient in treatment.

Description

technical field [0001] The invention belongs to the technical field of water pollution control engineering, and in particular relates to a preparation method of a hydroxylated graphene oxide-magnesium titanate / silver molybdate composite material. Background technique [0002] With the development of pesticide, metallurgy, electroplating and other industries, more and more organic pollutants and heavy metals enter the water environment, resulting in the decline of agricultural product quality and ecological damage, and ultimately seriously affecting human health. Pollutants in the water environment mainly include heavy metals and organic pollutants, which show the characteristics of coupled and compound pollution over time. Due to the complex adsorption, chemical and microbial interactions between heavy metals and organic pollutants, compound pollution is much more difficult than single-factor pollution remediation. [0003] The sheet structure of graphene oxide contains hig...

Claims

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Application Information

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IPC IPC(8): B01J23/68C02F1/28C02F1/30
CPCB01J23/686B01J35/004C02F1/288C02F1/30C02F2305/10
Inventor 钟晓梅唐晓声何云霞徐翔
Owner 江苏长三角环境科学技术研究院有限公司
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