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Nano-calcium plastic biodegradation composite resin and preparation and use method thereof

A biodegradable and composite resin technology, applied in the field of composite materials, can solve the problems of large amount of addition, high high-temperature carbonization rate, and low physical performance indicators of degraded plastic products, so as to improve quality and flexibility, improve comprehensive performance, and degradability adjustable effect

Active Publication Date: 2017-06-09
西安普草瑞珊生物科技有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The application of simple chitosan has a large amount of addition and a high high-temperature carbonization rate, and its physical performance indicators for degradable plastic products are low; chitosan derivatives are mainly side chain derivatives, and their physical performance indicators for degradable plastic products are low. The rate is high, and obvious carbonization can be seen in the product

Method used

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  • Nano-calcium plastic biodegradation composite resin and preparation and use method thereof
  • Nano-calcium plastic biodegradation composite resin and preparation and use method thereof
  • Nano-calcium plastic biodegradation composite resin and preparation and use method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Take 0.5 kg of KV-environmentally friendly plastic biodegradable element and mix it with 99.5 kg of nano-modified plastic composite material. Under the condition of 100 ° C, mix and stir at 150 rpm for 10 minutes, extrude and granulate, and obtain nano-calcium plastic biological Degradation of composite resin particles; (1) Take 5kg of the particles and 95kg of polyethylene to blow the film; (2) Take the particles of 30kg and 70kg of polyethylene to blow the film; (No: JQ2004-250W) and Xianyang City Product Quality and Technical Supervision Institute (No: Xianjian 2004-B096), the product meets the national GB13735-1992 quality standard. The results are as follows:

[0024]

[0025] The obtained degradable plastic film can be used for covering plastic film, nursery stock conservation bag and water-saving bag. In Tongchuan, Chang'an, Ganxian, Shaanxi, Lanzhou, Urumqi, Harbin and other places, different crop experiments such as nursery seedling cultivation, watermelon ...

Embodiment 2

[0027] Take 5kg of KV-environmentally friendly plastic biodegradable element and mix it with 95kg of nano-modified plastic composite material, and mix and stir at 180 rpm for 6 minutes at 110°C to extrude and granulate to obtain nano-calcium plastic biodegradable composite resin Particles; (1) take 10kg of the particles and 90kg of polyethylene to mix and blow the film, and the obtained degradable plastic film is tested to meet the national quality standard of GB13735-1992; (2) take the particles of 40kg and 60kg of polyethylene to mix and blister, and the prepared degradable plastic Products (disposable daily necessities and medical supplies, disposable food containers, medicine bottles and other packaging containers) have been tested and conform to the national GB18006.1-2009 technical standard and GB15980-1995 hygienic standard.

Embodiment 3

[0029] Mix 15kg of KV-environmentally friendly plastic biodegradable element with 85kg of nano-modified plastic composite material, and mix and stir at 150 rpm for 10 minutes at 130°C to extrude and granulate to obtain nano-calcium plastic biodegradable composite resin Granules, take 15kg of the granules and mix them with 85kg polyethylene to blow the film, and the obtained degradable plastic film is tested to meet the national standards GB13735-1992, GB18006.1-2009, GB / T4456-1996, GB / T10457-1989, GB / T1004 -2008, and YBB00132002.

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Abstract

The invention relates to a nano-calcium plastic biodegradation composite resin. The composite resin is prepared from 0.5 to 20% of KV-environment-friendly plastic biodegradation cellulose and 80 to 99.5% of a nano-calcium modified plastic composite material, and under the condition of 100 to 130 DEG C, granulation via plastic extrusion is performed by mixing and stirring at 150 to 200rpm; then 1 to 65% of particles manufactured and 35 to 99% of polyethylene, polyvinyl chloride or polypropylene are mixed, and different degradable plastic products can be prepared. According to the composite resin, biological waste and natural calcium carbonate are taken as main raw materials, the distribution is wide, and the resources are rich; the preparing operation of the composite resin is simple and convenient, an original process does not need to be changed, and a plasticizer is not used; the degradability is controllable, a product only needs simple packaging, and can be stored for 3 years in a dry and lucifugal condition, the storage cost is low, and the production cost is equivalent to that of a common plastic product; compared with the prior art, the product performance is improved obviously and the composite resin has no toxicity, so that the composite resin is suitable for preparation of degradable plastic products which take polyethylene, polyvinyl chloride and polypropylene as raw materials, the quality and flexibility of the products are improved, and the degradable plastics are favorably used widely.

Description

technical field [0001] The invention belongs to the technical field of composite materials, and in particular relates to a nano-calcium plastic biodegradable composite resin and a preparation and use method thereof. Background technique [0002] According to the market research firm Markets & Markets report: By 2019, the market value of the biodegradable plastics industry will grow at an average annual growth rate of 13.01% to 3.477 billion US dollars. Mainly used in four aspects of packaging, fiber, agriculture and injection molding. In 2011, the total output of biodegradable plastic products in my country was about 450,000 tons, a year-on-year increase of about 30%. [0003] Biodegradable plastics include various types. Starch-modified series products are used the most, but they are not suitable for degradable plastic film. In 2009, 323,000 tons were produced and used worldwide. It is estimated that by 2020, the global usage will reach one million tons. There are not ma...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/04C08L3/02C08L5/08C08L23/06C08L27/06C08L23/12C08K3/26
Inventor 张君曼张晗王静婉陈淑茗李红辉李利军张磊王菁苋卢美欢马世鹏
Owner 西安普草瑞珊生物科技有限责任公司
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