Ba hetero atom-containing LTL molecular sieve as well as preparation method and application thereof
A technology of molecular sieves and heteroatoms, applied in Ba heteroatom-containing LTL molecular sieves and its preparation and application fields, can solve the problems of limited industrial application and poor stability of single-function catalysts, and achieve good crystallinity, high single-pot yield, and good The effect of applying the foreground
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[0055] Example 1
[0056] Add 39.1g KOH and 45.2g aluminum hydroxide to 900g deionized water, stir evenly, transfer to a four-necked flask and react for 12h at 80°C. After cooling to room temperature, clear KAlO is obtained. 2 Solution, K in the aluminum source solution 2 O:Al 2 O 3 The molar ratio is 1.1:1. Slowly add 345.3g silica sol (SiO 2 The content is 30wt%), and the initial sol is obtained after vigorous stirring. Take 31.2g Ba(NO 3 ) 2 Dissolve 34g ethanol in 350g deionized water to make a barium source solution. The barium source solution was slowly dropped into the sol and continued to stir vigorously. After aging at 30°C for 16 hours, it was transferred to a dynamic kettle and reacted at 130°C for 20 hours. After the crystallization is completed, the reactant is cooled to room temperature, filtered, washed with deionized water to neutrality, and dried to obtain the LTL zeolite containing Ba.
[0057] Among them, the amount of aluminum hydroxide is Al 2 O 3 Calculated,...
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[0059] Example 2
[0060] Add 31.1g KOH and 45.2g aluminum hydroxide to 850g deionized water, stir evenly, transfer to a four-necked flask, react at 60℃ for 14h, and cool to room temperature to obtain clear KAlO 2 Solution, K in the aluminum source solution 2 O:Al 2 O 3 The molar ratio is 0.8:1. Slowly add 345.3g silica sol (SiO 2 The content is 30wt%), and the initial sol is obtained after strong stirring. Take 35.2g Ba(NO 3 ) 2 Dissolve 68 g of ethanol in 450 g of deionized water to make a barium source solution. The barium source solution was slowly dropped into the sol and continued to stir vigorously. After aging at 20°C for 20 hours, it was transferred to an autoclave and reacted at 120°C for 48 hours. After the crystallization is completed, the reactant is cooled to room temperature, filtered, washed with deionized water to neutrality, and dried to obtain the LTL zeolite containing Ba.
[0061] Among them, the amount of aluminum hydroxide is Al 2 O 3 Calculated, the amount...
Example Embodiment
[0063] Example 3
[0064] Add 36.1g KOH and 45.2g aluminum hydroxide to 650g deionized water, stir evenly, transfer to a four-necked flask, react at 70℃ for 13h, and cool to room temperature to obtain clear KAlO 2 Solution, K in the aluminum source solution 2 O:Al 2 O 3 The molar ratio is 0.9:1. Slowly add 362.8g silica sol (SiO 2 The content is 30wt%), and the initial sol is obtained after vigorous stirring. Take 41.2g Ba(OH) 2 ·8H 2 0 and 68 g of ethanol were dissolved in 450 g of deionized water to prepare a barium source solution. The barium source solution was slowly dropped into the sol and continued to stir vigorously. After aging at 30°C for 24 hours, it was transferred to an autoclave and reacted at 140°C for 38 hours. After the crystallization is completed, the reactant is cooled to room temperature, filtered, washed with deionized water to neutrality, and dried to obtain the LTL zeolite containing Ba.
[0065] Among them, the amount of aluminum hydroxide is Al 2 O 3 Ca...
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