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A preparing method of a cyanate resin composite

A technology of cyanate resin and composite materials, which is applied in the field of preparation of cyanate resin composite materials with anti-light aging performance. It can solve the problems of molecular chain breakage, crosslinking, chemical bond destruction, color change, etc., and achieve good light aging resistance. , The preparation process is simple and the effect of good manufacturability

Inactive Publication Date: 2017-09-26
WEIHAI GUANGWEI COMPOSITES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although ultraviolet light only accounts for about 5% of sunlight, its energy is very large, and its energy is enough to destroy the chemical bonds of the polymer, causing its molecular chains to break and crosslink, resulting in a malignant change in its mechanical properties, and at the same time, its color also changes.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Prepare according to the following formula,

[0018] 80 parts by weight of bisphenol A type cyanate resin;

[0019] Antioxidant 1010 0.2 parts by weight;

[0020] Antioxidant 168 0.2 parts by weight;

[0021] UV-9 0.4 parts by weight;

[0022] 6 parts by weight of polyaryletherketone;

[0023] KH560 0.5 parts by weight;

[0024] Fumed silica 1.5 parts by weight.

[0025] Stir 80 parts of bisphenol A type cyanate resin and 6 parts of polyarylether ketone at 180°C. After melting and dispersing evenly, cool down to 110°C, add 0.2 parts of antioxidant 1010, 0.2 parts of antioxidant 168, 0.4 parts of UV-9, after melting and dispersing evenly, lower the temperature to 80°C, add 0.5 parts of KH560, 1.5 parts of fumed silica, after the dispersion is uniform, pour the mixed resin directly into the glue tank of the coating machine , the film coating process is carried out, and then the compound process is carried out on the compound machine to combine the resin with the fib...

Embodiment 2

[0028] Prepare according to the following formula,

[0029] 80 parts by weight of bisphenol A type cyanate resin;

[0030] Antioxidant 1076 0.2 parts by weight;

[0031] Antioxidant 168 0.2 parts by weight;

[0032] UV-327 0.4 parts by weight;

[0033] 6 parts by weight of polyaryl ether sulfone;

[0034] KH550 0.5 parts by weight;

[0035] Fumed silica 1.5 parts by weight.

[0036] Stir 80 parts of bisphenol A type cyanate resin and 6 parts of polyarylether sulfone at 180°C. After melting and dispersing evenly, cool down to 110°C, add 0.2 parts of antioxidant 1076, 0.2 parts of antioxidant 168 , 0.4 parts of UV-327, after melting and dispersing evenly, lower the temperature to 80°C, add 0.5 parts of KH550, 1.5 parts of fumed silica, after being uniformly dispersed, pour the mixed resin directly into the glue tank of the film coating machine, The coating process is carried out, and then the compounding process is carried out on a compound machine to combine the resin wit...

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Abstract

The invention relates to the field of polymer materials and particularly relates to a preparing method of a cyanate resin composite. The method is characterized by comprising steps of stirring 50-100 parts by weight of cyanate resin and 1-30 parts by weight of a flexibilizer at 50-200 DEG C, after uniform melting and dispersion, cooling the mixture to 70-150 DGE C, adding 0.1-10 parts of an antioxidant and 0.1-20 parts of an ultraviolet absorber, cooling the mixture to 70-150 DGE C after uniform melting and dispersion, then adding 0.1-10 parts of a coupling agent and 0.1-10 parts of a thixotropic agent, fully dispersing the mixture to obtain a cyanate resin composition resistant to illumination aging, and subjecting the resin composition to a coating step, a fiber compositing step and curing to obtain the composite resistant to illumination aging. The prepared composite has better illumination aging resistance and good manufacturability, and can be subjected to film coating and composite processes to prepare prepregs. A preparing process is simple and the production cost is low.

Description

technical field [0001] The invention relates to the field of polymer composite materials, in particular to a preparation method of a cyanate resin composite material with light aging resistance. Background technique [0002] As we all know, cyanate resin has good mechanical properties, dielectric properties, heat resistance, etc., and it forms four high-performance resin matrix materials together with phenolic resin, epoxy resin, and bismaleimide resin. Because of its outstanding dielectric properties, dielectric constant (2.8-3.2), dielectric loss (0.002-0.008), it can be used in structural materials, wave-transmitting materials, dielectric functional materials, etc., used in aerospace, electronic information, etc. field. However, at present, cyanate ester resins have disadvantages such as poor manufacturability, poor toughness, short pot life and storage period, poor hardness, and poor wear resistance. Especially long-term exposure to the sun will accelerate the aging of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L79/04C08L71/10C08L81/06C08K13/04C08K3/36C08K5/132C08K5/3475
CPCC08L79/04C08K2201/014C08L2201/08C08L2205/06C08L71/00C08K13/04C08K3/36C08K5/1345C08K5/526C08K5/132C08L81/06C08K5/3475
Inventor 王大伟林凤森李盛林朱有欣
Owner WEIHAI GUANGWEI COMPOSITES
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