Phosphate mineral inhibitor as well as preparation method and use thereof
A technology of phosphorous acid, which is used in the field of phosphate mineral inhibitor-N-naphthyl-α-aminoaryl phosphonic acid compound, can solve the problems of high acid ion content, weak inhibition ability, scaling of equipment and pipelines, etc. Achieve the effect of high separation efficiency, strong inhibition and simple process
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Example Embodiment
[0023] Embodiment 1, a kind of N-naphthyl-α-amino arylphosphonic acid: its general molecular formula is such as formula ( ) as shown:
[0024]
[0025] in:
[0026] R 1 is H, F, Cl, Br or C 1~4 Hydrocarbyl;
[0027] R 2 It is phenyl, benzyl, phenethyl, styryl or phenyl, benzyl, phenethyl and styryl with various substitutions. The N-naphthyl-α-aminoarylphosphonic acid is prepared by mannich reaction of 1-naphthylamine, aromatic aldehyde and phosphorous acid under acidic conditions. The molar ratio of raw material 1-naphthylamine, aromatic aldehyde, phosphorous acid and concentrated hydrochloric acid is 1:1:1:0.9.
Example Embodiment
[0028] Embodiment 2, in a kind of N-naphthyl-α-amino arylphosphonic acid described in embodiment 1, the mol ratio of raw material 1-naphthylamine, aromatic aldehyde, phosphorous acid, concentrated hydrochloric acid is 1: 1.4: 1.4: 1.1. The rest are the same as in Example 1.
Example Embodiment
[0029] Embodiment 3, in a kind of N-naphthyl-α-amino arylphosphonic acid described in embodiment 1, the mol ratio of raw material 1-naphthylamine, aromatic aldehyde, phosphorous acid, concentrated hydrochloric acid is 1:1.1:1.1: 1. The rest are the same as in Example 1.
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