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A method for preparing zinc-based alloys from zinc-containing waste materials

A technology for scrap and alloy, applied in the field of zinc-based alloy preparation from zinc-containing scrap, can solve the problems of low product purity, inability to meet production requirements, poor quality, etc.

Active Publication Date: 2019-03-29
河北长力环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] With the continuous development of the world economy, the global zinc consumption has increased significantly, and the demand for zinc alloys is increasing day by day. However, zinc mineral resources on the earth are limited, and relying solely on traditional raw materials can no longer meet production needs.
Moreover, the cost of high-purity zinc oxide and zinc ingots is relatively high, and there is a problem of low product purity in the recycling of zinc-containing waste in the prior art, and the use in the preparation of zinc-based alloys will result in high alloy impurity content and poor quality, which cannot meet the requirements. Requirements

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0073] (1) The zinc-containing waste is mixed with water and then pelletized to obtain raw material wet pellets.

[0074]Zinc-containing waste includes zinc ash and gas mud with a mass ratio of 1.5:1, and the zinc content is 35%; after the zinc-containing waste is mixed with water, a wet material with a water content of 20% is obtained; the wet material is transported through the conveyor belt to the mixing ball Feeding machine, through the rotation of the drum, the mixture is made into a spherical shape; the ball forming rate is 94.8%, and the ball forming speed is 0.94mm·min - 1 , the ball size is 12mm, the ball making time is 23 minutes, the wet bulb compressive strength is 1417N / piece, and the burst temperature is 210℃.

[0075] (2) calcining raw material wet balls to obtain raw material dry balls.

[0076] The raw material wet ball was dried at 250°C for 30min, and then roasted at 1100°C for 60min to obtain the raw material dry ball; The dry ball compressive strength i...

Embodiment 2

[0109] The same method as in Example 1 is adopted, except that the zinc content in the zinc-containing waste in step (1) is 50%, and the moisture content of the raw material wet bulb is 25%; ; The reduction temperature in step (3) is 1100°C.

[0110] For the ZnAl prepared in this example 4 Cu 3 The composition of the alloy was tested, and the results were as follows:

[0111] element

Al

Cu

Mg

Zn

Fe

Pb

Cd

Sn

content / %

4.3

1.1

0.06

margin

0.035

0.004

0.003

0.0015

[0112] The experimental results show that the ZnAl prepared in this example 4 Cu 3 The alloy composition is uniform and conforms to the standard of "Zinc Alloy Ingots for Casting" (GB / T8738-2006).

[0113] The tensile strength of the prepared alloy is 350MPa, the elongation is 4%, and the impact toughness is 100J.

Embodiment 3

[0115] The same method as in Example 1 is adopted, except that the zinc content in the zinc-containing waste in step (1) is 40%, and the moisture content of the raw material wet bulb is 23%; ; The reduction temperature in step (3) is 1200°C.

[0116] For the ZnAl prepared in this example 4 Cu 3 The composition of the alloy was tested, and the results were as follows:

[0117] element

Al

Cu

Mg

Zn

Fe

Pb

Cd

Sn

content / %

4.1

1.0

0.04

margin

0.035

0.004

0.003

0.0015

[0118] The experimental results show that the ZnAl prepared in this example 4 Cu 3 The alloy composition is uniform and conforms to the standard of "Zinc Alloy Ingots for Casting" (GB / T8738-2006).

[0119] The tensile strength of the prepared alloy is 348MPa, the elongation is 3.8%, and the impact toughness is 97J.

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Abstract

The invention provides a method for preparing zinc-based alloy from zinc-containing waste materials. According to the method for preparing the zinc-based alloy from the zinc-containing waste materials, zinc oxide is prepared with the zinc-containing waste materials as raw materials, so that the problem that the difficulty of recovering zinc from the waste materials is large is solved; the zinc alloy is directly produced by using the zinc-containing waste materials, high-purity zinc oxide can be directly produced without purchasing zinc oxide powder or zinc ingots, and the production process requirements of the zinc-based alloy can be met; and a zinc liquid is prepared from the zinc oxide, the operation of carrying out smelting after zinc ingot making is not required, alloy raw materials are directly added into the zinc liquid to prepare the zinc-based alloy, and therefore the preparation process is emitted, the alloy components are ensured to be more uniform, and the alloy quality is higher. Experimental results show that the method provided by the invention is simple in process, and prepared zinc alloy components for casting ZnAl4Cu3 meet the GB / T8738-2006 requirements.

Description

technical field [0001] The invention relates to the technical field of metal material recycling, in particular to a method for preparing zinc-based alloys from zinc-containing wastes. Background technique [0002] Zinc and zinc alloys are widely used and occupy an important position in the national economy. Especially in recent years, the application of this metal in galvanizing, alloys, castings, compounds, zinc sheets, chemical industry, metallurgy, aerospace, automobile and human health has become more eye-catching. Zinc alloy is an alloy composed of zinc and other alloying elements, which plays an important role in the application of zinc. The purity of zinc alloy has a great influence on the properties of the alloy. Therefore, the existing technology for producing zinc alloy is to directly use high-purity zinc oxide or zinc ingot as raw material, and smelt it together with other alloying elements. [0003] With the continuous development of the world economy, the glob...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C1/02C22C18/00C22B1/02C22B1/24C22B19/20
CPCC22B1/02C22B1/2406C22B19/20C22C1/02C22C18/00
Inventor 李国强赵强
Owner 河北长力环保科技有限公司