Adhesive capable of preventing ceramic tiles from hollowing or falling off, its preparation method and application
A technology of adhesive and antifreeze, applied in the direction of adhesive, adhesive type, grafted polymer adhesive, etc. The effect of low water absorption performance and good bond strength
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[0019] The invention provides a binder. The raw material components of the binder include: 80-100 parts by weight of aqueous acrylate copolymer emulsion, 0.2-0.5 parts by weight of hydroxyethyl cellulose ether, anionic surface active 0.5 to 1.5 parts by weight of antifreeze, 1 to 3 parts by weight of antifreeze, 1 to 3 parts by weight of defoamer, 1.5 to 2.5 parts by weight of bactericide and 1 to 2 parts by weight of thickener; wherein, the anionic surfactant is selected from ten One or more of sodium dialkylbenzene sulfonate, sodium lauryl sulfate, sodium ethoxylated alkyl sulfate and ammonium ethoxylated alkyl sulfate; the antifreeze is selected from ethylene glycol, propylene glycol, One or more of isobutanol, urea and glycerol; the defoamer is selected from one or more of silicone defoamers, n-butanol, n-pentanol and n-octanol; the bactericide is selected from Benzoic Acid, Sodium Benzoate, Sorbic Acid, Potassium Sorbate, Calcium Propionate, Dehydroacetic Acid, Paraben, E...
Embodiment 1
[0026] This embodiment provides a kind of adhesive, and raw material component is calculated by weight, comprises:
[0027] 80 parts by weight of aqueous acrylate copolymer emulsion, 0.5 parts by weight of hydroxyethyl cellulose ether, anionic surfactant (by sodium dodecylbenzenesulfonate and ethoxylated alkylammonium sulfate with a mass ratio of 1:1 Mixed) 0.5 parts by weight, 3 parts by weight of antifreeze (ethylene glycol), 1 part by weight of defoamer (n-butanol), bactericide (by sodium benzoate, sorbic acid and salicylic acid in 1:3:2 The mass ratio of mixing) 2.5 parts by weight and thickener (xanthan gum) 1 parts by weight;
[0028] Among them, the water-based acrylate copolymer emulsion is composed of methyl methacrylate (acrylic acid monomer), vinyl-terminated polydimethylsiloxane (functional polysiloxane), vinyltrimethoxysilane (organic silicon Monomer) obtained by emulsion polymerization with a mass ratio of 45:20:1; the preparation method of the aqueous acrylate ...
Embodiment 2
[0033] This embodiment provides a kind of adhesive, and raw material component is calculated by weight, comprises:
[0034] 100 parts by weight of aqueous acrylate copolymer emulsion, 0.2 parts by weight of hydroxyethyl cellulose ether, 1.5 parts by weight of anionic surfactant (sodium lauryl sulfate), 1 part by weight of antifreeze (ethylene glycol), defoamer (N-amyl alcohol) 3 parts by weight, bactericide (benzoic acid and potassium sorbate mix with the mass ratio of 1:3) 1.5 parts by weight and thickener (magnesium aluminum silicate) 2 parts by weight;
[0035] Among them, the water-based acrylate copolymer emulsion is composed of methyl methacrylate (acrylic acid monomer), vinyl-terminated polydimethylsiloxane (functional polysiloxane), vinyltrimethoxysilane (organic silicon Monomer) obtained by emulsion polymerization at a mass ratio of 55:30:1; the preparation method of the aqueous acrylate copolymer emulsion comprises the following steps: acrylic acid and / or acrylate mo...
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