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Preparation method of ASA (acrylonitrile styrene acrylate copolymer) composite material applicable to 3D printing

A composite material and 3D printing technology, applied in the field of ASA composite materials, can solve the problems of low melt strength, poor aging resistance, moisture absorption tendency, etc., to reduce hollow and warping deformation, improve mechanical properties, and strong weather resistance Effect

Inactive Publication Date: 2017-08-11
HEILONGJIANG XINDA ENTERPRISE GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] (3) The melt has high viscosity and poor fluidity, and it is easy to block the nozzle during printing, causing machine failure;
[0008] (4) poor thermal stability, moisture absorption tendency, poor aging resistance, and poor product stability;
[0010] (1) The gas is highly toxic and can cause cancer;
[0011] (2) The processing temperature is 200°C, and the shrinkage rate is low, but the effect of printing larger-sized products is not good;
[0012] (3) With low melt strength, the surface gloss of the printed model is better, but it is easy to block the nozzle;
[0013] (4) Because the domestically produced materials are shoddy, it mainly relies on foreign imports, which are expensive

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Take 68% ASA resin, 23% AS resin powder, 5% calcium carbonate, 0.2% antioxidant DSTP, 0.3% anti-ultraviolet agent UV-531, 2% toner titanium dioxide, 1.5% lubricant stearic acid. Put it into a high-speed mixer for 30 seconds, repeat the mixing 3 times, and then add it to a flat twin-screw extruder to extrude at 220°C, the screw speed is 280rpm, and the ASA composite material is obtained after cooling.

Embodiment 2

[0034] Take 70% ASA resin, 20% AS resin powder, 6% calcium carbonate, 0.2% antioxidant DSTP, 0.3% anti-ultraviolet agent UV-531, 2% toner titanium dioxide, 1.5% lubricant stearic acid. Put it into a high-speed mixer for 30 seconds, repeat the mixing 3 times, and then add it to a flat twin-screw extruder to extrude at 220°C, the screw speed is 280rpm, and the ASA composite material is obtained after cooling.

Embodiment 3

[0036] Take 69% ASA resin, 22% AS resin powder, 5% calcium carbonate, 0.2% antioxidant 3114, 0.3% anti-ultraviolet light stabilizer 292, 2% toner iron oxide red, 1.5% lubricant EBS. Put it into a high-speed mixer for 30 seconds, repeat the mixing 3 times, and then add it to a flat twin-screw extruder to extrude at 220°C, the screw speed is 280rpm, and the ASA composite material is obtained after cooling.

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PUM

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Abstract

The invention provides an ASA (acrylonitrile styrene acrylate copolymer) composite material applicable to 3D printing. The ASA composite material is prepared from components in percentage by mass as follows: 50%-70% of ASA resin, 20%-30% of AS resin powder, 5%-12% of inorganic filler, 0.1%-0.5% of an antioxidant, 0.1%-0.5% of an anti-ultraviolet agent, 2%-4% of toner and 1%-2% of a lubricant. The molding process of the ASA composite material is simple, mechanical property and material quality stability are greatly improved and optimized when compared with those of traditional ABS (acrylonitrile-butadiene-styrene) and PLA (polylactic acid) materials for 3D printing, production rate of inferior-quality products with hollow defect, buckling deformation and the like during 3D printing is reduced, the actual application value is higher, and applicable range is wider.

Description

technical field [0001] The invention relates to an ASA composite material, in particular to an ASA composite material for 3D printing and a preparation method thereof. Background technique [0002] With the gradual increase in the market share of 3D printing, the performance of its manufactured products also meets different requirements in different fields. They need to be more durable in different environments, and have the necessary UV resistance and weather resistance. In order to adapt to the market In order to compete, the manufacturing cost also needs to be reduced. The effect of 3D printing mainly depends on the quality of the consumables used. Materials that can be widely used in 3D printing technology must at least meet the following requirements: no pungent smell during printing, strong fluidity after melting, certain weather resistance, certain mechanical properties, different colors can be equipped, reasonable price, etc. . [0003] Among the 3D printing techno...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L51/00C08L25/12C08K13/02C08K3/26C08K3/22C08K5/09C08K5/098
Inventor 佟喜国刘刚林航
Owner HEILONGJIANG XINDA ENTERPRISE GRP
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