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Treatment method of phenol-cyanogen wastewater generated by coal gas producer

A technology of gas generator and treatment method, which is applied in biological water/sewage treatment, multi-stage water treatment, water/sewage treatment, etc., can solve the problem of unstable treatment effect of biochemical treatment method, large investment in coal-water slurry preparation system, Deal with high cost problems, achieve obvious economic and environmental benefits, avoid inhibition, and reduce pollution

Inactive Publication Date: 2017-05-31
SICHUAN NORMAL UNIVERSITY
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AI Technical Summary

Problems solved by technology

The biochemical treatment method has unstable treatment effect and high cost; although the separate incineration method has a good treatment effect, the treatment cost is high; the coal-water slurry preparation system of the coal-water slurry treatment method has a large investment, and many manufacturers do not have this system, so it is difficult implement

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0007] Example 1: Treat 1m per day 3 Phenol cyanide wastewater (pH8.3, COD Cr 8200mg / L, volatile phenol 930mg / L, CN - 4.0mg / L, T-N128mg / L), after iron-manganese-zinc composite powder reduction (add 5g of iron-manganese-zinc composite powder per liter of wastewater, time 30min, 25°C, CO 2 Pressure 0.1MPa, ultrasonic power input per cubic meter of wastewater 4kW), hydrolytic acidification (24h, pH6.0), aerobic biochemical (12h) and activated carbon biological filter tower (hydraulic load is 40m 3 / m 2 .d, the total thickness of activated carbon is 2m) treatment, the effluent water quality is COD Cr 45mg / L, CN - 0.09mg / L, volatile phenol 0.19mg / L, T-N 12mg / L.

Embodiment 2

[0008] Embodiment 2: 20m is processed every day 3 Phenol cyanide wastewater (pH8.2, COD Cr 7800mg / L, volatile phenol 760mg / L, CN - 4.2mg / L, T-N112mg / L), after iron-manganese-zinc composite powder reduction (add 10g of iron-manganese-zinc composite powder per liter of wastewater, time 10min, 45°C, CO 2 Pressure 0.3MPa, ultrasonic power input per cubic meter of wastewater 2kW), hydrolytic acidification (8h, pH8.0), aerobic biochemical (8h) and porous ceramsite biological filter tower (hydraulic load 100m 3 / m 2 .d. The total thickness of porous ceramsite is 4m), and the effluent quality is COD Cr 42mg / L, CN - 0.05mg / L, volatile phenol 0.16mg / L, T-N9mg / L.

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Abstract

The invention provides a treatment method of phenol-cyanogen wastewater generated by a coal gas producer. The method comprises the treatment work procedures of filtration, CO2 pressurized iron manganese and zinc composite powder reduction under the ultrasonic wave effect, precipitation, hydrolytic acidification, aerobic treatment, biological filtration tower treatment and the like; the treated wastewater can be stably discharged in a standard reaching manner.

Description

technical field [0001] The invention relates to a treatment method for phenol cyanide wastewater produced by a gas generator. Background technique [0002] Coal gas is a kind of fuel widely used in production and life. It is produced from coal through a series of chemical reactions in a gas generator. In the process of preparing cold gas, phenol-cyanide wastewater (wastewater containing phenol and cyanide) will inevitably be produced. If the wastewater is directly discharged into the environment, it will cause serious pollution to the environment. At present, the treatment methods of phenol cyanide wastewater mainly include biochemical treatment method, separate incineration method, coal water slurry treatment method and raw material treatment method mixed into drying tower. The biochemical treatment method has unstable treatment effect and high cost; although the separate incineration method has a good treatment effect, the treatment cost is high; the coal-water slurry pre...

Claims

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Application Information

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IPC IPC(8): C02F9/14C02F101/30C02F101/34C02F101/18
CPCC02F1/36C02F1/66C02F1/705C02F3/02C02F3/28C02F3/34C02F9/00C02F2003/001C02F2003/003C02F2101/18C02F2101/345C02F2101/40C02F2301/046C02F2301/08C02F2303/24
Inventor 龙炳清唐勇胡德军
Owner SICHUAN NORMAL UNIVERSITY
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