Polyurethane resin used for breathable insole as well as preparation method and application
A polyurethane resin and resin technology are applied to the polyurethane resin for breathable insole and the fields of preparation and application, which can solve the problem of high production cost and achieve the effects of low cost, excellent air permeability and better physical properties
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Embodiment 1
[0055] 58.8kg of polyoxyethylene-oxypropylene trihydric alcohols (number-average molecular weight is 6000), 65.9kg of polyoxypropylene trihydric alcohols (number-average molecular weight is 1000), 152.4kg of styrene graft copolymerized polyoxyethylene-oxypropylene Trihydric alcohol (the number average molecular weight is 6000), 1.39kg ethylene glycol, the ethylene glycol solution of the triethylenediamine of 0.22kg, the bis(dimethylaminoethyl) ether of 0.89kg 70wt% and 30wt% ash A solution made of dipropylene glycol, 2.77kg of water and 0.28kg of silicone foam stabilizer were reacted at 50°C for 2.5h, cooled to 45°C, and mixed for 1.0h to obtain polyurethane resin component A.
[0056] With 60.0kg of diphenylmethane diisocyanate, 20.0kg of carbodiimide modified diphenylmethane diisocyanate, 1.0kg of polyoxyethylene-oxypropylene trihydric alcohol (number average molecular weight is 6000) and 0.002kg of Phosphoric acid was reacted at 75°C for 2 hours to obtain component B1 of po...
Embodiment 2
[0060]58.8kg of polyoxyethylene-oxypropylene trihydric alcohols (number-average molecular weight is 6000), 65.9kg of polyoxypropylene trihydric alcohols (number-average molecular weight is 1000), 152.4kg of styrene graft copolymerized polyoxyethylene-oxypropylene Trihydric alcohol (the number average molecular weight is 6000), 1.39kg ethylene glycol, the ethylene glycol solution of the triethylenediamine of 0.22kg, the bis(dimethylaminoethyl) ether of 0.89kg 70wt% and 30wt% ash A solution made of dipropylene glycol, 2.77kg of water and 0.28kg of silicone foam stabilizer were reacted at 50°C for 2.5h, cooled to 45°C, and mixed for 1.0h to obtain polyurethane resin component A.
[0061] With 9.19kg of diphenylmethane diisocyanate, 3.06kg of carbodiimide modified diphenylmethane diisocyanate, 0.15kg of polyoxyethylene-oxypropylene trihydric alcohol (number average molecular weight is 6000) and 0.00032kg of Phosphoric acid was reacted at 75°C for 2 hours to obtain component B1 of ...
Embodiment 3
[0065] The polyoxyethylene-propylene oxide trihydric alcohol of 48.08kg (the number average molecular weight is 10000), the polyoxypropylene trihydric alcohol of 120.19kg (the number average molecular weight is 5000), the acrylonitrile graft copolymerization polyoxyethylene oxide-propylene oxide of 33.66kg Trihydric alcohol (the number average molecular weight is 10000), 2.02kg ethylene glycol, the ethylene glycol solution of the triethylenediamine of 1.01kg, the bis (dimethylaminoethyl) ether of 70wt% and 30wt% ash of 1.01kg The solution made of dipropylene glycol, 3.03 kg of water and 4.04 kg of silicone foam stabilizer were reacted at 50° C. for 2.5 hours, cooled to 40° C., and mixed for 1.5 hours to obtain the polyurethane resin component A.
[0066] With 50.8g of diphenylmethane diisocyanate, 12.7kg of carbodiimide modified diphenylmethane diisocyanate, 12.7kg of polyoxyethylene-oxypropylene trihydric alcohol (number average molecular weight is 10000) and 0.002kg of Phosp...
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