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A kind of elastic conductive nanofiber yarn and preparation method thereof

A nanofiber, elastic and conductive technology, applied in the field of flexible electrode preparation, can solve the problems of high cost, complicated carbon nanotube fiber preparation process, non-continuous production, etc., to overcome poor flexibility, good carbon tube adsorption effect, and improve mechanical properties and the effect on electrical properties

Active Publication Date: 2018-11-30
ZHENGZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to their excellent electrical conductivity and high strength, carbon nanotube fibers are often used as substrates to prepare elastic conductive fibers by impregnating polymer solutions and polymers. However, the preparation process of carbon nanotube fibers is complicated and the cost is high. Continuous production, thus restricting the expansion of its application

Method used

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  • A kind of elastic conductive nanofiber yarn and preparation method thereof
  • A kind of elastic conductive nanofiber yarn and preparation method thereof
  • A kind of elastic conductive nanofiber yarn and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] An elastic conductive nanofiber yarn device such as figure 1 As shown, it includes a high-voltage power supply 1, a spraying device 2, a water bath receiving device 3, an ultrasonic device 4, a cleaning device 5, a heating device 6, a winding collection device 7 and five godet rollers; wherein, the high-voltage power supply 1 is connected to the spraying device 2 The spinneret 8 and the spraying device 2 are adjustable in height. The horizontal distance from the spinneret 8 of the spraying device 2 to the inner wall of the water bath receiving device 3 is controlled at 2 to 10 cm, and the vertical distance is controlled at 5 to 30 cm. The water bath receiving device 3 is located at the Below the device 2; the ultrasonic device 4 includes two ultrasonic machines, in each ultrasonic machine, the first glass bend 14 and the second glass bend 15 are respectively fixed, the first glass bend 14 holds the MWNTs aqueous dispersion, The SWNTs aqueous dispersion is filled in the ...

Embodiment 2

[0044] Raw material source:

[0045] Thermoplastic Polyurethane (TPU): Density 1.12g / cm 3 , Germany BASF Polyurethane Co., Ltd.;

[0046] Surfactant sodium dodecyl sulfate (SDS) is chemically pure, whiteness 60%, Sinopharm Chemical Reagent Co., Ltd.;

[0047] Single-walled carbon nanotubes (SWNTs) are high-purity single-walled carbon nanotubes, and the product label is TNSR; carboxylated multi-walled carbon nanotubes (MWNTs) are high-purity multi-walled carbon nanotubes, and the product label is TNMC5; Chemical Limited;

[0048] N,N-Dimethylformamide (DMF) is analytically pure, content ≥ 99.5%, Tianjin Fuyu Fine Chemical Co., Ltd.;

[0049] The tetrahydrofuran (THF) is analytically pure, with a content ≥ 90%, from Tianjin Fuyu Fine Chemical Co., Ltd.;

[0050] The high voltage power supply is Dongwen High Voltage Power Supply (Tianjin) Co., Ltd.

[0051] The structural parameters of the elastic conductive nanofiber yarn device are: the horizontal distance from the tip of ...

Embodiment 3

[0063] Raw material source:

[0064] Thermoplastic Polyurethane (TPU): Density 1.12g / cm 3 , Germany BASF Polyurethane Co., Ltd.;

[0065] Surfactant sodium dodecyl sulfate (SDS) is chemically pure, whiteness 60%, Sinopharm Chemical Reagent Co., Ltd.;

[0066] Single-walled carbon nanotubes (SWNTs) are high-purity single-walled carbon nanotubes, and the product label is TNSR; carboxylated multi-walled carbon nanotubes (MWNTs) are high-purity multi-walled carbon nanotubes, and the product label is TNMC5; Chemical Limited;

[0067] N,N-Dimethylformamide (DMF) is analytically pure, content ≥ 99.5%, Tianjin Fuyu Fine Chemical Co., Ltd.;

[0068] The tetrahydrofuran (THF) is analytically pure, with a content ≥ 90%, from Tianjin Fuyu Fine Chemical Co., Ltd.;

[0069]The high voltage power supply is Dongwen High Voltage Power Supply (Tianjin) Co., Ltd.

[0070] The structural parameters of the elastic conductive nanofiber yarn device are: the horizontal distance from the tip of t...

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Abstract

The invention relates to a continuous preparation method and application of high-elasticity electric-conductive fiber years. The electric-conductive nano-fiber yarns are composed of carbon nano tubes and TPU elastic nano-fiber yarns. According to the invention, an electrostatic spinning device is applied at first, and water bath is used for collection, so the continuous TPU elastic nano-fiber yarns could be prepared. For the purpose of making the nano-fiber yarns electrical-conductive, the fiber yarns are made to absorb carboxylation MWNTs and then absorb unmodified SWNTs through ultrasonic absorption. Two types of carbon tubes could react with a substrate and could react with each other, so the continuous elastic nano-fiber yarns with high electric conductivity is prepared. The elastic yarns have higher electric conduction performance than fiber yarns prepared through separate absorption of the MWNTs and SWNTs. The yarns are characterized by high elasticity, high electric conductivity, stretchability, linear knitting performance and so forth; and the yarns have extensive potential application in wearable electronic devices and have bright application prospect in fields such as electromagnetic shielding, static resistance, sensors and flexible energy devices.

Description

technical field [0001] The invention belongs to the flexible electrode preparation technology, and in particular relates to an elastic conductive nano yarn spinning device, an elastic conductive nano fiber yarn and a preparation method thereof. Background technique [0002] With the development of science and technology, the development trend of electronic devices is miniaturization and flexibility. In recent years, small fiber-shaped electronic devices have received extensive attention from the scientific and industrial circles and have been developed rapidly. Many fiber-shaped electronic devices It has been prepared, including supercapacitors, solar cells, organic light-emitting diode field-effect transistors, sensors, etc., and has been widely used in antistatic textiles, explosion protection, and electromagnetic shielding. The effective conductive channel in the polymer conductive fiber material can respond quickly and reversibly under the stimulation of external conditi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01D5/00D01D1/02D06M11/74D06B13/00D06M101/30
CPCD01D1/02D01D5/0046D01D5/0076D06B13/00D06M11/74D06M2101/30
Inventor 郑国强李亚红白冉代坤王波阮春蕾刘春太
Owner ZHENGZHOU UNIV
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