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Method for Co-production of Chromium Salt and Electrode Material from Electric Arc Furnace Dust

A technology of electric arc furnace dust and electrode materials, applied in battery electrodes, chemical instruments and methods, circuits, etc., can solve the problems of limited use development, complex dust composition, and inability to achieve full use of dust, to eliminate secondary pollution, The effect of obvious modification effect and simple and feasible implementation process

Active Publication Date: 2019-04-02
JIANGSU UNIV OF SCI & TECH IND TECH RES INST OF ZHANGJIAGANG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the early days, the electric arc furnace dust was mainly treated by vitrification and then landfilled. After mixing the electric arc furnace dust with clay or silica, aluminum oxide and other fluxes, it was smelted at 1100-1200 °C, and the output met the requirements of the environment. The dense and stable solidified slag that protects the standard cannot realize the full utilization of dust, and there is still a large amount of industrial waste slag after recycling valuable metals
[0008] At the same time, dust treatment cannot copy the treatment method of iron and steel metallurgical production waste slag. This is because the dust composition is relatively more complex, especially it contains a large amount of heavy metals. Developing a method for comprehensive treatment of dust has important theoretical and practical significance for the recycling of metallurgical waste, the development of high value-added products, the improvement of the comprehensive utilization of dust, the exploration of new application fields and even large-scale production

Method used

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  • Method for Co-production of Chromium Salt and Electrode Material from Electric Arc Furnace Dust
  • Method for Co-production of Chromium Salt and Electrode Material from Electric Arc Furnace Dust
  • Method for Co-production of Chromium Salt and Electrode Material from Electric Arc Furnace Dust

Examples

Experimental program
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Effect test

Embodiment 1

[0050] Take 20g of dust and grind it with a grinder for 4 hours; put the dust in a 1L beaker, add water and stir vigorously, put the supernatant after standing for 2 hours in another container, add fresh water to the dust, repeat the above Operate until the supernatant is colorless, filter, and save the filter cake and filtrate; place the filter cake in an oven and dry at room temperature; put the dried dust in fresh water again, add water and stir vigorously, let stand, and filter Pour the filtrate of the above filtrate into the above filtrate, and dry the filter cake again at room temperature; put all the above filtrates in an evaporator, set the temperature at 100°C, and evaporate the water to dryness, the obtained crystals are the product chromium salts, and the obtained crystals are chromium Potassium chromate and sodium chromate, the extraction rate of chromium is more than 80%, and the chromium salt is mainly potassium chromate and sodium chromate, with a purity of more ...

Embodiment 2

[0052] Take 20g of dust and grind it with a grinder for 4 hours; put the ground dust in a beaker, add water and stir vigorously and let it stand, pour out the upper layer filtrate and put it in another beaker, then add fresh water to the dust, repeat the above operation, Until the upper filtrate is colorless; filter, save the filter cake and filtrate, mix all the above filtrates, and dry the filter cake at 120°C; place the dried dust in fresh water again, add water and stir vigorously, then let it stand, and filter the filtrate Pour it into the above filtrate, and dry the filter cake at 120°C again; put all the above filtrate in an evaporator, set the temperature at 120°C, and evaporate the water in it, and the obtained crystal is a mixture of potassium chromate and sodium chromate, The purity is above 75%, and the extraction rate of chromium is above 78%. Put the above-mentioned dried filter cake in a grinder and grind for 2 hours, then add nickel oxide, wherein the molar rati...

Embodiment 3

[0054] Take 20g of dust and grind it with a grinder for 4 hours; put the dust in a 1L beaker, add water and stir vigorously, put the upper filtrate poured out after standing for 2 hours in another container, then add fresh water to the dust, repeat the above operation , until the upper filtrate is colorless, filter, save the filter cake and filtrate; dry the filter cake at room temperature; place the dried dust in fresh water again, add water and stir vigorously and let it stand, pour the filtered filtrate into the above filtrate, and Dry the filter cake at room temperature again; put all the above-mentioned filtrates in an evaporator, set the temperature at 50°C, and evaporate the water to dryness, the obtained crystals are potassium chromate and sodium chromate, the extraction rate of chromium is more than 80%, and the chromium salt is mainly It is potassium chromate and sodium chromate with a purity of more than 72%; the above-mentioned dried filter cake is placed in a grind...

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Abstract

The invention discloses a method for co-producing chromium salt and an electrode material by electric arc furnace dust. The method includes the following steps: first, grinding raw materials; second, stirring, standing, filtering and separating filtrate and dust filter residues; third, drying the dust filter residues, continuing adding water and stirring and separating the dust filter residues and the water; fourth, adding one of transition metal oxide, transition metal salt, rare-earth element oxide or rare-earth element salt and continuing grinding; fifth, performing heating and modification by calcination; sixth, continuing washing, drying and grinding modified dust to obtain the electrode material; seventh, combining the filtrate to obtain chromium salt extracting solution, and performing evaporative crystallization to obtain the chromium salt and reusable evaporated liquid. The industrial waste electric arc furnace dust serves as a raw material, resources are efficiently and completely used by a simple and feasible process, waste is turned into wealth, zero discharge of waste is realized, secondary pollution is greatly relieved and even eliminated, and the method has huge economic benefits and market prospect.

Description

technical field [0001] The invention relates to the technical field of dust comprehensive utilization, in particular to a method for preparing chromium salts and electrode materials using electric arc furnace dust as raw materials. Background technique [0002] With the rapid development of industrial production, the types and quantities of industrial solid waste continue to increase. As a pillar industry of my country's national construction, the iron and steel industry produces a large amount of waste residue, waste water, and smoke during its production process. However, the domestic treatment methods for iron and steel solid waste are not fully mature, and the waste composition is complex, so the amount of treatment is very small. Most of the solid waste is stacked in the open air or landfilled, which not only occupies land resources, but also causes serious pollution to the environment. endanger people's health. In recent years, with the country's increasing emphasis ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/48
CPCC01G37/00H01M4/48H01M10/0525H01M10/4235Y02E60/10
Inventor 白妮徐玉松金云学王淑艳居殿春张艳
Owner JIANGSU UNIV OF SCI & TECH IND TECH RES INST OF ZHANGJIAGANG
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