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Water-based epoxy anti-corrosion primer

An anti-corrosion primer, water-based epoxy technology, applied in anti-corrosion coatings, epoxy resin coatings, coatings, etc., can solve the problems of poor leveling, low product solid content, narrow use surface, etc., to achieve good film appearance, Good corrosion protection, no VOC emissions

Inactive Publication Date: 2017-05-10
福建百花化学股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The current customer still uses solvent-based epoxy coatings, which need to add 30-50% organic solvents during production and use, which seriously pollutes the environment and affects the health of construction workers; and the main problems of water-based epoxy coatings developed and produced at this stage are: 1. Single function, narrow use area, lack of versatility; 2. Corrosion inhibitors and co-solvents need to be added, otherwise the product is prone to problems such as poor leveling, pinholes, edge shrinkage, and rust when used on steel structures; 3. Products The solid content is low, and the non-volatile content of water-based products currently stays at about 40%; 4. Some water-based epoxy products only meet the requirements of the experimental stage, and cannot meet the requirements in actual production and application; 5. There is no advantage in high prices; therefore, The development of water-based epoxy anti-corrosion coatings is the necessity of social and environmental protection and development

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Primer Example 1, component A modified amine curing agent 15%, deionized water 29.3%, talc powder 15%, iron red 25%, aluminum tripolyphosphate 5%, zinc phosphate 10%, defoamer 0.2% , Leveling agent 0.5%, total 100%. Stir evenly according to A:B=10:4.5, and test according to industry standards: the appearance of the coating film is iron red, flat and smooth, surface dry 1h, hard dry 6h, solid content 62.32%, bending test 2mm, impact 50cm, scratch test level 0, The flash rust inhibition is normal, the water resistance is 240h, and the salt water resistance is 144h without exception, and the heavy metal meets the requirements of GB18581-2009.

[0024] Primer Example 2, component A is modified amine curing agent 15%, deionized water 29.2%, titanium dioxide 8%, zinc phosphate 10%, aluminum tripolyphosphate 5%, talcum powder 17%, heavy calcium 15% , defoamer 0.2%, leveling agent 0.6%, total 100%. Stir evenly according to A:B=10:4.5: the appearance of the coating film is gra...

Embodiment 3

[0025] Primer Example 3: Component A is 15% of modified amine curing agent, 30% of deionized water, 10% of titanium dioxide, 20% of zinc phosphate, 5% of aluminum tripolyphosphate, 10% of talcum powder, and 10% of heavy calcium , totaling 100%. Stir evenly according to A:B=10:4.5: Since no defoamer and leveling agent are added, the appearance of the coating film is uneven with bubbles and shrinkage cavities, surface dry 1h, hard dry 6h, solid content 61.21%, water resistance, salt water resistance Rust and blisters appear.

[0026] It can be known from the unqualified conditions of the primer that if the modified amine curing agent, defoamer, and leveling agent are not in the scope, and the usage ratio does not pass the equivalent calculation, the manufactured product cannot meet the standard requirements.

[0027] Operation process: Component B, add the formula amount of deionized water and emulsifier into the stainless steel reactor, disperse evenly, slowly add liquid epoxy r...

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PUM

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Abstract

The invention discloses a water-based epoxy anti-corrosion primer which consists of a component A and a component B, wherein the component A is prepared from the following raw materials in percentage by weight: 10 to 20 percent of a modified amine hardener, 25 to 40 percent of deionized water, 5 to 30 percent of pigment, 15 to 35 percent of a filler, 5 to 15 percent of an antirust pigment, 0.1 to 0.4 percent of a defoaming agent and 0.3 to 0.8 percent of a leveling agent; the component B is prepared from the following raw materials in percentage by weight: 10 percent of an emulsifier, 50 percent of liquid epoxy resin, 39.8 percent of deionized water and 0.2 percent of a defoaming agent; the quality indexes are as follows: the fineness is less than or equal to 15 [mu]m, the epoxy value is 0.28 to 0.30, and the solid content is 55 + / - 2 percent. The invention further discloses a processing method. The primer is solvent-free and can realize odorlessness and zero discharge; a paint film can be naturally dried, smooth, flat and compact; solvent discharge is eliminated in storage, transportation and use processes; the performance meets the requirements of the standard HG / T4759-2014.

Description

technical field [0001] The invention belongs to the technical field of industrial anticorrosion coatings, and relates to a two-component water-based epoxy anticorrosion primer. Background technique [0002] There are the following four technologies close to the present invention. [0003] 1. A water-based epoxy anti-corrosion coating and its preparation method, application number: CN201410480505.2, which discloses a water-based epoxy anti-corrosion coating, including epoxy resin, composite iron-titanium powder, silicon carbide, aluminum tripolyphosphate, iron oxide Red, talcum powder, mica powder, deionized water, butyl acrylate, curing agent, wetting agent, dispersant, defoamer and corrosion inhibitor; the preparation method is: deionized water, wetting agent, dispersant, The foaming agent is added to the disperser according to the preset mass ratio, followed by adding composite iron-titanium powder, aluminum tripolyphosphate, iron oxide red, talc powder, and mica powder t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/00C09D5/08C09D7/12C09D7/00
CPCC09D163/00C08K3/26C08K3/30C08K3/32C08K3/34C08K2003/265C08K2003/3045C08K2003/321C08K2003/327C09D5/084C09D7/20C09D7/61
Inventor 吴远光
Owner 福建百花化学股份有限公司
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