Preparation method of sludge-based charcoal slow-release phosphate fertilizer and sludge-based charcoal slow-release phosphate fertilizer

A technology of biochar and sludge, which is applied in the direction of phosphate fertilizer, ammonium orthophosphate fertilizer, pyrolysis treatment sludge, etc., can solve the problems of multi-energy and economic cost, high energy consumption of slow-release fertilizer, difficult process control, etc., and achieve shortening The effect of high treatment cycle, high treatment efficiency and high solid yield

Inactive Publication Date: 2017-08-01
SHENZHEN INST OF ADVANCED TECH +1
View PDF3 Cites 24 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these current methods have disadvantages. For high-temperature incineration and thermal cracking, the raw materials need to be dried in advance. However, the current moisture content of most municipal sludge is still as high as 80%. The basic requirements of the basic requirements, it needs to consume more energy and economic costs for high-intensity drying treatment; for microbial fermentation, the treatment cycle is longer, so the process is difficult to control
That is to say, the current method of preparing biochar from sludge has high energy consumption and long treatment cycle, resulting in high cost and difficult process control
This further leads to higher energy consumption and longer treatment cycle when using sludge to prepare slow-release fertilizer, which leads to higher cost and difficult control of the process

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0023] The preparation method of the sludge-based biochar slow-release phosphate fertilizer of the embodiment of the present invention comprises the following steps:

[0024] S1: Add a conditioner to the sludge and stir evenly to obtain conditioned sludge.

[0025] Specifically, in the embodiment of the present invention, the water content of the sludge is 50-85wt%, and the added weight of the conditioner is 0.5%-10% of the dry solid weight of the sludge. The conditioner is steel slag waste, KOH, CaO, CaCO 3 、Al 2 o 3 , ZnCl 2 A mixture of one or more of inorganic conditioners. In the embodiment of the present invention, adding a conditioner to the sludge for conditioning can increase the porosity of the sludge, thereby making the reaction of the sludge in the subsequent steps more sufficient, thereby obtaining a higher yield of sludge-based biochar.

[0026] S2: Put the conditioned sludge into a hydrothermal reactor, seal it, and heat it for hydrothermal carbonization re...

Embodiment 1

[0041] S1: Add steel slag to the domestic sludge with a water content of 85wt%. The amount of steel slag added is 5.0% of the dry solid weight of the sludge. Stir evenly to obtain conditioned sludge.

[0042] S2: Put the conditioned sludge into a hydrothermal reactor, seal it, and microwave-assisted heating for hydrothermal carbonization reaction, wherein the microwave power is 400W, the reaction temperature is controlled at 200°C, the reaction time is 90min, and the hydrothermal carbonization reaction is carried out. The pressure inside the reactor is 2.4Mpa, and a hydrothermal carbonization liquid is obtained.

[0043] S3: The hydrothermal carbonization liquid is centrifuged at 3500 r / min for solid-liquid separation, and the separated solid product is washed three times with water, and dried in an oven at 50° C. to obtain sludge-based biochar.

[0044] S4: Place the sludge-based biochar in a potassium dihydrogen phosphate solution with a concentration of 200ppm, the solid-to...

Embodiment 2

[0047] S1: Dosing Al mixed in a 1:1 weight ratio to domestic sludge with a moisture content of 85wt% 2 o 3 and ZnCl 2 The mixed conditioner, the dosage of the mixed conditioner is 7.5% of the dry solid weight of the sludge, and the mixed conditioner is evenly stirred to obtain the conditioned sludge.

[0048] S2: Put the conditioned sludge into the hydrothermal reactor, seal it, and feed N 2 , wherein the reaction temperature is controlled at 250°C, the reaction time is 150min, and the pressure inside the hydrothermal reactor is about 5.0Mpa to obtain the hydrothermal carbonization liquid.

[0049] S3: The hydrothermal carbonization liquid is centrifuged at 3500 r / min for solid-liquid separation, and the separated solid product is washed three times with water, and dried in an oven at 50° C. to obtain sludge-based biochar.

[0050] S4: Place the sludge-based biochar in a diammonium phosphate solution with a concentration of 500ppm, the solid-to-liquid ratio of the sludge-ba...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a preparation method of a sludge-based charcoal slow-release phosphate fertilizer, which comprises: adding a conditioner into sludge, and uniformly stirring to obtain conditioned sludge; placing the conditioned sludge into a hydrothermal reactor, sealing, and heating to perform a hydrothermal carbonization reaction so as to obtain hydrothermal carbonated solution; carrying out solid-liquid separation on the hydrothermal carbonated solution, washing a solid product, and drying at a temperature of 40 to 60 DEG C to obtain sludge-based charcoal; placing the sludge-based charcoal into phosphate solution, after oscillating for 16 to 48h at a speed of 100 to 200r/min, carrying out solid-liquid separation, and drying a solid product at a temperature of 40 to 60 DEG C to obtain the sludge-based charcoal slow-release phosphate fertilizer. The invention further discloses a sludge-based charcoal slow-release phosphate fertilizer. The preparation method of the sludge-based charcoal slow-release phosphate fertilizer, which is disclosed by the invention, is low in cost, high in processing efficiency and high in solid yield; the charcoal slow-release phosphate fertilizer disclosed by the invention is slowly released, effectively prevents pollution of the fertilizer to the environment, and can improve solid and prevent soil hardening.

Description

technical field [0001] The invention relates to the field of regeneration treatment and resource utilization of sludge, in particular to a preparation method of sludge-based biochar slow-release phosphate fertilizer and sludge-based biochar slow-release phosphate fertilizer. Background technique [0002] With the development of urbanization and the improvement of sewage treatment capacity, urban surplus sludge as a by-product of sewage treatment plants has increasingly become a new problem that cannot be ignored. According to statistics, as of June 2015, Guangdong Province has built a total of 487 sewage treatment facilities, with a daily processing capacity of 24.13 million tons, and an annual sludge production of about 3.62 million tons (water content 80%). There are still nearly 50 sewage treatment facilities in the province. % sludge still to be treated. Sludge is the final product of the sewage treatment process. The water content of most municipal sludge is still as h...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/04C02F11/10C10B53/00C05G3/80
CPCC02F11/10C05B1/02C05B7/00C05G3/80C10B53/00C05D9/00C05D9/02C05D3/02
Inventor 费颖恒赵丹
Owner SHENZHEN INST OF ADVANCED TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products