Silver paste used for printing crystalline silicon solar cell and preparation method for silver paste
A technology of solar cells and crystalline silicon, which is applied in the direction of cable/conductor manufacturing, circuits, electrical components, etc., can solve the problems affecting the processing cost of silver paste, and achieve the effect of improving photoelectric conversion efficiency, reducing processing cost, and good electrical conductivity
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[0046] The preparation method step of silver paste for printing of crystalline silicon solar cell of the present invention is as follows:
[0047] a, weigh the above-mentioned raw materials according to the proportioning ratio;
[0048] (1) Preparation of slurry A
[0049] b1, the PbO, SiO 2 , B 2 o 3 , TeO 2 and other inorganic oxides are evenly mixed, and placed in a ceramic crucible for drying;
[0050] c1. Put the mixture obtained in step b1 into a muffle furnace for smelting for 1-2 hours, then extract it with water and dry it for later use;
[0051] d1. Grind the mixture obtained in step c1 with a planetary ball mill for 1-3 hours, then dry and sieve to obtain slurry A glass powder;
[0052] e1. Weigh the slurry A thickener, thixotropic agent, slurry A organic solvent and organic additives in proportion, and stir at room temperature until they are evenly mixed, then raise the ambient temperature to 80-120°C, and continue After stirring for 60-90 minutes, the slurr...
Embodiment 1
[0063] The silver paste for crystalline silicon solar cell printing of the present invention comprises: paste A and paste B, paste A includes silver-coated copper powder, paste A glass powder and paste A organic carrier, and the content of each component is calculated by mass percentage They are: silver-coated copper powder 90%; slurry A glass powder 5%; slurry A organic vehicle 5%, slurry B includes silver powder, slurry B glass powder and slurry B organic vehicle, and the content of each component is based on mass The percentages are: silver powder 95%; paste B glass powder 1%; paste B organic vehicle 4%.
[0064] The silver-coated copper powder of the paste A has a silver content of 50% and a particle size of 0.2 micron, and the silver powder of the paste B has a particle size of 0.1 micron. And the paste A glass powder is PbO-SiO 2 -B 2 o 3 -TeO 2 The system is a mixture that is mixed and melted in any proportion, and the paste B glass powder is Bi 2 o 3 -SiO 2 -B ...
Embodiment 2
[0083] The silver paste for crystalline silicon solar cell printing of the present invention comprises: paste A and paste B, paste A includes silver-coated copper powder, paste A glass powder and paste A organic carrier, and the content of each component is calculated by mass percentage They are: silver-coated copper powder 80%; slurry A glass powder 3%; slurry A organic vehicle 17%, slurry B includes silver powder, slurry B glass powder and slurry B organic vehicle, and the content of each component is based on mass The percentages are: silver powder 85%; slurry B glass powder 2%; slurry B organic vehicle 13%.
[0084] The silver-coated copper powder of the paste A has a silver content of 20% and a particle size of 0.5 microns, and the silver powder of the paste B has a particle size of 0.3 microns. And the paste A glass powder is PbO-SiO 2 -B 2 o 3 -TeO 2 The system is a mixture that is mixed and melted in any proportion, and the paste B glass powder is Bi 2 o 3 -SiO ...
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