Method and device for measuring dissolved oxygen based on dual-channel lock-in amplifying technique

A technology of lock-in amplification and measurement device, which is applied in measurement device, material analysis by optical means, instrument, etc., can solve the problems of multiplier and low-pass filter output influence, easy failure, instability and other problems, and achieves convenient use. , the effect of improving anti-pollution ability, high detection accuracy and test data stability

Active Publication Date: 2017-11-24
OCEANOGRAPHIC INSTR RES INST SHANDONG ACAD OF SCI
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  • Application Information

AI Technical Summary

Problems solved by technology

Since the iodometric method consumes a large amount of samples, remote monitoring cannot be realized, and the sensor made by the electrochemical method has inherent defects such as easy contamination, frequent cleaning, instability and failure.
Although the analog lock-in amplification technology can detect the weak dissolved oxygen signal submerged in the strong noise background, it has strict requirements on the phase of the reference signal.
Because the prerequisite for the output DC signal to be proportional to the amplitude of the measured signal is to ensure that the frequency of the input signal and the reference signal are the same, and the phase difference is 0, because the initial phase difference between the useful signal and the reference signal is different. Can have a large impact on the output of the multiplier and low-pass filter
The DC output signal of the lock-in amplifier can truly reflect the change of the actual signal when the initial phase difference is 0, but the detection effect in other cases is not ideal, and the measured dissolved oxygen parameters are quite different from the actual ones.
This requires adding a phase shift circuit between the reference signal and the measured signal to ensure that the phase difference between the two is 0, but there are many difficulties in real-time and accurate adjustment of the phase difference to 0.

Method used

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  • Method and device for measuring dissolved oxygen based on dual-channel lock-in amplifying technique
  • Method and device for measuring dissolved oxygen based on dual-channel lock-in amplifying technique
  • Method and device for measuring dissolved oxygen based on dual-channel lock-in amplifying technique

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Embodiment 1

[0029] As shown in the figure, the dissolved oxygen measurement device based on dual-channel lock-in amplification technology includes an oxygen sensitive film, an optical detection module, a signal modulation and demodulation module, a signal processing module, a system control module, a communication module, and a power management module.

[0030] Oxygen sensitive membrane is dissolved in water oxygen content detection module, such as figure 1 The black part of the oxygen-sensitive film shown is the light-shielding film that mainly shields external light interference, and the white part is the quenched fluorescent substance. When the excitation light generated by the LED lamp of the optical detection module is irradiated on the oxygen-sensitive film, it will excite fluorescence, and the oxygen dissolved in water will promote the quenching of fluorescence, resulting in a shortened lifetime of fluorescence, so the fluorescence excited by the different oxygen content The lifesp...

Embodiment 2

[0044] Stern-Volmer constant It needs to be obtained by fitting the data measured through a large number of experiments in the laboratory. When the temperature is 25°C and the salinity is 0, the experimental fitting is 0.007824345. When the dissolved oxygen is 8.335μmol / L, the measured phase value of the blue LED is 63.443 degrees, and the phase value of the red LED is 8.1 degrees. The phase delay caused by dissolved oxygen is 55.343 degrees. The above-mentioned fluorescence delay phase and dissolved oxygen The concentration relationship formula is a linear equation, so the phase 55.343 degrees when the dissolved oxygen is 8.335 μmol / L can be taken here as the phase when there is no oxygen . Then measuring the phase delay under different dissolved oxygen concentrations can calculate the corresponding dissolved oxygen concentration. When the phase difference measured by the experimental test is 49.836 degrees, the dissolved oxygen content calculated by the formula is 30.7...

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Abstract

The invention belongs to the technical field of ocean observation and discloses a device and a method for measuring dissolved oxygen based on a dual-channel lock-in amplifying technique. The device comprises an oxygen sensitive membrane, an optical detection module, a signal modulation and demodulation module, a signal processing module, a system control module, a communication module and a power management module. Through the technical scheme, the device and the method are capable of measuring the content of the dissolved oxygen in the water in real time, are free of consumption of samples and free of pollution, is stable and efficient, and is also capable of achieving remote on-line in-situ monitoring.

Description

technical field [0001] The patent of the present invention relates to the technical field of marine monitoring, in particular to a dissolved oxygen measuring device and method based on dual-channel lock-in amplification technology. Background technique [0002] Oxygen is closely related to people's production and life. The determination of dissolved oxygen has important applications in aquaculture, papermaking, metallurgy, chemical oil refining, sewage treatment, and medical biology. Traditional dissolved oxygen measurement techniques mainly include titration iodometric method, electrochemical method and analog lock-in amplification method. Since the iodometric method consumes a large amount of samples, remote monitoring cannot be realized, and the sensor made by the electrochemical method has inherent defects such as easy contamination, frequent cleaning, instability and failure. Although the analog lock-in amplification technology can detect the weak dissolved oxygen sign...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/64
CPCG01N21/6428G01N2021/6432G01N2201/12
Inventor 吴丙伟张颖颖刘东彦袁达张云燕张颖侯广利程岩
Owner OCEANOGRAPHIC INSTR RES INST SHANDONG ACAD OF SCI
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