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Copper slag and laterite nickel ore co-reduction method for preparing copper-containing, nickel-iron powder

A technology of laterite nickel ore and ferronickel powder, which is applied in the field of metallurgy and material science to achieve the effect of improving metal recovery rate, reducing powder, and reducing ring formation in rotary kiln

Active Publication Date: 2019-01-29
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Foreign high-grade lateritic nickel ore resources are mostly controlled by companies such as Japan, Europe and the United States, while low-grade lateritic nickel ore accounting for 70% of the reserves has no effective extraction technology

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A method for co-reduction of copper slag and laterite nickel ore of the present invention to prepare copper-containing, ferronickel powder, specifically comprises the following steps:

[0030] (1) Pretreatment of lateritic nickel ore: dry the low-grade lateritic nickel ore containing 17.49% iron and 1.7% nickel to a moisture content of 10% to 15%, crush it to a particle size of less than 3mm, and then pass it through high-pressure roller milling. Until the specific surface area of ​​laterite nickel ore is not less than 1500cm 2 / g, more than 80% of the particle size is less than 0.074mm, and the pretreated laterite nickel ore is obtained.

[0031] (2) Copper slag pretreatment: The copper slag containing 40.03% iron and 0.63% copper is subjected to high-pressure roller grinding until more than 80% of the particles in the copper slag have a particle size of less than 0.074mm and a specific surface area of ​​not less than 2000cm 2 / g to obtain pretreated copper slag.

[...

Embodiment 2

[0039] A method for co-reduction of copper slag and laterite nickel ore of the present invention to prepare copper-containing, ferronickel powder, specifically comprises the following steps:

[0040] (1) Pretreatment of lateritic nickel ore: dry the low-grade lateritic nickel ore containing 17.49% iron and 1.7% nickel to a moisture content of 10% to 15%, crush it to a particle size of less than 3mm, and then pass it through high-pressure roller milling. Until the specific surface area of ​​laterite nickel ore is not less than 1500cm 2 / g, more than 80% of the particle size is less than 0.074mm, to obtain pretreated lateritic nickel ore.

[0041] (2) Copper slag pretreatment: The copper slag containing 40.03% iron and 0.63% copper is subjected to high-pressure roller grinding until more than 80% of the particles in the copper slag have a particle size of less than 0.074mm and a specific surface area of ​​not less than 2000cm 2 / g to obtain pretreated copper slag.

[0042](3) ...

Embodiment 3

[0049] A method for co-reduction of copper slag and laterite nickel ore of the present invention to prepare copper-containing, ferronickel powder, specifically comprises the following steps:

[0050] (1) Pretreatment of lateritic nickel ore: dry the low-grade lateritic nickel ore containing 17.49% iron and 1.7% nickel to a moisture content of 10% to 15%, crush it to a particle size of less than 3mm, and then pass it through high-pressure roller milling. Until more than 80% of the particles in the laterite nickel ore have a particle size of less than 0.074mm and a specific surface area of ​​not less than 1500cm 2 / g, to obtain pretreated laterite nickel ore.

[0051] (2) Copper slag pretreatment: The copper slag containing 40.03% iron and 0.63% copper is subjected to high-pressure roller grinding until more than 80% of the particles in the copper slag have a particle size of less than 0.074mm and a specific surface area of ​​not less than 2000cm 2 / g to obtain pretreated coppe...

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Abstract

The invention discloses a method for preparing iron powder containing copper and nickel by coreduction of copper slag and nickel laterite ores. The method comprises the following steps: nickel laterite ores, copper slag and a composite binding agent are mixed and pelletized to obtain green balls; the green balls are preheated after drying, and are fed in a rotary kiln; reducing coals are added for reduction to obtain reducing products; and the ore grinding and the magnetic separation are performed on the reducing products to obtain the iron powder containing copper and nickel. The method can realize comprehensive utilization of the copper slag and the nickel laterite ores by one step, and obtains the iron powder containing copper and nickel to provide high-quality burdens for smelting of weather resistant steel; and meanwhile, the excellent soft melting characteristic of the copper slag is used for reinforcing generation of a liquid phase in the reduction process, so that the aggregation and the growth of iron grains are accelerated, and the copper and nickel recovery rates are increased.

Description

technical field [0001] The invention relates to the technical field of metallurgy and material science, in particular to a method for co-reducing copper slag and laterite nickel ore to prepare copper-containing nickel-iron powder. Background technique [0002] Weathering steel is a low-alloy steel series between ordinary steel and stainless steel. Weathering steel is made of ordinary carbon steel with a small amount of corrosion-resistant elements such as Cu and Ni. It has the toughness, plastic extension, forming, welding and cutting of high-quality steel. , abrasion, high temperature, fatigue resistance and other characteristics; weather resistance is 2 to 8 times that of ordinary carbon steel, and paintability is 1.5 to 10 times that of ordinary carbon steel. It is widely used in buildings, vehicles, bridges, towers, containers, railways Vehicles, oil derricks, harbor buildings, oil production platforms and other structural parts. In the process of producing weathering s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B1/242C21B13/08C22B15/00C22B23/02
CPCC21B13/08C22B1/2406C22B1/242C22B15/0054C22B23/021C22B23/023
Inventor 潘建朱德庆李启厚郭正启薛钰霄李紫云梁钟仁
Owner CENT SOUTH UNIV
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