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Environment-friendly coal-water slurry and its production method

A coal-water slurry, environment-friendly technology, applied in the field of coal chemical industry, can solve the problem of high production cost, and achieve the effect of low cost, good fluidity and good dispersion effect

Active Publication Date: 2017-10-31
SHANDONG UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The present invention aims at the problem that the existing coal-water slurry has high production cost and needs to add a certain amount of dispersant, and provides an environment-friendly coal-water slurry with low production cost and no need to add dispersant and its production method. Weathered coal is the main raw material dispersant, and industrial alkali slag is used as a stabilizer through modification. The production cost is low and the fluidity is good. The environment-friendly coal-water slurry does not produce hard precipitation after long-term storage, and is environmentally friendly and pollution-free.

Method used

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  • Environment-friendly coal-water slurry and its production method
  • Environment-friendly coal-water slurry and its production method
  • Environment-friendly coal-water slurry and its production method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] The environment-friendly coal-water slurry includes: 600g of long-flame coal, 350g of water, 60g of weathered coal-water slurry with dispersing effect, and 4g of stabilizer.

[0054] The production method of above-mentioned environment-friendly type coal-water slurry is as follows:

[0055] Step 1: 120g of weathered coal with a humic acid content of 42%, 30g of NaOH for industrial use, 0.8g of polyoxyethylene sorbitol, 1g of sodium benzenesulfonate, and 250g of water are added to the coal-water slurry ball mill through the feed port. Under the condition of 50°C, the ball milling slurry was made for 1.5 hours. After ball milling, the proportion of weathered coal particles with a particle size of less than 200 mesh was 85%, and the weathered coal-water slurry with dispersing effect was obtained. The weathered coal-water slurry with dispersing effect passed through the outlet Feed mouth enters in the dispersant storage tank and stores, and the weathered coal-water slurry w...

Embodiment 2

[0062] The environment-friendly coal-water slurry includes: 650g of gas coal, 350g of water, 60g of weathered coal-water slurry with dispersing effect, and 5g of stabilizer.

[0063] The production method of above-mentioned environment-friendly type coal-water slurry is as follows:

[0064] Step 1: Add 140g of weathered coal with a humic acid content of 38%, 28g of NaOH for industrial use, 0.9g of polyoxyethylene sorbitol, 1.2g of sodium benzenesulfonate, and 260g of water into the coal-water slurry ball mill through the feed port. Under the condition of 50°C, ball milling pulping for 2 hours, after ball milling, the proportion of weathered coal particles with particle size less than 200 mesh is 90%, and weathered coal-water slurry with dispersing effect is obtained, and the weathered coal-water slurry with dispersing effect passes through the outlet Feed mouth enters in the dispersant storage tank and stores, and the weathered coal-water slurry with dispersing effect obtained...

Embodiment 3

[0071] The environment-friendly coal-water slurry includes: 650g of long-flame coal, 350g of water, 70g of weathered coal-water slurry with dispersing effect, and 8g of stabilizer.

[0072] The production method of above-mentioned environment-friendly type coal-water slurry is as follows:

[0073] Step 1: 120g of weathered coal with a humic acid content of 45%, 26g of industrial NaOH, 0.7g of polyoxyethylene sorbitol, 0.9g of sodium benzenesulfonate, and 230g of water are added to the coal-water slurry ball mill through the feed port. Under the condition of 50 ℃, ball milling pulping for 1 hour, after ball milling, the proportion of weathered coal particles with particle size less than 200 mesh is 85%, and the weathered coal water slurry with dispersing effect is obtained, and the weathered coal water slurry with dispersing effect passes through the outlet Feed mouth enters storage in the dispersant storage tank, gets the weathered coal-water slurry with dispersing effect that...

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Abstract

The invention relates to environment-friendly coal water slurry and a production method thereof. The environment-friendly coal water slurry comprises the following materials in parts by weight: 60-70 parts of bitumite, 20-40 parts of water, 3-10 parts of weathered coal water slurry with a dispersion effect and 0.05-1 part of a stabilizer, wherein the weathered coal water slurry with the dispersion effect comprises the following materials in parts by weight: 25-40 parts of weathered coal with humic acid content not less than 30%, 1-20 parts of industrial NaOH, 60-80 parts of water, 0.1-0.5 part of sorbitol polyethenoxy ether and 0.1-0.5 part of sodium benzenesulfonate; and the stabilizer comprises the following materials in parts by weight: 5-10 parts of industrial alkali waste, 30-80 parts of water and 0.1-5 parts of sodium carboxymethyl cellulose. The environment-friendly coal water slurry provided by the invention requires no additional dispersing agent, the oxidized ingredients, including rich humic acid, and the like, in the weathered coal, are fully utilized through different-quality blended coals, and a dispersing agent type coal water slurry additive is prepared according to an alkali neutralizing principle, so that the environment-friendly coal water slurry has an excellent flowing property and a sulfur fixation function and can solve the problem of higher production cost of the coal water slurry in the prior art.

Description

technical field [0001] The invention belongs to the technical field of coal chemical industry, and in particular relates to an environment-friendly coal-water slurry and a production method thereof. Background technique [0002] Coal-water slurry is a coal-based liquid fuel that emerged in the 1970s. It can be used as a furnace fuel or a raw material for syngas, and has the advantages of stable combustion and low pollution emissions. Coal water slurry is a mixture of coal powder with a certain particle size, water and a small amount of dispersant in a certain proportion. The production process of coal water slurry is that coal, water and dispersant are slurried in a ball mill. After reaching a certain particle size and viscosity requirements, a small amount of stabilizer is added to form a two-phase coal-water slurry, and then enters the storage tank for standby. On the basis of maintaining the original physical and chemical properties of coal, coal water slurry also has go...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10L1/32C10L1/24C10L1/198C10L1/12C10L1/192
CPCC10L1/106C10L1/12C10L1/1216C10L1/192C10L1/1985C10L1/2443C10L1/326
Inventor 高洪阁王志文高明洋
Owner SHANDONG UNIV OF SCI & TECH
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