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Complex catalyst, catalyst composition and preparation method of a kind of olefin polymer

A technology of catalyst and composition, which is applied in the field of preparation of compounds, complex catalysts, catalyst compositions and olefin polymers, and can solve the problems of poor adhesion, wettability and miscibility, metal deactivation, and the inability to achieve polar monolithic Copolymerization and other issues

Active Publication Date: 2020-10-27
合肥中科科乐新材料有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although polyolefin materials have such a large amount of use, there are still some problems to be solved, such as because polyolefin is a non-polar material, its adhesion, wettability and miscibility are relatively poor (J.-Y.Dong, Y. Hu, Coord. Chem. Rev. 2006, 250, 47.)
Late transition metals can catalyze the copolymerization of olefins and polar monomers, making it a research hotspot in recent years. However, in order to achieve better copolymerization effects, there are still some problems to be solved. The three main problems are: 1. Polar functional group to metal; 2, forming a stable metal-alkyl chelating ring to deactivate the metal; 3, rapid β-X elimination
(B.S.Williams, M.D.Leatherman, P.S.White, M.Brookhart, J.Am.Chem.Soc.2005, 127, 5132.) And due to the fast chain walking characteristics of the Brookhart type catalyst, even if long-chain polar monomers are used (Introduction of methylene between the double bond and the polar functional group) can not achieve the above-mentioned polar monomer copolymerization
The characteristic of chain walking also makes the polymer product catalyzed by this catalyst amorphous, which further limits the application of this type of polymer.

Method used

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  • Complex catalyst, catalyst composition and preparation method of a kind of olefin polymer
  • Complex catalyst, catalyst composition and preparation method of a kind of olefin polymer
  • Complex catalyst, catalyst composition and preparation method of a kind of olefin polymer

Examples

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preparation example Construction

[0079] The present invention has no special limitation on the preparation method of the compound represented by the structure of formula (I), just use the conventional preparation method well known to those skilled in the art, and those skilled in the art can according to the actual production situation, product requirements and use requirements To select and adjust, the present invention is to optimize the preparation process, a complete technical scheme, the preparation method of the compound shown in the formula (I) structure is specifically preferably the following steps:

[0080] (a) by reacting the diketone of formula A and the amine compound of formula B, form the compound of formula C; As shown in reaction formula (a):

[0081]

[0082] (b) react by formula C compound and formula D amine compound, form formula (I) compound; As shown in reaction formula (b):

[0083]

[0084] In the preparation method of the above-mentioned compound represented by the structure of...

Embodiment 1

[0131] Synthesis of Ligand NO-L

[0132]

[0133] 2,6-Dimorpholine aniline (1.05 g, 4 mmol) was added to a 20 mL Schlenk bottle under nitrogen (Irie, Y.; Koga, Y.; Matsumoto, T.; Matsubara, K. Eur. J .Org.Chem.2009, 2243.), 2,3-butanedione (0.174 ml, 2 mmol), formic acid (0.05 ml, 1.33 mmol) and methanol (6 ml). After stirring at room temperature for three days, a yellow solid precipitated. After filtration, the solid precipitate was washed three times with ice methanol and then dried by vacuum pump to obtain the target product NO-L (0.737 g, yield 64%).

[0134] The product prepared in Example 1 of the present invention is detected by proton nuclear magnetic spectrum and carbon spectrum, and the results are as follows:

[0135] 1 H NMR (400MHz, CDCl 3 )δ7.06(t, J=8.0Hz, 2H, ArH), 6.74(d, J=8.1Hz, 4H, ArH), 3.88–3.65(m, 16H, OCH 2 ),3.39–3.17(m,8H,NCH 2 ),2.80–2.60(m,8H,NCH 2 ), 1.93(s,6H,N=CCH 3 ).

[0136] 13 C NMR (100MHz, CDCl 3 )δ166.73 (N=C), 141.94, 138.62...

Embodiment 2

[0140] Synthesis of Ligand N6-L

[0141]

[0142] 2,6-Dihexahydropyridineaniline (1.04 g, 4 mmol) was added to a 20 mL Schlenk bottle under nitrogen (Irie, Y.; Koga, Y.; Matsumoto, T.; Matsubara, K. Eur. J. Org. Chem. 2009, 2243.), 2,3-butanedione (0.174 mL, 2 mmol), formic acid (0.05 mL, 1.33 mmol) and methanol (6 mL). After stirring at room temperature for three days, a yellow solid precipitated. After filtration, the solid precipitate was washed three times with ice methanol and then dried by vacuum pump to obtain the target product N6-L (0.795 g, yield 70%).

[0143] The product prepared in Example 2 of the present invention is detected by proton nuclear magnetic spectrum and carbon spectrum, and the results are as follows:

[0144] 1 H NMR (400MHz, CDCl 3 )δ6.97(t, J=8.0Hz, 2H, ArH), 6.66(d, J=8.0Hz, 4H, ArH), 3.22(d, J=7.5Hz, 8H, NCH 2 ),2.69–2.56(m,8H,NCH 2 ), 1.95(s,6H,N=CCH 3 ), 1.69–1.61 (m, 8H, NCH 2 CH 2 CH 2 ),1.57–1.47(m,16H,NCH 2 CH 2 ).

[0145]...

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Abstract

The invention provides a compound as shown in formula (I) and a complex catalyst. The compound is based on the ligand effect of second layer space among molecules, and ensures that the second layer coordination space strategy is applied to olefin body polymerization and the copolymerization of olefin and polar monomers, so as to obtain a good technical effect. The complex catalyst belongs to palladium, nickel and iron catalysts containing alpha-diimine ligands with second layer coordination space effect, in the system, beta-H and beta-X elimination is restrained through the second layer coordination space effect, but normal coordination of ethylene is not prevented, therefore, the occurrence of chain walking is restrained, the polyethylene branching coefficient is reduced, and the copolymerization of ethylene and more polar monomers is realized.

Description

technical field [0001] The invention relates to the technical field of catalysts, and relates to a preparation method of a complex catalyst, a catalyst composition and an olefin polymer, in particular to a preparation method of a compound, a complex catalyst, a catalyst composition and an olefin polymer. Background technique [0002] Polyolefins, that is, polymers of olefins, are mainly composed of ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 1-octene, 4-methyl-1-pentene and other α-olefins and certain A general term for a class of thermoplastic resins obtained by polymerizing or copolymerizing cyclic olefins alone. Polyolefin has the characteristics of low relative density, good chemical resistance, good water resistance, good mechanical strength, electrical insulation, etc., and because of abundant raw materials, low price, easy processing and excellent comprehensive performance, it is the largest output of a class. Polymer materials are widely used in various fiel...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F10/00C08F110/02C08F210/02C08F220/14C08F218/12C08F214/14C08F216/08C08F216/20C08F212/06C08F4/70C08F4/80C07D295/135C07F15/04C07F15/00
CPCC07D295/135C07F15/0066C07F15/045C08F10/00C08F110/02C08F210/02C08F4/7006C08F4/80C08F220/14C08F2500/02C08F2500/03C08F218/12C08F214/14C08F216/08C08F216/20C08F212/06
Inventor 陈昶乐李敏
Owner 合肥中科科乐新材料有限责任公司
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