Flexible non-volatile memory based on black phosphorus quantum dots and preparation method of flexible non-volatile memory
A technology of black phosphorus quantum and quantum dots, which is applied in the field of flexible non-volatile memory based on black phosphorus quantum dots and its preparation, can solve the problems of non-volatile memory such as poor mechanical properties, insufficient stability, and difficult regulation, and achieve The effects of controllable electrical performance, controllable storage performance, and easy regulation
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Embodiment 1
[0068] Transfer 6 mg of black phosphorus material powder to a 40 ml scintillation tube in a nitrogen box, then add 20 ml of N-methyl-2-pyrrolidone to obtain a 0.3 mg / ml black phosphorus powder solution, and add ethylene glycol to the black phosphorus powder solution amine, in a sealed state for 2 hours in a water bath to prepare an organic solution of black phosphorus quantum dots; on the PE plastic substrate, a 100nm thick aluminum electrode is used to form a metal film bottom electrode through a mask in the form of thermal evaporation, and on the metal film bottom Spin-coat polymethyl methacrylate on the electrode to form the first polymer layer, and then anneal at 100°C for 1 h; spin-coat an organic solution of black phosphorus quantum dots on the annealed first polymer layer to form black phosphorus quantum dots. Dot layer; spin-coat polymethyl methacrylate on top of the black phosphorus quantum dot layer to form a second polymer layer; on the second polymer layer, a 100nm ...
Embodiment 2
[0070] Transfer 6 mg of black phosphorus material powder to a 40 ml scintillation vial in a nitrogen box, then add 30 ml of N-methyl-2-pyrrolidone to obtain a 0.2 mg / ml black phosphorus powder solution, and add hydroboration to the black phosphorus powder solution The organic solution of black phosphorus quantum dots was prepared by ultrasonication in a water bath in a sealed state for 1 hour; an 80nm thick copper electrode was used on the PE plastic substrate to form the bottom electrode of the metal film through a mask in the form of thermal evaporation, and the bottom electrode of the metal film was formed on the bottom of the metal film. Spin-coat polystyrene on the electrode to form the first polymer layer, and then anneal at 90°C for 2 hours; spin-coat black phosphorus quantum dot organic solution on the annealed first polymer layer to form a black phosphorus quantum dot layer; Spin-coat polystyrene on the black phosphorus quantum dot layer to form a second polymer layer;...
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