This invention belongs to the field of
refractory materials technology, and relates to a magnesia-carbon core
nozzle raw material composition and
mass percentage as follows: 55-70% magnesia aggregate with a particle size of 1-0.047mm, 15-30%
magnesium titanate with a particle size <0.047mm, 9-12%
flake graphite with a particle size of 0.1-0.3mm, 2-3% carbon
fiber powder with a particle size <0.047mm, and 1-3%
antioxidant with a particle size <0.047mm; the bonding
system of the magnesia-carbon core
nozzle consists of phenolic resin
powder,
lithium carbonate, and
furfural; after the raw materials and bonding
system are mixed and granulated in a high-speed mixer, the billet is dried and the volatile matter is controlled appropriately, then added to the core
nozzle mold for medium static pressure molding, and after demolding, the billet is cured and then heat-treated; during the heat treatment process, the magnesia aggregate and the
magnesium titanate as the matrix are... m MgO· n TiO2
fine powder undergoes a
solid-
phase reaction, MgO+ m MgO· n TiO2→ x MgO· y TiO2, where 0.5 < x / y ≤2,
magnesium oxide aggregate diffuses into the matrix through
solid-
phase diffusion, forming reactive annular gaps. This invention improves the mechanical properties and
thermal shock resistance of the material.