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High-temperature-resistant anti-oxidation paint for ZrN-SiAlON-based stainless steel

An anti-oxidation coating, stainless steel technology, applied in the direction of fireproof coatings, coatings, etc., can solve the problems of poor chemical stability, easy cracking and falling off, etc., achieve low thermal expansion rate, not easy to crack and fall off, improve high temperature resistance and chemical stability Effect

Inactive Publication Date: 2017-05-24
长兴天晟能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to overcome the problems of poor chemical stability and easy cracking and falling off of existing stainless steel high-temperature heating protective coatings, and provide a high-temperature-resistant and anti-oxidation coating for ZrN-SiAlON-based stainless steel with good high temperature resistance and adhesion

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A ZrN-SiAlON-based high-temperature and anti-oxidation coating for stainless steel, consisting of the following raw materials in parts by weight: 30 parts of ZrN-SiAlON powder, 3 parts of manganese dioxide, 20 parts of composite binder, 0.5 parts of potassium fluoroborate, carbonized 0.5 parts of boron, and the particle size of each of the above components is 300-500 mesh.

[0033] Among them, the ZrN-SiAlON powder is prepared by the following method:

[0034] (1) The weight parts are respectively 4 parts of alumina powder, 10 parts of zircon, and 30 parts of carbon black. The mass ratio to water is 1.5:1;

[0035] (2) Dry mix the mixture after step (1) freeze-drying for another 20 minutes;

[0036] (3) The dry-blended mixture was pressed into shape at a pressure of 70 MPa, and then placed in a microwave high-temperature atmosphere furnace, and kept at 1400 ° C for 5 hours. During the heat preservation process, flowing nitrogen gas was introduced at a flow rate of 0.5...

Embodiment 2

[0046] A ZrN-SiAlON-based high-temperature and anti-oxidation coating for stainless steel, consisting of the following raw materials in parts by weight: 40 parts of ZrN-SiAlON powder, 4 parts of manganese dioxide, 25 parts of composite binder, 1 part of potassium fluoroborate, carbonized 1 part of boron, the particle size of each of the above components is 300-500 mesh.

[0047] Among them, the ZrN-SiAlON powder is prepared by the following method:

[0048] (1) The weight parts are respectively 7 parts of alumina powder, 12 parts of zircon, and 35 parts of carbon black. The mass ratio to water is 1.7:1;

[0049] (2) Dry mix the mixture after step (1) freeze-drying for another 25 minutes;

[0050] (3) The dry-blended mixture was pressed into shape at a pressure of 75MPa, and then placed in a microwave high-temperature atmosphere furnace, and kept at 1500°C for 7 hours, and flowing nitrogen was introduced during the heat preservation process, with a flow rate of 1L / min;

[00...

Embodiment 3

[0060] A ZrN-SiAlON-based high-temperature and anti-oxidation coating for stainless steel, consisting of the following raw materials in parts by weight: 50 parts of ZrN-SiAlON powder, 5 parts of manganese dioxide, 30 parts of composite binder, 1.5 parts of potassium fluoroborate, carbonized 1.5 parts of boron, the particle size of the above components is 300-500 mesh.

[0061] Among them, the ZrN-SiAlON powder is prepared by the following method:

[0062] (1) The weight parts are respectively 8 parts of alumina powder, 15 parts of zircon, and 45 parts of carbon black. The mass ratio with water is 2:1;

[0063] (2) Dry mix the mixture after step (1) freeze-drying for another 30 minutes;

[0064] (3) The dry-blended mixture was pressed into shape at a pressure of 80 MPa, then placed in a microwave high-temperature atmosphere furnace, and kept at 1600°C for 8 hours, and flowing nitrogen gas was introduced during the heat preservation process, with a flow rate of 2L / min;

[006...

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Abstract

The invention discloses high-temperature-resistant anti-oxidation paint for ZrN-SiAlON-based stainless steel. The paint is prepared from, by weight, 30-50 parts of ZrN-SiAlON powder, 3-5 parts of manganese dioxide, 20-30 parts of composite adhesive, 0.5-1.5 parts of potassium borofluoride and 0.5-1.5 parts of boron carbide. The ZrN-SiAlON material serves as filler, and the high temperature resistance and chemical stability of the paint are improved. The composite adhesive is prepared from phthalocyanine resin prepolymer, so that the stability and viscosity of the adhesive at high temperature are improved, a coating is not likely to crack or fall off, and the high temperature resistance and oxidation resistance of the coating are enhanced. The provided paint can be sprayed or coated on the surface of billet steel from room temperature to 500 DEG C, and after hot processing, the coating can naturally fall off in the cooling process.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a high-temperature and oxidation-resistant coating for ZrN-SiAlON-based stainless steel. Background technique [0002] In the current steel rolling process, whether it is ordinary steel or special steel, during heat treatment processes such as rolling, forging, quenching, annealing, and normalizing, surface oxidation is prone to occur under high temperature, and it will also be accompanied by alloy elements. depletion and decarbonization. This phenomenon directly restricts the improvement of rolled steel yield and affects the surface quality of finished steel. At present, there are high-temperature coating method, vacuum method and protective atmosphere method to prevent iron and steel products from oxidation and burning. The vacuum method and the protective atmosphere method are to place the steel products in a vacuum environment or an inert gas protection environment for hea...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D179/04C09D5/20C09D7/12C08G73/06
CPCC08G73/0672C08K3/00C08K3/22C08K3/34C08K2003/2262C08K2201/014C09D5/18C09D5/20C09D7/61C09D179/04
Inventor 佘海中
Owner 长兴天晟能源科技有限公司